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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006044
EISBN: 978-1-62708-172-6
... Abstract Acrylic coatings are one of the major generic classes of organic coatings and are prevalent in both architectural and industrial applications. This article provides information on the chemistry of acrylic polymers, the methods used in their manufacture, the relationship between...
Abstract
Acrylic coatings are one of the major generic classes of organic coatings and are prevalent in both architectural and industrial applications. This article provides information on the chemistry of acrylic polymers, the methods used in their manufacture, the relationship between structure and properties when they are formulated into coatings, and how they are being used in coatings. The main discussion points are the differences between solventborne and waterborne technologies and some of the challenges in formulating and applying waterborne acrylic coatings. The article describes the mechanism of film formation of acrylic latex polymers and its effect on final coating properties. It discusses the types of waterborne acrylic latex coatings based on chemical properties and based on applications such as primers, intermediate coats, topcoats, stains, and direct-to-substrate finishes. The article concludes with a description of the advances in the development of waterborne acrylic coatings for maintenance and protective applications.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003048
EISBN: 978-1-62708-200-6
.... It also describes classifications and types, comparing and contrasting sealants made from oil-based caulks, asphalts, coal tar resins, latex acrylic sealants, polyvinyl acetate caulks, solvent acrylics, butyl sealants, polysulfides, polyurethanes, modified silicones, anaerobics, vinyl plastisols...
Abstract
This article is an informative primer on sealants and the role they play in engineered assemblies. It discusses the physical, thermal, chemical, and electrical properties of sealant materials and the various forms in which they are applied, including liquids, pastes, and extruded tapes. It also describes classifications and types, comparing and contrasting sealants made from oil-based caulks, asphalts, coal tar resins, latex acrylic sealants, polyvinyl acetate caulks, solvent acrylics, butyl sealants, polysulfides, polyurethanes, modified silicones, anaerobics, vinyl plastisols, and polypropylenes. In addition, the article provides practical design insight, addressing application requirements, seal configurations, and joint stresses. It concludes with a brief discussion on the use of sealants in aerospace, automotive, electrical, and construction applications.
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Published: 01 January 1994
Fig. 1 Adduct of hydroxyethyl acrylate and caprolactone, used by Chang et al. ( Ref 3 ) to make elastomeric coatings from acrylics
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Published: 30 September 2015
Fig. 21 Acrylate chemistry. The methyl methacrylate monomer acts as a cross linker (bridge) between the longer multifunctional chains. Courtesy of Loyd Burcham, Stonhard
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Published: 30 September 2015
Fig. 20 Color-coated concrete bridges. (a) Acrylic coating system on a concrete bridge. (b) Concrete bridge span coated with an epoxy-acrylic coating. Courtesy of KTA-Tator, Inc.
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in Guidance for the Use of Protective Coatings in Municipal Potable Water Systems
> Protective Organic Coatings
Published: 30 September 2015
Fig. 2 Prestressed concrete tank with exterior acrylic coating. Courtesy of DN Tanks
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in Guidance for the Use of Protective Coatings in Municipal Potable Water Systems
> Protective Organic Coatings
Published: 30 September 2015
Fig. 19 Lower-film-stress acrylic coating system being applied over an aged epoxy-urethane system on a hydropillar (type of water storage tank)
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in Coatings for Commercial Structures and Building Deficiencies that Affect Performance
> Protective Organic Coatings
Published: 30 September 2015
Fig. 27 Moisture-sensitive elastomeric finish coat was overcoated with acrylic. Entrapped moisture led to wrinkling and blistering of the elastomeric.
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in Coatings for Commercial Structures and Building Deficiencies that Affect Performance
> Protective Organic Coatings
Published: 30 September 2015
Fig. 28 Cracks in the acrylic overcoat are visible to the left of the blister. The wrinkled coating is the original elastomeric finish that is failing to the block filler (beneath the wrinkled coating but not visible in the photo).
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Published: 30 September 2015
Fig. 16 Fourier transform infrared spectrum of acrylic coating suspended in a potassium bromide pellet. Courtesy of KTA-Tator, Inc.
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Published: 30 September 2015
Fig. 1 Polymerization of acrylic monomers to generate linear polymer chains
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Published: 30 September 2015
Fig. 3 Reaction of acrylic polyol and polyisocyanate to form a polyurethane
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Published: 30 September 2015
Fig. 4 Reaction of an acrylic polyol and melamine-formaldehyde resin
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Published: 30 September 2015
Fig. 5 Reaction of an acrylic polymer with carboxylic acid functionality and an epoxy resin
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Published: 30 September 2015
Fig. 6 Moisture-cure reaction of alkoxysilane-functional acrylic resin
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Published: 30 September 2015
Fig. 8 Scanning electron microscope image of acrylic latex particles
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Published: 30 September 2015
Fig. 9 Possible morphologies of acrylic latex particles. Source: Ref 19
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Published: 30 September 2015
Fig. 10 Film-formation mechanism for a waterborne acrylic latex polymer. Inset shows that each latex particle consists of multiple high-molecular-weight polymer chains.
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