This article summarizes the Sendzimir process, the Cook-Norteman process, the coating types, composition, characteristics, and typical applications of various metallic coatings, such as zinc, aluminum, zinc-aluminum alloy, and aluminum-zinc alloy coatings. It provides a discussion on aqueous corrosion and atmospheric corrosion of galvanized steel and aluminized steel, as well as the intergranular corrosion of galvanized steel.

This article describes the widespread use of diffusion coatings for elevated-temperature protection of the turbine components for aircraft engines and gas turbines. The principles of pack diffusion coating, namely, aluminizing, chromizing, and siliconizing, are discussed. The article presents information on the coating formation mechanism of superalloys and explains the steps involved in a typical pack cementation process. It concludes with information on the processing procedures and properties of pack aluminized steels.

Porcelain enamels are glass coatings applied primarily to products or parts made of sheet steel, cast iron, and aluminum to improve appearance and to protect the metal surface. This article describes the types of porcelain enamels, and details enamel frits for these materials. It provides a list of steels suitable for porcelain enameling and discusses the most important factors considered in the selection of steel for porcelain enameling. The article briefly presents the preparation methods of these materials for porcelain enameling and covers the methods, and furnaces of porcelain enameling. It examines the role of coating thickness, firing time and temperature, metal substrate, and color on the performance of enameled surfaces. The article concludes with a discussion on the properties of enameled surfaces, factors considered in process control, and test procedures for evaluating the quality of enameled surfaces.

Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.

This article presents a detailed account on the process flow, composition, alternative sources, and the advancement of ironmaking, steelmaking and secondary steelmaking practices. Some steels, such as bearing steels, heat-resistant steels, ultrahigh strength missile and aircraft steels, and rotor steels have higher quality requirements and tighter composition control than plain carbon or ordinary low-alloy steels. The production of special-quality steels requires vacuum-based induction or electric remelting and refining capabilities. The article explores the types and characteristics of various steel manufacturing processes, such as ingot casting, continuous casting, and hot rolling. It provides an outline of specialized processing routes of producing ultralow plain carbon steels, interstitial-free steels, high strength low-alloy steels, ultrahigh strength steels, stainless steels, and cold-rolled products, and briefly explains the analytical techniques for liquid steels.

Low-carbon steel sheet and strip are used primarily in consumer goods. This article discusses quality descriptors and mechanical properties of low-carbon steel sheet and strip and carbon and low-alloy steel plate. Alloy steel sheet and strip are used primarily for those special applications that require the mechanical properties normally obtained by heat treatment. Steel sheet is coated in coil form before fabrication either by the steel mills or by specialists called coil coaters. Porcelain enamels are glass coatings applied primarily to products or parts made of sheet steel, cast iron, or aluminum to improve appearance and to protect the metal surface.

Hot-rolled steel bars and other hot rolled steel shapes are produced from ingots, blooms, or billets converted from ingots, or from strand cast blooms and billets, and comprise a variety of sizes and cross sections. This article provides a brief discussion on mechanical properties, quality descriptors and chemical compositions of hot-rolled steel bars, cold-finished steel bars, steel wire rod and steel wire. It contains tables that provide size tolerances for cold-finished carbon steel bar and cold-finished alloy steel bar.

This article discusses the most common methods of melting steels, namely, electric arc and induction melting. It describes the classification of refractories by an index of the “basicity” of the slag formed on the steel surface. The steel melt refinements are classified as treatments by either converter metallurgy or ladle metallurgy. The article provides a detailed discussion on the converter and ladle metallurgy. The converter metallurgy includes melt refinement in argon oxygen decarburization (AOD) vessels and vacuum oxygen decarburization (VODC) in a converter vessel. The ladle metallurgy includes vacuum induction degassing, vacuum oxygen decarburization, and vacuum ladle degassing.

There are various coating techniques in practice to prevent the deterioration of steels. This article focuses on dip, barrier, and chemical conversion coatings and describes hot-dip processes for coating carbon steels with zinc, aluminum, lead-tin, and other alloys. It describes continuous electrodeposition for steel strip and babbitting and discusses phosphate and chromate conversion coatings as well. It also addresses painting, discussing types and selection, surface preparation, and application methods. In addition, the article describes rust-preventive compounds and their application. It also provides information on weld-overlay and thermal spray coating, porcelain enameling, and the preparation of enamel frits for steels. The article closes by describing methods and materials for ceramic coating.

This article provides information on the salt baths used for a variety of heat treatments, including heating, quenching, interrupted quenching (austempering and martempering), case hardening, and tempering. It describes two general types of salt bath systems for steel hardening: the first type uses atmosphere austenitizing followed by salt quench and the second type employs austenitizing salt baths with rapid transfer to the quench salt. The article provides a detailed account on the construction, advantages and disadvantages, and limitations of isothermal quenching furnaces, submerged-electrode furnaces, immersed-electrode furnaces, and externally heated furnaces. It discusses the important applications of various furnace designs, including the austempering of ductile iron, the hardening of tool steels, and the isothermal annealing of high-alloy steels.

