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ammonium hydroxide
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004185
EISBN: 978-1-62708-184-9
... Abstract Ammonia and ammonium hydroxide are not particularly corrosive in themselves, but corrosion problems can arise with specific materials, particularly when contaminants are present. This article discusses the corrosion resistance of materials used for the manufacture, handling...
Abstract
Ammonia and ammonium hydroxide are not particularly corrosive in themselves, but corrosion problems can arise with specific materials, particularly when contaminants are present. This article discusses the corrosion resistance of materials used for the manufacture, handling, and storage of ammonia. These materials include aluminum alloys, iron and steel, stainless steels, nickel and its alloys, copper and its alloys, titanium and its alloys, zirconium and its alloys, niobium, tantalum, and nonmetallic materials.
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Published: 01 January 2002
Fig. 43 Effect of initial tensile stress on time-to-fracture by SCC at room temperature of brass in three corrosive environments. Curve A, partly immersed in concentrated ammonium hydroxide; B, exposed to the vapor of concentrated ammonium hydroxide; C, exposed to a gaseous mixture of ammonia
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Published: 15 January 2021
Fig. 54 Plot showing the effect of initial tensile stress on stress-corrosion cracking time to fracture of brass in three corrosive environments at room temperature. Curve A: samples were partially immersed in concentrated ammonium hydroxide; B: samples were exposed to the vapor
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Published: 01 January 2000
Fig. 24 Vickers indents (50 gf) in the matrix (dark) and in the intergranular beta (white) phase in as-cast beryllium copper (C 82500) that was burnt in solution annealing (differential interference contrast illumination, aqueous 3% ammonium persulfate and 1% ammonium hydroxide). 500×
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Published: 01 January 2000
Fig. 25 Vickers indents (100 gf) in the matrix (dark) and in the intergranular beta (white) phase in an age-hardened as-cast beryllium copper (C 82500) that was burnt in solution annealing (differential interference contrast illumination, aqueous 3% ammonium persulfate and 1% ammonium
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Published: 01 December 2004
Fig. 1 Native copper showing a clean microstructure with a large grain size. Ammonium hydroxide/hydrogen peroxide etch. Source: Ref 16
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Published: 15 December 2019
Fig. 55 Microstructure of as-cast Cu-8.4%P eutectic structure of alpha copper and Cu 3 P etched using KBI reagent (100 mL water, 3 g ammonium persulfate, and 1 mL ammonium hydroxide) and viewed using (a) bright field, (b) dark field, and (c) Nomarski DIC. In dark field, all copper-phosphide
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in Metallography and Microstructures of Stainless Steels and Maraging Steels[1]
> Metallography and Microstructures
Published: 01 December 2004
Fig. 18 Delta-ferrite stringer and carbides along the centerline in solution-annealed (954 °C, or 1750 °F, water quenched) type 316L were revealed using (a) aqueous 20% NaOH and (b) concentrated ammonium hydroxide (NH 4 OH) at 5 V dc for 10 s.
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Published: 15 June 2019
Fig. 6 Effect of pH on corrosion of aluminum 1100-H14 in various chemical solutions. The concentration of all the solutions ranged from 0.00001 to 0.1 N , except acetic acid (0.00001 to 17.4 N ), ammonium hydroxide (NH 4 OH) (0.00001 to 15 N ), and sodium disilicate (Na 2 Si 2 O 5
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Published: 01 January 1994
Fig. 3 Effect of succinate additions on the plating rate of an electroless nickel solution. Solutions contain 16 g/L (2.1 oz/gal) nickel chloride (NiCl 2 ) and 24 g/L (3.2 oz/gal) sodium hypophosphite (NaH 2 PO 2 ). 5 g/L (0.7 oz/gal) ammonium hydroxide (NH 4 OH) and 1 mg/L (4 mg/gal) lead
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Published: 01 December 2004
Fig. 17 Wrought, solution-annealed, and aged beryllium-copper (Cu-1.8%Be-0.3%Co) in the heat treated condition: 790 °C (1455 °F), held 1 h, oil quenched, and aged at 315 °C (600 °F) for 2 h (380 HV). (a) Swab etched with equal parts ammonium hydroxide and hydrogen peroxide (3% conc
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Published: 01 January 2005
these solutions. (b) Effect of pH. The concentration of all the solutions ranged from 0.00001 to 0.1 N , except acetic acid (0.00001 to 17.4 N ), ammonium hydroxide (NH 4 OH) (0.00001 to 15 N ), and sodium disilicate (Na 2 Si 2 O 5 ) (0.00001 to 1 N ). (c) Effect of concentration of HNO 3 solutions at room
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Published: 01 August 2013
