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Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003010
EISBN: 978-1-62708-200-6
... the general and family characteristics of thermosetting resin families, including allyls, aminos (urea formaldehyde and melamine formaldehyde), cyanates, epoxies, polybenzimidazoles, unsaturated polyesters, thermoset polyimides, phenolics, and vinyl esters. It also explains processing methods, including...
Abstract
A thermosetting resin, or thermoset, is a synthetic organic polymer that cures to a solid, infusible mass by forming a three-dimensional network of covalent chemical bonds. Significant applications include construction and thermoset engineering plastics. This article discusses the general and family characteristics of thermosetting resin families, including allyls, aminos (urea formaldehyde and melamine formaldehyde), cyanates, epoxies, polybenzimidazoles, unsaturated polyesters, thermoset polyimides, phenolics, and vinyl esters. It also explains processing methods, including curing and curing agents. The article provides descriptions of commercial product forms and the wide array of applications of thermosetting resins. It also tabulates the performance properties (mechanical, thermal, electrical and chemical resistance) of some families of unfilled or unreinforced thermosetting resins and reinforced or filled grades.
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Published: 01 January 1986
Fig. 3 Normal-phase chromatograms. (a) Using a silica column. (b) Using an amino column. (c) Using a phenyl-NP column. (d) Using a cyano column. Source: Ref 2
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Published: 01 November 1995
Fig. 8 Constituents of nylons. (a) Diamines and dibasic acids. (b) ω-amino acids. (c) Lactams
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Published: 01 January 2006
Fig. 9 Principle of dieless NC forming. Courtesy of Amino Corporation
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Published: 01 January 2006
Fig. 7 Schematic illustration of dieless numerical-control forming. Courtesy of Amino Corporation
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Published: 01 January 2006
Fig. 8 The control system of a dieless numerically controlled forming machine. Courtesy of Amino Corporation
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Published: 01 January 2006
Fig. 5 Machines used for incremental sheet forming (ISF). (a) Upgraded milling machine. (b) Dedicated machine for ISF by AMINO. (c) A special ISF machine built at the University of Cambridge. (d) Roboforming process using two robots. (a) to (c) Source: Ref 3 (d) Source: Ref 5
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Published: 15 May 2022
)aluminum; Ir(ppy) 3 : tris[2-phenylpyridinato-C2,N]iridium(III); TCTA: tris(4-carbazoyl-9-ylphenyl)amine; A-NPD: (4,4-bis[N-1-naphthyl-N-phenylamino]biphenyl, alpha-NPD); BPAPF: 9,9-bis[4-(N,N-bis(biphenyl-4-yl)amino)phenyl]-9H-fluorine; ITO: indium tin oxide. Courtesy of ION-TOF GmbH
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001777
EISBN: 978-1-62708-178-8
... though it has not been modified with a bonded phase, is usually considered along with polar bonded phases because it is employed in a similar manner. BPC stationary phases Table 1 BPC stationary phases Designation Formula Silica (Si) Si–OH Amino (NH 2 ) Si–O–Si(OH) 2 –(CH 2 ) 3 –NH...
Abstract
This article introduces the fundamental concepts and the essential components of liquid chromatography (LC). It discusses the different modes of LC, such as liquid-solid chromatography, liquid-liquid chromatography, bonded-phase chromatograph, normal-phase chromatography, reversed-phase chromatography, ion-exchange chromatography, ion-pair chromatography, and size-exclusion chromatography. The article also includes a discussion on the qualitative and quantitative analyses and the applications of LC.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003698
EISBN: 978-1-62708-182-5
... (DICHAN) Protection of ferrous metals and alloys 46 , 47 Amino nitrobenzoate Effective passivator 48 Dintroresorcinate hexamethylenetetramine Protects iron in humid environment 49 Tall oil plus industrial oils Considerable protection of steel in sulfur dioxide atmosphere 50...
Abstract
This article discusses the definitions, classifications, structural features, vapor pressure values, corrosion inhibition mechanisms, and methods of evaluation of vapor-phase-corrosion inhibitors or volatile corrosion inhibitors (VCIs). Practical methods of using VCIs for corrosion protection of aluminum, ferrous, and nonferrous alloys are discussed with specific examples. The article contains tables that summarize the applications of different VCIs used for protecting ferrous metals, copper and its alloys, and silver.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006009
EISBN: 978-1-62708-172-6
... of flexibility paired with excellent surface hardness and stability. High-molecular-weight linear polyesters primarily are used in baking enamels for highly flexible coatings, such as those for coils and cans, with amino resins or other suitable hydroxyl-reactive cross linkers, but also may be used as physically...
Abstract
This article provides a discussion on polyester coating applications such as powder coatings, can coatings, and automotive paints. It includes an overview, structure, properties, and benefits of vinyl ester resins. The article discusses the additives for both unsaturated polyester and vinyl ester coatings, namely, curing systems, thixotropic agents and fillers. It exemplifies polyester and vinyl ester coating, lining and flooring systems that are used for top-to-bottom protection of industrial plants and equipment. The article also highlights the concerns to be addressed when using polyesters and vinyl esters.
Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005154
EISBN: 978-1-62708-186-3
... effective. The technique was developed to meet the needs of the automotive industry as an alternative manufacturing method for small production lot sizes and rapid prototyping. It has been commercialized by the Japanese company Amino Corporation. Principle of Operation In dieless NC forming...