This article presents information regarding the use of protective coatings in municipal potable water systems, including raw water collection and transmission, water treatment plants, and treated water distribution. It provides useful guidance for the selection and use of protective coatings in these municipal water systems. The most commonplace corrosion-damage mechanisms are highlighted. The article describes the most common materials of construction found in municipal water systems, namely, cast iron, ductile iron, carbon steel, precast concrete cylinder pipe and reinforced concrete pipe, prestressed concrete tanks, and stainless steel. It provides information on the most common generic coating systems used for new steel tanks and water storage tanks. It concludes with a discussion of quality watch-outs when selecting or using protective coatings in municipal water systems.

This article lists functions of lubricants common to the majority of applications and processes. It discusses the lubricant candidates widely used in forging: conversion coatings with soaps (stearate compounds) and molybdenum disulfide for cold forging; oil-based thick, film oil or polymerbased lubricants and molybdenum disulfide for warm application; graphite suspensions in oil or water for hot forging steels; and glass films for titanium and superalloys hot forgings. The article describes the applications of lubricants in warm extrusion and forging, hot forging of steel, hot forging of aluminum, isothermal and hot die forging, and the extrusion of steel.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of ASTM/ASME alloy steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the solidification cracking, creep failure, brittle fracture, fracture by overpressurization, inclusion effect, fatigue crack propagation, ductile fatigue striation, secondary cracking, intergranular fracture, and elevated-temperature fracture of alloy steels used in pressure vessels, steam boiler superheater tubes, and box-girder bridges.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of low-carbon steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: the intergranular fracture, bending impact fracture, brittle fracture, tensile-test fracture, transgranular fracture, cleavage fracture, delayed fracture, corrosion fatigue, inclusion morphology, fatigue crack propagation, and in-service fatigue fracture of various automotive components. These components include tie rod adjusting sleeves, automotive bolts, hydraulic jack shafts, crank handle collars, boiler tubes, drive shafts, bicycle pedal axles, lift-truck hydraulic-piston rods, and steel springs.

This article focuses on the recycling of metals including iron and steel, stainless steel, superalloys, nickel, aluminum, copper, precious metals, lead, magnesium, tin, titanium, and zinc. It provides information on the identification and sorting of scrap metals and discusses the equipment and procedures used for small-scale and large-scale scrapping operations.

This article discusses the classifications, compositions, properties, advantages, disadvantages, limitations, and applications of the most commonly used methods for surface engineering of carbon and alloy steels. These include cleaning methods, finishing methods, conversion coatings, hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment.

This article addresses two issues on thermodynamics, namely, the calculation of solubility lines and the calculation of the activity of various components. It discusses alloying elements in terms of their influence on the activity of carbon. The article describes the desulfurization and deoxidation of cast iron and steel. It illustrates the thermodynamics of the iron-carbon system and the iron-silicon system. The article examines solubility and saturation degrees of carbon in multicomponent iron-carbon systems. One of the main applications of the thermodynamics of the iron-carbon system is the calculation of structure-composition correlations. The article concludes with information on the structural diagrams, such as Maurer diagram and Laplanche diagram, for cast iron.

Autoclave molding is a process used to impart a controlled heat and pressure cycle cure to a layup. This article describes the materials used for preparing a layup, including peel ply, separator, bleeder, barrier, breather, dam, and vacuum bag. It describes the major elements and functions of an autoclave system, including pressure vessel, gas stream heating and circulation sources, gas stream pressurizing systems, vacuum systems, control systems, and loading systems. The article includes information about modified autoclaves for specialized applications and safety practices in autoclave molding. It also describes the tooling configuration and type of tooling which includes aluminum and steel tooling, electroformed nickel tooling, graphite-epoxy tooling, and elastomeric tooling.

This article provides an overview of exogenous and indigenous inclusions. It discusses the general concepts of phase diagrams, thermochemical relationships, and reaction rates, along with their practical significance. The article describes the most common techniques for controlling the occurrence of inclusions in any cast metal. The article provides a discussion on the inclusions in ferrous and nonferrous alloys. The ferrous and nonferrous alloys include steels, cast irons, aluminum alloys, copper alloys, and magnesium alloys.

Portland cement concrete has low environmental impact, versatility, durability, and economy, which make it the most abundant construction material in the world. This article details the types and causes of concrete degradation. Concrete can be degraded by corrosion of reinforcing steel and other embedded metals, chlorides, carbonation, galvanic corrosion, chemical attack, alkali-aggregate reaction, abrasion, erosion, and cavitation as well as many other factors. The article addresses the durability of concrete by two approaches, namely, the prescriptive approach and the performance approach. In the former, designers specify materials, proportions, and construction methods based on fundamental principles and practices that exhibit satisfactory performance. In the latter, designers identify functional requirements such as strength, durability, and volume changes and rely on concrete producers and contractors to develop concrete mixtures to meet those requirements.