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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001317
EISBN: 978-1-62708-170-2
... provides information on catalyst powder processing. active carriers beading catalyst catalyst powder processing catalyst preparation chemical activity chemical process extrusion honeycombing impregnation inert carriers ion exchange precipitation spray drying tableting A CATALYST...
Abstract
The chemical process being catalyzed should have a high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the general catalyst preparation procedures, namely, impregnation, ion exchange, and precipitation. Catalyst carriers are usually high-surface-area inorganic materials with complex pore structures, into which catalytic materials such as palladium, platinum, cobalt, chromium oxide, and vanadium pentoxide are deposited using these procedures. The article also provides information on catalyst powder processing.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001747
EISBN: 978-1-62708-178-8
... carrier gas. This article describes the operating principles and sample selection of inert gas fusion. It explains the mechanisms involved in the introduction of fusion gas, separation and detection of fusion gas by thermal-conductive and infrared detection methods. Additionally, the article explains...
Abstract
Inert gas fusion is a method of determining the quantitative content of gases in ferrous and nonferrous materials where gases, such as hydrogen, nitrogen, and oxygen, are physically and chemically adsorbed by the materials and later removed and swept by from the fusion area by an inert carrier gas. This article describes the operating principles and sample selection of inert gas fusion. It explains the mechanisms involved in the introduction of fusion gas, separation and detection of fusion gas by thermal-conductive and infrared detection methods. Additionally, the article explains the methods used for analyzing trace amounts of nitrogen, oxygen, and hydrogen in the carrier mediums, providing examples that aid in solving several problems.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003218
EISBN: 978-1-62708-199-3
... such as aluminum oxide. A halide salt activator is added that changes to the vapor phase at the processing temperature and serves as a carrier gas to bring chromium to the surface of the part. Diffusion coatings can be formed on nickel-base superalloys by pack cementation using ammonium chloride as a chromium...
Abstract
Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005799
EISBN: 978-1-62708-165-8
... to sustain a carburizing atmosphere that proceeds in the forward direction. ( Ref 3 ). Gas carburizing atmospheres are often generated by enriching an endothermic carrier gas with methane. The carburizing potential of endothermic gas without hydrocarbon enrichment is not sufficient to produce significant...
Abstract
This article describes the thermodynamics and kinetics of gas carburizing reactions, and details the mass transfer mechanism during gas carburizing. It discusses the various considerations involved in carburizing process planning, and reviews successful operation of the gas carburizing process based on the control of three principal variables: temperature, atmosphere composition or carbon potential, and time. The article also describes the selection criteria for alloy, carbon sources, atmosphere types, and carbon monoxide level for endothermic carburizing atmospheres. It provides information on carburizing modeling, case depth prediction, case depth measurement, and case depth evaluation as well as on carburizing equipment, and also covers the factors affecting distortion after carburizing.
Book Chapter
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005775
EISBN: 978-1-62708-165-8
...-rich coating, and many of the same principles of aluminizing packs apply to chromizing packs. Parts are packed in chromium powder with an inert filler such as aluminum oxide. A halide salt activator is added that changes to the vapor phase at the processing temperature and serves as a carrier gas...
Abstract
Pack cementation is the most widely employed method of diffusion coating. This article briefly reviews pack cementation processes of aluminizing, chromizing, and siliconizing. It contains tables that list typical characteristics of pack cementation processes and commercial applications of pack cementation aluminizing, which is used to improve the performance of steels in high-temperature corrosive environments.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003361
EISBN: 978-1-62708-195-5
... former name, New England Butt, and now called Wardwell Braiding Machine Company), which manufactures braiders ranging from three-carrier to 144-carrier models. There are a number of braid manufacturers actively producing braided preforms and/or developing braided composites. A sample list...
Abstract
Braided structures are unique in their high level of conformability, torsional stability, and damage resistance. This article describes the classifications of braiding such as two-dimensional braiding and three-dimensional braiding. It presents the governing equations for computer-controlled braiding in a table. The article lists the applications of braided fabrics and composites. It discusses the formation, structure, and properties of two-dimensional braid composites and three-dimensional braid composites: the damage tolerance and the impact damage limitation.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003035
EISBN: 978-1-62708-200-6
... the chopper in Fig. 1 ), which meters a specified amount of resin filler paste onto a plastic carrier film. The paste consists of several ingredients, which can be changed to fit the particular needs of specific processing conditions and applications. The carrier film passes under a chopper, which cuts glass...