; original magnification: 500×. (d) Specimen similar to (c); electron diffraction reveals that the diagonal bands have a twin orientation with respect to the parent grain. TEM; original magnification: 50,000×. (e) Shear-band strain markings revealed by an ammonium hydroxide/hydrogen peroxide etch
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Published: 01 December 2004
Fig. 24 Wrought cartridge brass (Cu-30%Zn) cold reduced 50% and annealed at 704 °C (1300 °F) for 30 min. Fully recrystallized and grown, equiaxed face-centered cubic grains with annealing twins. (a) Etched with equal parts ammonium hydroxide and hydrogen peroxide (3%). (b) The specimen
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Published: 01 January 1994
(2.7 oz/gal) Ammonium hydroxide 30.4 mL/L (4.0 fl oz/gal) Water bal pH (colorimetric) 4.5–6.8 (k) 6 Nickel electroplate (l) Basic nickel carbonate 120 g/L (16.0 oz/gal) 49–60 (120–140) (i) Low–carbon steel (m) Hydrofluoric acid (as 100% HF) 43 mL/L (5.7 fl oz/gal
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Book Chapter
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003764
EISBN: 978-1-62708-177-1
... hydroxide NH 4 OH Corrosive (>35%), irritating Liquid: aqueous solution; pungent smell; density, 0.882–0.96 g/cm 3 Ammonium molybdate (NH 4 ) 6 Mo 7 O 24 ·4H 2 O … Crystalline: colorless; releases NH 3 when exposed to air Ammonium persulfate (NH 4 ) 2 S 2 O 8 Irritating, supports burning...
Abstract
This article is a comprehensive collection of tables listing: dangerous reactions of chemicals and designations of etchants; chemical-polishing solutions for irons and steels and nonferrous materials; attack-polishing solutions, macrostructure etchants for iron and steel; and major microstructure etchants for common phases and constituents in ferrous materials.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001247
EISBN: 978-1-62708-170-2
... solutions Table 1(a) Compositions of cadmium plating cyanide solutions Solution No. Ratio of total sodium cyanide to cadmium metal Composition (a) Cadmium oxide Cadmium metal Sodium cyanide Sodium hydroxide (b) Sodium carbonate (c) g/L oz/gal g/L oz/gal g/L oz/gal g/L oz/gal...
Abstract
Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature of cadmium plating with attention to the materials of construction and equipment used. The article provides a description of the selection of plating method with examples, applications, and several postplating processes of cadmium plating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001254
EISBN: 978-1-62708-170-2
... Solution B Palladium (as diamino-palladous nitrite), g/L (oz/gal) 10 (1) Ammonium sulfamate, g/L (oz/gal) 110 (15) Ammonium hydroxide To pH pH 7.5-8.5 Temperature Room Current density, A/dm 2 (A/ft 2 ) 0.5-2.2 (5-20) (b) Cathode efficiency, % 70 Anodes Insoluble; platinum...
Abstract
The electroplating of platinum-group metals (PGMs) from aqueous electrolytes for engineering applications is limited principally to palladium and, to a lesser extent, to platinum, rhodium, and thin layers of ruthenium. This article provides a discussion on the plating operations of these PGMs along with the types of anodes used in the process.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006489
EISBN: 978-1-62708-207-5
... caustic and acid etching was introduced. This patented process is being used as a true alternative to sodium hydroxide etching. This process is ammonium bifluoride based and produces a low gloss with minimal aluminum dissolution. Ammonium bifluoride etchants have been used in the past; however, they were...
Abstract
Etching aluminum can be a pretreatment step for anodizing, chemical conversion coating, metal-to-rubber bonding, and a host of other processes. Chemical etching, using either alkaline or acid solutions, produces a matte finish on aluminum products. This article describes the alkaline etching and acid etching of aluminum. Alkaline etching reduces or eliminates surface scratches, nicks, extrusion die lines, and other imperfections. Acid etching can be done without heavy smut problems, particularly on aluminum die castings. Hydrochloric, hydrofluoric, nitric, phosphoric, chromic, and sulfuric acids are used in acid etching. The article presents a flow chart of the operations used in acid etching.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001317
EISBN: 978-1-62708-170-2
... with hydrazine, in order to reduce the metal, or with acids or bases, in order to neutralize the impregnating solution (i.e., the addition of ammonium hydroxide to a H 2 PdCl 4 impregnating solution) and precipitate the metal oxide to obtain dispersions. This step is carried out after impregnation, but before...
Abstract
The chemical process being catalyzed should have a high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the general catalyst preparation procedures, namely, impregnation, ion exchange, and precipitation. Catalyst carriers are usually high-surface-area inorganic materials with complex pore structures, into which catalytic materials such as palladium, platinum, cobalt, chromium oxide, and vanadium pentoxide are deposited using these procedures. The article also provides information on catalyst powder processing.
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