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alkaline etching
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Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006489
EISBN: 978-1-62708-207-5
... Abstract Etching aluminum can be a pretreatment step for anodizing, chemical conversion coating, metal-to-rubber bonding, and a host of other processes. Chemical etching, using either alkaline or acid solutions, produces a matte finish on aluminum products. This article describes the alkaline...
Abstract
Etching aluminum can be a pretreatment step for anodizing, chemical conversion coating, metal-to-rubber bonding, and a host of other processes. Chemical etching, using either alkaline or acid solutions, produces a matte finish on aluminum products. This article describes the alkaline etching and acid etching of aluminum. Alkaline etching reduces or eliminates surface scratches, nicks, extrusion die lines, and other imperfections. Acid etching can be done without heavy smut problems, particularly on aluminum die castings. Hydrochloric, hydrofluoric, nitric, phosphoric, chromic, and sulfuric acids are used in acid etching. The article presents a flow chart of the operations used in acid etching.
Image
Published: 31 August 2017
Fig. 21 Same as in Fig. 20 but after etching with hot alkaline sodium picrate. L, ledeburite; C, eutectic cementite; F, ferrite; and P, pearlite with slightly etched cementite. Original magnification: 650× (microscopic magnification: 500×)
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Image
Published: 31 August 2017
Fig. 28 Same as in Fig. 27 but after etching with hot alkaline sodium picrate. F, ferrite (unaffected); C, cementite; IP, iron phosphide + ferrite; and TiN, titanium nitride. Original magnification: 1300× (microscopic magnification: 1000×)
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Image
Published: 31 August 2017
Fig. 34 Same as in Fig. 33 but after etching with hot alkaline sodium picrate and 4% nital. Pearlitic matrix is revealed; phosphorus eutectic is unaffected. Original magnification: 500×
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Image
Published: 01 December 2004
Fig. 17 Same as in Fig. 16 but after etching with hot alkaline sodium picrate. C, eutectic cementite; L, ledeburite; F, ferrite; and P, pearlite with slightly etched cementite. 650× (microscopic magnification 500×)
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Image
Published: 01 December 2004
Fig. 24 Same as in Fig. 23 but after etching with hot alkaline sodium picrate. C, cementite; F, ferrite (unaffected); IP, iron phosphide + ferrite; and TiN, titanium nitride. 1300× (microscopic magnification 1000×)
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Image
Published: 01 December 2004
Fig. 30 Same as in Fig. 29 but after etching with hot alkaline sodium picrate and 4% nital. Pearlitic matrix is revealed; phosphorous eutectic is unaffected. 500×
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Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
..., and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating...
Abstract
Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.
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Published: 01 January 1994
Fig. 5 Operations sequence in sulfuric acid anodizing of architectural parts Solution No. Type of solution Composition Operating temperature Cycle time, min °C °F 1 Alkaline cleaning Alkali, inhibited 60–71 140–160 2–4 2 Alkaline etching NaOH, 5 wt% 50–71 120
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Published: 01 January 1994
Fig. 1 Effect of time on the amount of metal removed from aluminum alloys during alkaline etching. (a) By micrometer measurement. (b) Calculated from loss in weight. Both solutions contain 5 wt% NaOH at 70 ± 5 °C (160 ± 5 °F).
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Image
Published: 30 November 2018
Fig. 1 Effect of time on the amount of metal removed from aluminum alloys during alkaline etching. (a) By micrometer measurement. (b) Calculated from loss in weight. Both solutions contain 5 wt% NaOH at 70 ± 5 °C (160 ± 9 °F).
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Image
Published: 01 December 2004
Fig. 19 High-carbon tool steel etched with boiling alkaline sodium picrate to color the cementite. Note the lighter-colored carbides in the segregation streak. These probably contain a small amount of molybdenum, present in this steel.
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Image
Published: 01 December 2004
Fig. 6 AISI W2 (1.05% C), spheroidize annealed. (a) Etched with boiling alkaline sodium picrate for 60 s to color the cementite brown. (b) Etched lightly with 4% picral and tint etched with Beraha's Na 2 S 2 O 3 /K 2 S 2 O 5 reagent to color the ferrite (wide range of colors). (c) Etched
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001221
EISBN: 978-1-62708-170-2
..., hydrochloric acid dip, rinse Vapor degrease Phosphoric acid etch Vapor degrease Cold solvent dip Alkaline spray Alkaline dip, rinse, dry or dip in rust preventative Continuous high production Automatic vapor degrease Automatic vapor degrease Emulsion power spray, rinse Automatic vapor...