Abstract
Sheet molding compounds (SMCs) refers to both material and process for producing glass-fiber-reinforced polyester resin items. This article discusses the material components incorporated into the resin paste for desirable processing and molding characteristics and optimum physical and mechanical properties, including catalyst, fillers, thickeners, pigments, thermoplastic polymers, flame retardants, and ultraviolet absorbers. It talks about the mixing techniques available for SMC resin pastes, including batch, batch/continuous, and continuous mixing. The article also outlines the design features and the operations of continuous-belt and beltless machine type SMCs.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001245
EISBN: 978-1-62708-170-2
... to a separate treatment tank where it is treated with activated carbon, filtered, and returned to the main tank.) The stress-reducing property of carriers is increased if they contain amido or imido nitrogen. For example, saccharin is a most effective stress reducer and often helps to decrease or eliminate...
Abstract
This article discusses the process considerations and deposit properties of nickel plating. It describes the Watts solution and the anode materials used. The article focuses on the nickel plating processes used for decorative, engineering, and electroforming purposes. It provides information on the quality control of nickel plating. It concludes with a review of the environmental, health, and safety considerations associated with nickel plating.
Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005244
EISBN: 978-1-62708-187-0
.../ester Phenolic urethane/amine Polyolisocyanate Alumina phosphate The cold box and heat-cured (heat-activated) processes lend themselves exceptionally well to medium- and high-production applications. Examples of high-production operations are foundries that cast automotive, pipe fitting...
Abstract
Cores are separate shapes of sand that are placed in the mold to provide castings with contours, cavities, and passages that are not otherwise practical or physically obtainable by the mold. This article describes the basic principles of coremaking and the types of core sands, binders, and additives used in coremaking. It discusses the curing of compacted cores by core baking and the hot box processes. The article provides an overview of the core coatings, assembling and core setting, coring of tortuous passages, and cores in permanent mold castings and investment castings. It also discusses the design considerations in coremaking to eliminate cores and compares coring with drilling.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001460
EISBN: 978-1-62708-173-3
... are unable to activate at lower working temperatures, there can be some wetting difficulties when indium-tin alloys are used. Indium-base alloys can wet several ceramic materials, including quartz, and some glasses. However, they can be susceptible to corrosion damage, and have poor mechanical properties...
Abstract
Soldering represents the primary method of attaching electronic components, such as resistors, capacitors, or packaged integrated circuits, to either printed wiring board whose defects is minimized by consideration of proper PWB design, device packages, and board assembly. This article discusses the categories that are most important to successful electronic soldering, namely, solders and fluxes selection, nature of base materials and finishes, solder joint design, and solderability testing.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006670
EISBN: 978-1-62708-213-6
... perspective, semiconductors form the active material components of structures whose electrical behavior, such as resistance, can be controlled through external stimulation, such as the gate voltage applied to a metal-oxide-semiconductor field-effect transistor (MOSFET) or visible light illumination...
Abstract
This article introduces various techniques commonly used in the characterization of semiconductors, namely single-crystal, polycrystalline, amorphous, oxide, organic, and low-dimensional semiconductors and semiconductor devices. The discussion covers material classification, fabrication methods, sample preparation, bulk/elemental characterization methods, microstructural characterization methods, surface characterization methods, and electronic characterization methods.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001401
EISBN: 978-1-62708-173-3
... soldering; larger packages (e.g., leaded or leadless chip carriers) may be damaged by exposure to the harsh environments (flux and molten solder) as well as be more prone to solder defects ( Ref 1 ). The wave soldering technique encompasses a sequence of processes, all of which are typically contained...
Abstract
This article focuses on the design considerations and process parameters critical to the successful implantation of wave soldering on printed circuit boards. The design considerations include the through-hole technology and the surface-mount technology. The article presents information on process parameters, which can be divided into three groups: the fluxing operation, solder wave properties, and process schedule. It provides information on various solder defects.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006661
EISBN: 978-1-62708-213-6
... the relative surface coverage of cesium chemisorbed on tungsten. An adsorbed species can be bound to a surface by van der Waals forces (physisorption) and by covalent bonding (chemisorption). At a characteristic temperature, adsorbates begin to desorb from the surface via an activated process. Knowledge...
Abstract
This article focuses on the principles and applications of thermal desorption spectroscopy (TDS) use to study adsorption, desorption, and reaction of adsorbed atoms and molecules on surfaces. The discussion provides information on various components of and specimen preparation processes for a TDS experiment. The factors that must be considered when performing TPD experiments and several methods of analyzing TPD data are covered. A few studies where TPD was used to elucidate surface reactions that impact the tribological performances of materials are also discussed.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004032
EISBN: 978-1-62708-185-6
... stable up to 200 °C (390 °F) and lose their function under more severe forging conditions. When solid lubricants are used, the phosphate coating only serves as the porous carrier with physical bonding characteristics. When forming high-alloy steels (e.g., stainless), oxalate conversion coatings are used...
