Aluminum and its alloys are highly corrosion resistant, protected by a self-healing oxide film that effectively passivates the underlying surface. This article examines the various processes by which the protective layer can be breached and the types of corrosion that can occur. It describes pitting, galvanic, and atmospheric corrosion as well as stress-corrosion cracking, corrosion fatigue, and erosion corrosion. It also covers intergranular, exfoliation, filiform, deposition, and crevice corrosion and special cases of corrosion in soils, seawater, and automotive coolant systems. The article provides an extensive amount of data as well as information on coatings, claddings, and cathodic protection methods; the effects of composition, microstructure, and surface treatments; and the compatibility of aluminum with food and various household and industrial chemicals.

This article focuses on a variety of laser beam machining (LBM) operations of aluminum and its alloys, namely, laser cutting, laser drilling, laser milling, laser turning, laser grooving, laser scribing, laser marking, and laser micromachining. It presents different approaches for carrying out machining operations, laser processing parameters, efficiency and accuracy of the process, and the effect of laser processing parameters on the quality of the machined surface. The article provides an overview of the various conventional (chip forming) and nonconventional machining techniques employed for aluminum-based materials. A comparison of the various aspects of LBM with other non-conventional techniques is also presented. The article also describes the features of LBM techniques employed for aluminum and its alloys for different types of machining.

This article focuses on the various forms of corrosion that occur in the passive range of aluminum and its alloys. It discusses pitting corrosion, galvanic corrosion, deposition corrosion, intergranular corrosion, stress-corrosion cracking, exfoliation corrosion, corrosion fatigue, erosion-corrosion, atmospheric corrosion, filiform corrosion, and corrosion in water and soils. The article describes the effects of composition, microstructure, stress-intensity factor, and nonmetallic building materials on the corrosion behavior of aluminum and its alloys. It also provides information on the corrosion resistance of anodized aluminum in contact with foods, pharmaceuticals, and chemicals.

This article discusses the corrosion resistance of aluminum and aluminum alloys in various environments, such as in natural atmospheres, fresh waters, seawater, and soils, and when exposed to chemicals and their solutions and foods. It describes the forms of corrosion of aluminum and aluminum alloys, including pitting corrosion, intergranular corrosion, exfoliation corrosion, galvanic corrosion, stray-current corrosion, deposition corrosion, crevice corrosion, filiform corrosion, stress-corrosion cracking, corrosion fatigue, and hydrogen embrittlement. The article also presents a short note on aluminum clad products and corrosion at joints.

Aluminum and its alloys are used in a broad range of applications. This article discusses the primary and secondary production of aluminum and the classification system for cast and wrought products. It describes some of the more common manufactured forms, including commercial wrought aluminum products, aluminum alloy engineered castings, powder metallurgy parts, and metal-matrix composites. The article also reviews fabrication characteristics such as machining, forming, forging, and joining. It concludes with a description of the major industrial applications of wrought and cast aluminum alloys.

Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.

Aluminum, the second most plentiful metallic element, is an economic competitor in various applications owing to its appearance, light weight, fabricability, physical properties, mechanical properties, and corrosion resistance. This article discusses the primary and secondary production of aluminum and classification system for cast and wrought aluminum alloys. It talks about various manufactured forms of aluminum and its alloys, which are classified into standardized products such as sheet, plate, foil, rod, bar, wire, tube, pipe, and structural forms, and engineered products such as extruded shapes, forgings, impacts, castings, stampings, powder metallurgy parts, machined parts, and metal-matrix composites. The article also reviews important fabrication characteristics in the machining, forming, forging, and joining of aluminum alloys. It concludes with a description of the major industrial applications of aluminum, including building and construction, transportation, consumer durables, electrical, machinery and equipment, containers and packaging, and other applications.

A four-digit numerical designation system is used to identify wrought aluminum and aluminum alloys. In addition to providing a detailed account of the temper designation system for aluminum and aluminum alloys, this article describes wrought and cast aluminum and aluminum alloy designations. It also tabulates the grade designations and compositions of wrought and cast aluminum and aluminum alloys. The article provides information on cross-referencing of aluminum wrought and ingot/cast products according to composition, per the Aluminum Association, Unified Numbering System (UNS) and International Organization for Standardization (ISO) standards.

This article discusses the chemical composition, mechanical, physical, thermal, electrical, optical, and magnetic properties of a variety of grades of wrought aluminum and aluminum alloys. It also discusses the standard specifications, mass and fabrication characteristics, corrosion resistance, and applications of a variety of grades of wrought aluminum and aluminum alloys.

This article begins with a discussion on the classification of aluminum alloys and the selection of alloy and temper based on machinability. It provides an overview of cutting force and power, tool design and material, and general machining conditions. In addition, the article discusses distortion and dimensional variation and machining problems during the machining of high-silicon aluminum alloy. It also provides information on tool design and material, speed and feed, and the cutting fluid used for various machining processes, namely, turning, boring, planing and shaping, broaching, reaming, tapping, milling, sawing, grinding, honing, and lapping. The article concludes with a discussion on drilling operations in automatic bar and chucking machines and drill presses.

