This article begins with a schematic illustration of a eutectic system in which the two components of the system have the same crystal structure. Eutectic systems form when alloying additions cause a lowering of the liquidus lines from both melting points of the pure elements. The article describes the aluminum-silicon eutectic system and the lead-tin eutectic system. It discusses eutectic morphologies in terms of lamellar and fibrous eutectics, regular and irregular eutectics, and the interpretation of eutectic microstructures. The article examines the solidification of a binary alloy of exactly eutectic composition. It concludes with a discussion on terminal solid solutions.

This article illustrates the equilibrium phase diagram for an aluminum-silicon system, showing the metastable extensions of liquidus and solidus lines. It describes the classification and microstructure of the aluminum-silicon eutectic. The article presents the theories of solidification and chemical modification of the aluminum-silicon eutectic.

This article discusses the two extremes of solute redistribution, equilibrium solidification and nonequilibrium Gulliver-Scheil solidification, for which solid redistribution of solute within the primary solid phase is the distinguishing parameter. The process and material parameters that control microsegregation are discussed in relation to the manifestations of microsegregation in simple and then increasingly complex alloy systems. The measurement and kinetics of microsegregation are discussed for the binary isomorphous systems: titanium-molybdenum; binary eutectic systems: aluminum-copper and aluminum-silicon; binary peritectic systems: copper-zinc; multicomponent eutectic systems: Al-Si-Cu-Mg; and for systems with both eutectic and peritectic reactions: Fe-C-Cr and nickel-base superalloy.

The most common aluminum alloy systems are aluminum-silicon, aluminum-copper, and aluminum-magnesium. This article focuses on the grain structure, eutectic microstructure, and dendritic microstructure of these systems. It provides information on microsegregation and its problems in casting of alloys. The article also illustrates the casting defects such as macroporosity, microshrinkage, and surface defects, associated with the alloys.

This article focuses on aspects that are important for the commercial production of castings. It discusses the modification process in hypoeutectic and eutectic alloys that differ only in the relative volume fraction of primary aluminum and aluminum-silicon eutectic. The article explains how modification changes porosity formation in a casting. It describes the mechanisms responsible for silicon modification, as well as the modifications and changes in eutectic nucleation and the eutectic grain structure. The article reviews the usage of strontium in foundry practices. The growth of silicon eutectic is described to explain effects ancillary to silicon modification. The article also examines the effects of elements, such as phosphorus, antimony, bismuth, magnesium, boron, and calcium, on the silicon structure.

This article focuses on the metallography and microstructures of wrought and cast aluminum and aluminum alloys. It describes the role of major alloying elements and their effect on phase formation and the morphologies of constituents formed by liquid-solid and/or solid-state transformations. The article also describes specimen preparation procedures and examines the microstructure of several alloy samples.

The physical and mechanical properties of aluminum alloy can be improved by strengthening mechanisms such as strain hardening used for non-heat treatable aluminum alloy and precipitation hardening used for heat treatable aluminum alloy. This article focuses on the effect of strengthening mechanisms on the physical and mechanical properties of non-heat treatable and heat treatable aluminum alloys. It describes the use of the aluminum alloy phase diagram in determining the melting temperature, solidification path, equilibrium phases, and explains the effect of alloying element in phase formation.

This article begins with a description of indirect and direct semisolid metalworking processes. It then provides information on alloy compositions of common aluminum semisolid metalworking alloys and primary die-cast magnesium alloys in a tabular form. The article describes the macroscopic examination of defects, which occur in semisolid metalworking with illustrations. It discusses the macroscopic examination of gating systems and semisolid feedstocks. The article also provides information on feedstock microstructures, direct semisolid metalworking component microstructures, and indirect semisolid metalworking component microstructures of series 300 aluminum casting alloys and magnesium die-casting alloys.

Castability is a complex characteristic that depends on both the intrinsic fluid properties of the molten metal and the manner in which the particular alloy solidifies. This article discusses the practical aspects of solidification important to aluminum foundrymen. The primary focus is on the chemical segregation that occurs during freezing, because it determines the castability of the alloy. The article describes the two types of segregation, namely, microsegregation and macrosegregation. It discusses the effect of freezing range on castability of an alloy. The article lists the freezing range of a number of important alloys. It concludes with a discussion on castability of 2xx, 3xx, 4xx, 5xx, and 7xx alloys.

Alloy phase diagrams are useful for the development, fabrication, design and control of heat treatment procedures that will produce the required mechanical, physical, and chemical properties of new alloys. They are also useful in solving problems that arise in their performance in commercial applications, thus improving product predictability. This article describes different equilibrium phase diagrams (unary, binary, and ternary) and microstructures, description terms, and general principles of reading alloy phase diagrams. Further, the article discusses plotting schemes; areas in a phase diagram; and the position and shapes of the points, lines, surfaces, and intersections, which are controlled by thermodynamic principles and properties of all phases that comprise the system. It also illustrates the application of the stated principles with suitable phase diagrams.