Abstract
This article lists functions of lubricants common to the majority of applications and processes. It discusses the lubricant candidates widely used in forging: conversion coatings with soaps (stearate compounds) and molybdenum disulfide for cold forging; oil-based thick, film oil or polymerbased lubricants and molybdenum disulfide for warm application; graphite suspensions in oil or water for hot forging steels; and glass films for titanium and superalloys hot forgings. The article describes the applications of lubricants in warm extrusion and forging, hot forging of steel, hot forging of aluminum, isothermal and hot die forging, and the extrusion of steel.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005300
EISBN: 978-1-62708-187-0
... fluxes may be a blend of an inert and a chemically active gas that is injected into the molten bath. Solid fluxes are blends of salts, which, at the present time (2008), are the most preferred type of fluxes used in foundries, especially since gaseous mixtures with chlorine have been almost completely...
Abstract
Aluminum fluxing is a step in obtaining clean molten metal by preventing excessive oxide formation, removing nonmetallic inclusions from the melt, and preventing and/or removing oxide buildup on furnace walls. This article discusses the solid fluxes and gas fluxes used in foundries. It reviews the classification of solid fluxes depending on their use and function at the foundry operation. These include cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article also examines the operational practices and applications of the flux injection in the foundries. It describes the applications of the aluminum fluxing such as crucible furnaces, transfer ladles, reverberatory furnaces, and holding/casting furnaces.
Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005251
EISBN: 978-1-62708-187-0
... of the magnetic molding, like other no-bond methods, include the absence of a chemical binder, reductions in dust and noise levels, full mechanization or automation of the process, and the elimination of normally used molding activities (such as ramming and jolting). The increased heat conductivity of the iron...
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001225
EISBN: 978-1-62708-170-2
... polymers and coatings Dissolution of sand, ceramic, and glassy materials Stripping of plasma carbide coatings In addition, molten salt baths may be used to pretreat cast iron surfaces before brazing and bonding operations. Molten salt baths for cleaning applications are chemically active...
Abstract
Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal. It provides an overview of the basic design and safety considerations of the salt bath equipment and describes the environmental impact of molten salt bath cleaning.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006423
EISBN: 978-1-62708-192-4
... hydrochloric and sulfuric acids. After descaling, lubricant carriers are impregnated on the surface followed by applying a lubricant. Fig. 12 Wire surface pretreatment and lubricant coating Nonreactive Lubricant Carriers Lubricant carriers have the propensity to firmly hold lubricant...
Abstract
Drawing is a process by which a workpiece is pulled against a die to produce a wire, bar, or tube with smaller cross sectional area compared with the initial stock. This article discusses the variables that affect the drawing process and the parameters that influence friction, lubrication, and wear. These parameters include process, lubricant, workpiece, and tooling. The article provides information on dry and wet lubrication in wire drawing. The dry lubrication refers to use of solid lubricants while wet lubrication refers to the practice of providing a liquid lubricant to the workpiece-die interface. The article describes the most common types and causes of die wear: abrasive wear, adhesive wear, surface fatigue wear, thermal fatigue wear, and catastrophic failure. It concludes with a discussion on the surface treatment and texturing that are used to reduce die wear in drawing operations.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003189
EISBN: 978-1-62708-199-3
...) or compounded (combined with polar additives and/or chemically active or inactive additives or compounds). They have excellent lubrication properties, good rust control, and long life, but they do not cool as well as water-miscible fluids. Oils can be classified as inactive or active. Inactive Cutting Oils...
Abstract
Cutting fluids play a major role in increasing productivity and reducing costs by making possible the use of higher cutting speeds, higher feed rates, and greater depths of cut. After listing the functions of cutting fluids, this article then covers the major types, characteristics, advantages and limitations of cutting and grinding fluids, such as cutting oils, water-miscible fluids, gaseous fluids, pastes, and solid lubricants along with their subtypes. It discusses the factors considered during the selection of cutting fluid, focusing on machinability (or grindability) of the material, compatibility (metallurgical, chemical, and human), and acceptability (fluid properties, reliability, and stability). The article also describes various application methods of cutting fluids and precautions that should be observed by the operator.
Book Chapter
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002433
EISBN: 978-1-62708-194-8
... objective of LCA is to provide a total life-cycle “big-picture” view of the interactions of a human activity (manufacturing of a product) with the environment. Other major goals are to provide greater insight into the overall environmental consequences of industrial activities and to provide decision makers...
Abstract
Life-cycle engineering is a part-, system-, or process-related tool for the investigation of environmental parameters based on technical and economic measures. This article focuses on life-cycle engineering as a method for evaluating impacts. It describes the four steps of life-cycle analysis, namely, goal definition and scoping, inventory analysis, impact assessment and interpretation, and improvement analysis. The article discusses the applications of life-cycle analysis results and presents a case history of life-cycle analysis of an automobile fender.
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