Abstract
This article describes the basic attributes of the most widely used metal surface cleaning processes to remove pigmented drawing compounds, unpigmented oil and grease, chips, cutting fluids, polishing and buffing compounds, rust and scale from steel parts, and residues and lapping compounds from magnetic particle and fluorescent penetrant inspection. The cleaning processes include emulsion cleaning, electrolytic alkaline cleaning, acid cleaning, solvent cleaning, vapor degreasing, alkaline cleaning, ultrasonic cleaning, and glass bead cleaning. The article provides guidelines for choosing an appropriate process for particular applications and discusses eight well-known methods for determining the degree of cleanliness of the work surface.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001281
EISBN: 978-1-62708-170-2
... Steam, cooked foods (j) Voice transmitter 50 mm diam 2 in. diam 5052-O Burnish, alkaline etch Sulfuric acid Dye, seal (k) Gas mask Wheel pistons Up to 5200 mm 2 area Up to 8 in. 2 area 6151 Machine Sulfuric acid (l) Seal Wear and corrosion (m) Computer chip hat 160 by 160...
Abstract
Anodizing refers to conversion coating of the surface of aluminum and its alloys to porous aluminum oxide. This article provides the reasons for performing anodizing and discusses the three principal types of anodizing processes, namely, chromic acid process, sulfuric acid process, and hard anodic process. It describes the limitations imposed by variables, such as alloy composition, surface finish, prior processing, temper or heat treatment, and the use of inserts, on the anodizing processes. The article explains the causes and means adopted for correcting several specific problems in anodizing aluminum. It also discusses the process control techniques and equipment used for anodizing. The article reviews the sealing processes for anodic coatings and the method for coloring the coatings. It concludes with a discussion on the effects of anodic coatings on the surface and mechanical properties of aluminum and its alloys.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003680
EISBN: 978-1-62708-182-5
... for conversion coating, metal deposition, and organic coating as well as for anodizing, and typical etching and polishing processes are listed in Table 2 . Both acid etching and alkaline etching are possible, and the latter requires a posttreatment of “desmutting” in a nitric acid solution. Electrograining...
Abstract
Anodizing is one of the most common surface treatments of aluminum and is performed for corrosion protection. This article describes the structure and growth characteristics of the types of anodic oxide films such as a barrier-type oxide film and a porous-type anodic oxide film. It discusses each step involved in the anodizing process of an aluminum or aluminum alloy specimen. The anodizing process includes pretreatments (degreasing, etching, and polishing), anodizing, coloring, and sealing. The article provides an observation of the morphology of the anodic oxide films by transmission electron microscopy and the scanning electron microscopy for testing properties of anodic oxide films.
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Published: 01 January 1994
3.5 82 180 3–10 Sulfuric acid 18.0 3 Chromate dip Chromic sulfate 0.2 Ambient 1–6 Potassium dichromate 14.4 Sodium hydroxide 7.75 (a) Vapor degreasing may be used instead of alkaline cleaning. (b) Either inhibited or mildly etching (uninhibited) cleaners can
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Image
Published: 01 January 1994
3.5 82 180 3–10 Sulfuric acid 18.0 … … … 3 Chromate dip Chromic sulfate 0.2 Ambient Ambient 1–6 Potassium dichromate 14.4 … … … Sodium hydroxide 7.75 … … … (a) Vapor degreasing may be used instead of alkaline cleaning. (b) Either inhibited or mildly etching
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Image
in Fractography of Ancient Metallic Artifacts, and Restoration and Conservation Aspects
> Fractography
Published: 01 June 2024
Fig. 25 Optical metallographs from a kabuto sample showing (a) coarse slag (nital etch) and (b) grain-boundary cementite films (alkaline sodium picrate etch). Courtesy of George Vander Voort, Vander Voort Consulting LLC, Wadsworth, IL
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003221
EISBN: 978-1-62708-199-3
... preliminary treatments also are helpful in specific instances, particularly for cast aluminum parts. One of these pretreatments entails etching the castings for 20 s in an alkaline solution at 82 °C (180 °F) and then dipping them for 2 to 3 s in a solution consisting of (by volume) 3 parts nitric acid (36...
Abstract
This article discusses surface engineering of nonferrous metals including aluminum and aluminum alloys, copper and copper alloys, magnesium alloys, nickel and nickel alloys, titanium and titanium alloys, zirconium and hafnium, zinc alloys, and refractory metals and alloys. It describes various techniques to improve functional surface properties and enhance the appearance of product forms. The article discusses various cleaning and finishing techniques such as abrasive blast cleaning, polishing and buffing, barrel burnishing, chemical cleaning, pickling, etching and bright dipping, electrochemical cleaning, mechanical cleaning, and mass finishing. It also examines coating processes such as plating, anodizing, chemical conversion coating, and thermal spray, and concludes with a discussion on oxidation-resistant coatings for refractory metals.
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