This article addresses two issues on thermodynamics, namely, the calculation of solubility lines and the calculation of the activity of various components. It discusses alloying elements in terms of their influence on the activity of carbon. The article describes the desulfurization and deoxidation of cast iron and steel. It illustrates the thermodynamics of the iron-carbon system and the iron-silicon system. The article examines solubility and saturation degrees of carbon in multicomponent iron-carbon systems. One of the main applications of the thermodynamics of the iron-carbon system is the calculation of structure-composition correlations. The article concludes with information on the structural diagrams for cast iron: the Maurer diagram and the Laplanche diagram.

This article presents the binary eutectic phase diagram to understand the various structures that evolve in a binary eutectic system during solidification. It describes the various classifications and solidification principles of the eutectic structures. The formation of halos in eutectic microstructures of most alloy systems is also discussed.

This article begins by describing the designations of cast and wrought aluminum alloys. It explains the effects of main alloying elements in aluminum alloys: boron, chromium, copper, iron, lithium, magnesium, manganese, nickel, phosphorus, silicon, sodium, strontium, titanium, and zinc. The article describes the microstructure of cast and wrought aluminum alloys and the various strengthening mechanisms, including solid solution, grain refinement, strain or work hardening, precipitation (or age) hardening, and dispersoid strengthening. The article explicates the tribological behavior of aluminum alloys, aluminum-base composites, and metal-matrix composites. It presents the effect of material-related parameters and external factors on wear behavior and transitions of aluminum-silicon alloys. The article also presents the most important factors affecting the dry sliding wear behavior of particle-reinforced aluminum-base composites against a steel counterface.

Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out during inoculation and nucleation of molten cast iron, assisting in the formation of cast iron. The different types of cast irons are gray cast iron, nodular cast iron, compacted graphite iron, malleable cast iron, and alloyed cast iron. The article provides an overview of the melt treatment processes carried out in cast steel, wrought and cast aluminum, and copper materials.

Heat treatment of aluminum alloys frequently refers to the heat treatable aluminum alloys that can be strengthened by solution treatment, quenching, and subsequent hardening. This article introduces the general metallurgy of strengthening aluminum alloys by heat treatment. It discusses various heat treatable alloying elements, such as copper, chromium, iron, magnesium, silicon, zinc, and lithium. The article describes the age-hardening treatments and generalized precipitation sequence for aluminum alloys. It reviews the solution heat treatment in terms of solution heating time and temperature, as well as high-temperature oxidation. The article also discusses quench sensitivity, vacancy loss, grain-boundary precipitates, and quench delay for the heat treatment of aluminum. It concludes with a discussion on the deformation of aluminum alloys prior to aging.

Aluminum alloys are widely used in engineered components because of their excellent strength-to-weight ratio. Their use in applications requiring wear resistance is more limited. One of the main limitations of aluminum alloys is the poor tribological behavior mainly due to their relatively low hardness, which favors large plastic deformation under sliding conditions. This article discusses the classes and mechanisms of wear in aluminum-silicon alloys, aluminum-tin bearing alloys, and aluminum-matrix composites; describes the effect of material-related parameters on wear behavior of these alloys; and reviews their applications in a variety of tribological applications in the automotive industry ranging from aluminum-tin alloys for plain bearings to alloys with hard anodizing for machine elements. Methods to improve wear resistance and alloy hardness are also discussed.

This article begins with a discussion on the effects of alloying and impurity elements on the properties of aluminum cast alloys and their chemical compositions. It describes the various means of structural control, namely, chemistry control, control of element ratios based on the stoichiometry of intermetallic phases, and control of solidification conditions. The article discusses the modification and grain refinement of aluminum-silicon alloys by the use of modifiers and refiners to influence eutectic and hypereutectic structures in aluminum-silicon alloys. It provides information on foundry alloys for specific casting applications. The article concludes with a discussion on the heat treatment practices and properties of aluminum casting alloys.

The control of the solidification process of cast iron requires understanding and control of the thermodynamics of the liquid and solid phases and of the kinetics of their solidification, including nucleation and growth. This article addresses issues that allow for the determination of probability of formation and relative stability of various phases. These include the influence of temperature and composition on solubility of various elements in iron-base alloys; calculation of solubility lines, relevant to the construction of phase diagrams; and calculation of activity of various components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems, along with saturation degree and carbon equivalent.

This article focuses on the various criteria considered in the selection of product forms, joint types, solders, and filler metals for brazing and soldering of base material components.

This article provides an overview of heat treatment processes, namely, solution heat treatment, quenching, natural aging, and artificial aging. It contains a table that lists the various heat treatment tempers commonly practiced for nonferrous castings. The article describes microstructural changes that occur due to the heat treatment of cast alloys.