Fracture of aluminum alloys can occur due to several failure types and/or fracture morphologies, including overload, intergranular fracture, fatigue, corrosion, and mixed-mode fracture. This article provides a detailed discussion on these failure types and/or fracture morphologies. It also presents the differences between wrought and cast aluminum products.

This article aims to summarize the work on cryogenic strength and toughness and to present the fractography of aluminum alloys. It presents case studies on the importance of understanding the fractography of aluminum alloys and the role of microstructure in the appearance of fractographic features, with variables comprised of in-plane/through-thickness anisotropy, test temperature, heat treatment condition, and the effect of welding.

In high-strength aluminum alloys, stress-corrosion cracking (SCC) is known to occur in ordinary atmospheres and aqueous environments. This article discusses the mechanisms of SCC in aluminum alloys, providing information on two main types of SCC models: those of anodic dissolution based on electrochemical theory and those that involve the stress-sorption theory of mechanical fracture. It reviews three different categories of experiments used to compare SCC performance of candidate materials for service. The categories are tests on statically loaded smooth samples, tests on statically loaded precracked samples, and tests using slowly straining samples. The article describes SCC susceptibility and ratings of SCC resistance for high-strength wrought aluminum products, such as 2xxx, 5xxx, and 7xxx series alloys, aluminum-lithium alloys, and 7xxx alloys containing copper.

This article describes the effects of cyclic fatigue properties on aluminum alloys. It provides a discussion on strain-control fatigue and the effects of two microstructural features on the strain life of aluminum alloys: shearable precipitates and precipitate-free zones. The article discusses various models of fatigue crack growth (FCG) and the effects of alloy microstructure and composition on FCG.

Aluminum alloys are widely used in engineered components because of their excellent strength-to-weight ratio. Their use in applications requiring wear resistance is more limited. One of the main limitations of aluminum alloys is the poor tribological behavior mainly due to their relatively low hardness, which favors large plastic deformation under sliding conditions. This article discusses the classes and mechanisms of wear in aluminum-silicon alloys, aluminum-tin bearing alloys, and aluminum-matrix composites; describes the effect of material-related parameters on wear behavior of these alloys; and reviews their applications in a variety of tribological applications in the automotive industry ranging from aluminum-tin alloys for plain bearings to alloys with hard anodizing for machine elements. Methods to improve wear resistance and alloy hardness are also discussed.

This article discusses the concepts underlying linear elastic fracture mechanics and elastic-plastic fracture mechanics as well as their importance in characterizing the fracture behavior of the high-strength aluminum alloys. It describes the three methods used for analyzing elastic-plastic fracture, namely R-curve concept, J-integral concept, and crack tip opening displacement method. The article considers the primary measures used to assess the toughness of aluminum alloy castings and wrought alloys: notch toughness, tear resistance, and plane-strain fracture toughness.

Investment casting, in which molten metal is poured into hot molds, allows for the production of aluminum parts with extremely thin sections, knife edges and sharp detail. This article describes the various steps in the investment casting process, including patternmaking and dimensioning, the design and manufacture of shell molds, melting and casting methods, and postcasting operations such as knockout, core removal, and cleaning. It also addresses a wide range of design considerations, discusses casting defects, and provides several design examples.

This article summarizes a typical solution and aging heat treatments of 2xxx (Al-Cu), 6xxx (Al-Mg-Si), and 7xxx (Al-Zn-Mg) wrought alloys. It discusses the general aging characteristics and the effects of reheating of aluminum alloys. Typical examples of hardness and conductivity values for various aluminum alloy tempers are listed in a table. The article also describes the age hardening of Al-Cu (Mg) alloys, Al-Mg-Si alloys, and Zn-Mg-(Cu) aluminum alloys.

This article examines aluminum forging processes, including open-die, closed-die, upset, roll, orbital, spin, and mandrel forging, and compares and contrasts their capabilities and the associated design requirements for forged parts. It discusses the effect of key process variables such as workpiece and die temperature, strain rate, and deformation mode. The article describes the relative forgeability of the ten most widely used aluminum alloys, and reviews common forging equipment, including hammers, mechanical and screw presses, and hydraulic presses. It also discusses postforge operations such as trimming, forming, repairing, cleaning, and heat treatment.

Brazing technology is continually advancing for a variety of metals including aluminum and its alloys and nonmetals. This article discusses the key physical phenomena in aluminum brazing and the materials for aluminum brazing, including base metals, filler metals, brazing sheet, and brazing flux. It describes various aluminum brazing methods, such as furnace, vacuum, dip, and torch brazing. Friction, flow, induction, resistance, and diffusion brazing are some alternate brazing methods discussed. The article reviews the brazing of aluminum to ferrous alloys, aluminum to copper, and aluminum to other nonferrous metals. It also discusses post-braze processes in terms of post-braze heat treatment and finishing. The article concludes with information on the safety precautions considered in brazing aluminum alloys.