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Published: 31 December 2017
Fig. 4 Adhesion and surface energy of contacting materials: atomically clean diamond, atomically clean sapphire, diamond with adsorbed species, and sapphire with adsorbed species in contact with atomically clean aluminum in ultrahigh vacuum (10 −8 Pa). Δγ: the surface energy difference More
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001348
EISBN: 978-1-62708-173-3
... based on theoretical analysis. A discussion on the properties affecting adhesion is also provided. adhesion adhesion energy bonding grain boundary energy interfacial characterization interfacial energy mechanical properties metal adhesion metal-to-ceramic adhesion solid-state welding...
Book Chapter

Series: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003280
EISBN: 978-1-62708-176-4
... liquid films ( Ref 15 , 16 ), and the friction between two molecularly smooth solids ( Ref 17 ). Thermodynamic Adhesion Thermodynamic adhesion refers to the change in free energy when an interface is formed or separated. This concept of adhesion is defined in terms of surface energy, interfacial...
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005412
EISBN: 978-1-62708-196-2
... that the SUs model well describes the interface structure. For such interfaces, one may expect high adhesion between the two crystals and the presence of sharp energy minima for LEORs ( Ref 2 ). The principal question is: Under what conditions is this model of the interface structure applicable at all...
Book Chapter

By Lawrence T. Drzal
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003374
EISBN: 978-1-62708-195-5
... Abstract Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy...
Image
Published: 01 December 2009
Fig. 13 The work of adhesion and factors decreasing adhesion. (a) Bonded interface. (b) Cleaved interface and dangling bonds. (c) Decrease of free surface energy and adhesion due to chemical reactions at the surfaces. (d) Decrease of free surface energy and adhesion due to segregation More
Book Chapter

By K.L. DeVries, Paul Borgmeier
Series: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003324
EISBN: 978-1-62708-176-4
... of fracture mechanics (see the section “Adhesive Fracture Mechanics Tests” in this article) to obtain critical information and insight into the behavior of adhesive joints ( Ref 12 , 13 ). The peel specimen is, in principle, a very versatile geometry for obtaining adhesive fracture energy because various...
Book Chapter

By Tao Xu, Jennifer Hoffman, Suresh Donthu
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005672
EISBN: 978-1-62708-198-6
... (UV) light, visible light, gamma, or electron beam. The reaction is usually a free-radical addition type. A photo initiator is usually present in the adhesive formulation to absorb the irradiation energy and generate free radicals, which are highly reactive species. Irradiation-cured adhesives include...
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006379
EISBN: 978-1-62708-192-4
... Work of Adhesion A thought experiment has been used to define the work of cohesion of a solid as twice the surface energy (because two surfaces are created) or interfacial energy, as appropriate. If a similar experiment were done in which two different materials were separated from contact...
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006375
EISBN: 978-1-62708-192-4
... and surface energy ( Ref 33 ) by a factor of 22 with an aluminum-diamond couple and by a factor of 13 with an aluminum-sapphire couple. Thus, contamination is an important factor in determining such solid surface properties as adhesion in vacuum environments. Contaminant layers can greatly reduce adhesion...
Image
Published: 31 October 2011
Fig. 6 Schematic illustration of the various mechanisms that can lead to adhesion during adhesive bonding, that is, (a) mechanical interlocking of adhesive into microscopic surface asperities, (b) secondary bonding from adsorption with proper wetting from surface energy effects, (c More
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001286
EISBN: 978-1-62708-170-2
... 2 on Fe 3.0 Ni on Mo 2.1 Ag on Mo 1.5 Au on W 3.0 O 2 on Mo 7.5 Note: 1 eV/atom = 23 kcal/mole. Source: Ref 8 The bonding between a metal atom and an oxide surface is proportional to the metal-oxygen free energy of formation, with the best adhesion produced...
Book Chapter

By Om S. Kolluri
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001319
EISBN: 978-1-62708-170-2
... that is merely resting on the surface. In addition, increasing the surface energy of the substrate above the surface tension of the adhesive makes it possible for the adhesive to wet the entire surface of the polymer substrate. The increase in the apparent surface area of contact increases the strength...
Image
Published: 31 December 2017
by indenting hard asperities of contacting bodies or hard particles (microcutting, microplowing, microcracking). (c) Adhesion. Formation and rupture of adhesive interfacial cold weld spots, materials transfer, and generation of wear debris. (d) Tribochemical reaction. Chemical materials/atmosphere/lubricant More
Book Chapter

By Jim Kindinger
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003375
EISBN: 978-1-62708-195-5
... honeycomb: adhesive bonding and expansion, corrugation and adhesive bonding, corrugation and braze welding, and extrusion. The article describes cell configuration and properties of honeycomb. It discusses the factors influencing specification of structural cores, including materials, size, density...
Image
Published: 15 January 2021
Fig. 19 Evolution of fretting wear rate increase with applied sliding amplitude for an adhesive wear Ti-6Al-4V interface. (a) Basic friction energy approach. (b) Extended friction energy approach (results normalized versus a reference test condition: α n = α/α ref ; δ S,n = δ S /δ S,ref More
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003043
EISBN: 978-1-62708-200-6
... no solvents, chemical fumes, disposal problems, or heat that could harm the plastic surface. The plasma reacts to a depth of 0.01 to 0.1 μm ( Ref 8 ). The effect of plasma treatment is to reduce the contact angle (a function of surface energy) of the surface to which adhesive will be applied. This reduction...
Book Chapter

By Janet Devine
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005607
EISBN: 978-1-62708-174-0
... Abstract Ultrasonic metal welding is a solid-state welding process that produces coalescence through the simultaneous application of localized high-frequency vibratory energy and moderate clamping forces. This article discusses the parameters to be considered when selecting a suitable welder...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003021
EISBN: 978-1-62708-200-6
... factors: the chemical nature of the polymer, the surface free energy, the surface topography, and contamination of the polymer surface by dust, oil, and grease. These factors markedly affect the effectiveness of the adhesive and solvent bonding methods. Fusion welding, however, is much more tolerant...
Book Chapter

By Robert W. Messler, Jr.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005551
EISBN: 978-1-62708-174-0
... with proper wetting from surface energy effects, (c) electrostatic attraction from charge separation or polarization, and (d) diffusion of some atoms or molecules back and forth between adhesive and adherends. Also, (e) the formation of a weak boundary layer that can lead to the adhesive failure of joints...