Abstract
Rapid prototyping (RP) techniques in the sheet-metal forming industry is developed to quickly test the form and fit of new sheet-metal products on a prototype basis as well as for production runs characterized by small lot sizes. This article provides an overview of some of the technologies used for RP and low-volume production of sheet-metal parts. It discusses low-cost tooling and flexible sheet-forming processes and reviews the various aspects of incremental sheet forming.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006855
EISBN: 978-1-62708-392-8
... or hydroxylysine amino acid groups through Schiff’s base formation ( Fig. 3 ) ( Ref 2 , 9 ). The synthesis and use of ADA-based hydrogels has been reviewed by Reakasame et al. ( Ref 5 ). Fig. 2 Oxidation reaction of alginate by (a) sodium periodate, (b) formation of alginate dialdehyde, and (c) hemiacetal...
Abstract
This article discusses alginate/gelatin-based bioinks in 3D bioprinting applications, providing a summary of the most relevant previous work in the field. It presents advanced compositions to enhance functionality and/or optimize hydrogels for 3D bioprinting. The article discusses advanced printing techniques for alginate/gelatin-based bioinks.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006036
EISBN: 978-1-62708-172-6
... of this crowded environment, the chemical reaction (also called the curing reaction of the coating) of this amino group in the co-reactant with the isocyanate group (-NCO) of the polyisocyanate crosslinker is slower than typical reactions of secondary amines with polyisocyanates. The amount of steric crowding...
Abstract
Polyaspartic coating technology has found utility in a variety of coating applications, including corrosion protection and flooring topcoats, as these coatings are based on aliphatic polyisocyanates and aliphatic diamines. This article describes the chemistry of polyaspartic esters and curing characteristics and performance properties of polyaspartic coatings. It also provides information on curing corrosion protection coating systems, polyaspartic floor coatings, and safe-use recommendations for handling isocyanates.
Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0009153
EISBN: 978-1-62708-186-3
...: an upgraded conventional milling machine with moveable blank holder ( Fig. 5a ), a specially designed ISF machine distributed by the Japanese company AMINO ( Fig. 5b ), a special incremental sheet-forming machine built at the University of Cambridge ( Fig. 5c ), and the roboforming process that uses two...
Abstract
This article provides an overview of the incremental sheet forming (ISF) process and discusses the process variations of ISF. These variations include single-point incremental forming, two-point incremental forming, and kinematic incremental sheet forming. The article discusses the machines and equipment used in the process and describes the process parameters, process mechanics, and process limits. It illustrates multistage forming strategies and summarizes difficulties that exist with regard to the finite-element process simulation of ISF process. The article also describes hybrid process variations, such as stretch forming and laser-assisted ISF.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001745
EISBN: 978-1-62708-178-8
... of proteins, α-amino acids, amides, and amines. Mercury is required for samples containing heterocyclic compounds, such as pyridine and pyrrole. Some types of heterocyclic compounds consistently produce low results and are best determined using the Dumas method for nitrogen ( Ref 1 ). Compounds...
Abstract
This article discusses the major methods of elemental analysis, namely, the combustion method for carbon, hydrogen, and nitrogen; the Kjeldahl method for nitrogen; and the Schoniger flask method for other common elements. It also discusses the methods of functional group analysis for acids, alcohols, aldehydes and ketones, amines, esters, aromatic hydrocarbons, peroxides, phenols, water (Karl Fischer method), and alkenes.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001319
EISBN: 978-1-62708-170-2
... selected, a large variety of chemical groups can be incorporated into the surface: hydroxyl, carbonyl, carboxylic, amino, or peroxyl groups. Most important, the insertion or substitution of these groups in the polymer chain is under the control of the operator. In this manner, the surface energies...
Abstract
This article provides an overview of plasma surface treatments for plastics. It covers the equipment and methods used in plasma processing, providing detailed explanations of the plasma discharge reactions and how they affect surface state and topography. It also provides information on contamination removal, plasma surface modification, plasma-induced grafting, and plasma film deposition.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006920
EISBN: 978-1-62708-395-9
... subsequently with a polymeric alkyl radical to an amino ether ( Fig. 19 ). This amino ether can react with other radicals such as a peroxy radical to form a cross-linked polymer peroxide and regenerate the nitroxy radical, which can react with new alky radicals ( Ref 47 ). This process is catalytic...
Abstract
This article describes the processes involved in photochemical aging and weathering of polymeric materials. It explains how solar radiation, especially in the UV range, combines with atmospheric oxygen, driving photooxidation and the development of unstable photoproducts that cause various types of damage when they decompose, including the scission of carbon bonds and polymer chains. The article illustrates some of the degradation reactions that occur in different polymers and presents an overview of the strategies used to prevent such reactions or otherwise mitigate their effects.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004209
EISBN: 978-1-62708-184-9
... 97 Glycogen 6.8 Polysaccharides (nonglucosamine) 129 Organic acids 19 Citric 2.2 Lactic 36 Other organic acids 5 Lipids 530 Fatty acids 316 Amino acids 37.1 Major proteins Albumin 4800 Globulins 2300 Fibrinogen 300 Source: Ref 34...
Abstract
This article describes dental alloy compositions and its properties. It discusses the safety and efficacy considerations of dental alloy devices. The article defines and compares interstitial fluid and oral fluid environments. Artificial solutions developed for the testing and evaluation of dental materials are summarized. The article examines the effects of restoration contact on electrochemical parameters and reviews the concentration cells developed by dental alloy-environment electrochemical reactions. The composition and characterization of biofilms, corrosion products, and other debris that deposit on dental material surfaces are discussed. The article evaluates the types of alloys available for dental applications, including direct filling alloys, crown and bridge alloys, partial denture alloys, porcelain fused to metal alloys, wrought wire alloys, soldering alloys, and implant alloys. The effects of composition and microstructure on the corrosion of each alloy group are also discussed. The article concludes with information on the tarnishing and corrosion behavior of these alloys.
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