Steels may be annealed to facilitate cold working or machining, to improve mechanical or electrical properties, or to promote dimensional stability. This article, using iron-carbon phase diagram, describes the types of annealing processes, namely, subcritical annealing, intercritical annealing, supercritical or full annealing, and process annealing. Spheroidizing is performed for improving the cold formability of steels. The article provides guidelines for annealing and tabulates the critical temperature values for selected carbon and low-alloy steels and recommended temperatures and time cycles for annealing of alloy steels and carbon steel forgings. Different combinations of annealed microstructure and hardness are significant in terms of machinability. Furnaces for annealing are of two basic types, batch furnaces and continuous furnaces. The article concludes with a description of the annealing processes for steel sheets and strips, forgings, bars, rods, wires, and plates.

This article summarizes the key mechanical characteristics of various types of stainless steel, including ferritic, austenitic, martensitic, precipitation hardening, and duplex steels. Particular emphasis is on fracture properties and corrosion fatigue. The article tabulates typical room-temperature mechanical properties and fatigue endurance limits of stainless steels. Stainless steels are susceptible to embrittlement during thermal treatment or elevated-temperature service. The article discusses embrittlement in terms of sensitization, 475 deg C embrittlement, and sigma-phase embrittlement. It also describes the effect of environment on fatigue crack growth rate.

Dual-phase steels are a new class of high-strength low alloy (HSLA) steels characterized by a microstructure consisting of about 20% hard martensite particles dispersed in a soft ductile ferrite matrix. In addition to high tensile strength, in the range of 550 MPa (80 ksi), dual-phase steels exhibit continuous yielding behavior, a low 0.2% offset yield strength, and a higher total elongation than other HSLA steels of similar strength. The article discusses some of the more pertinent aspects of dual-phase steels, such as heat treatment, microstructure, mechanical properties, chemical composition, and manufacturability. In general, these steels have a carbon content of less than 0.1%, which ensures that they can be spot welded. However, newer high-carbon dual-phase steels in development are generating interest due to their unique combination of total elongation and tensile strength.

Malleable iron possesses considerable ductility and toughness because of its combination of nodular graphite and a low-carbon metallic matrix. The desired formation of temper carbon in malleable irons has two basic requirements. First, graphite should not form during the solidification of the white cast iron, and second, graphite must also be readily formed during the annealing heat treatment. These two metallurgical requirements influence the useful compositions of malleable irons and the melting, solidification, and annealing procedures. There are two basic types of malleable iron: blackheart and whiteheart. This article considers only the blackheart type and describes the metallurgical factors of malleable iron. It discusses the mechanical properties of pearlitic and martensitic malleable irons. The article provides additional information on the properties and heat treatment of ferritic, pearlitic, and martensitic malleable irons. The article lists some of the typical applications of malleable iron castings.

Malleable iron, like ductile iron, possesses considerable ductility and toughness because of its combination of nodular graphite and low-carbon metallic matrix. This article discusses melting practices such as batch cold melting and duplexing, and their control mechanisms. It schematically illustrates the microstructure of annealed ferritic malleable iron, which is characterized by microstructures consisting of uniformly dispersed fine particles of free carbon in a matrix of ferrite or tempered martensite. The article describes the digital solidification analysis technology, simulation technologies, and smart engineering for the production of malleable iron. It provides information on the applications of ferritic and pearlitic malleable irons.

Malleable iron is a cast ferrous metal that is initially produced as white cast iron and is then heat treated to convert the carbon-containing phase from iron carbide to a nodular form of graphite called temper carbon. This article provides a discussion on the melting practices, heat treatment, microstructure, production technologies, mechanical properties, and applications of ferritic, pearlitic, and martensitic malleable irons.

Maraging steels are highly alloyed low-carbon iron-nickel martensite steels that possess an excellent combination of strength and toughness superior to that of most carbon-hardened steels. This article provides a detailed account of the formation of martensite in maraging steels. It discusses the heat treatment of these steels, namely, aging, solution annealing, age hardening, and nitriding. Their hardening during aging has been attributed to two different mechanisms: short-range ordering and precipitation. The article concludes with a discussion on the grain refinement using thermal cycling and transformation-induced plasticity maraging methods.

This article summarizes the metallurgical and environmental variables that affect fracture toughness, fatigue life, and subcritical crack growth of titanium alloys, such as chemistry, microstructure, texture, environment, and loading. The classes of titanium alloys considered in the article include alpha-beta alloys, Ti-6AI-4V; alpha alloys, Ti-8Al -1Mo-IV, Ti-5AI-2.5Sn, Ti-6242S; and beta alloys, solute-lean beta alloys and solute-rich beta alloys.

Cr-Mo steels are preferred in the construction of high-temperature components because they possess excellent strength, toughness, and corrosion resistance relative to carbon steels and most low-alloy steels. This article discusses the composition and metallurgy of the heat-resistant Cr-Mo steels. It details the Charpy V-notch (CVN) toughness properties of Cr-Mo steels relevant to fatigue and fracture resistance. The fracture mechanics of Cr-Mo steels are reviewed. The article analyzes the characterization of low-cycle fatigue based on fatigue damage calculations. It concludes with information on fatigue crack growth and fatigue behavior of weldments.

This article provides information on nickel alloying elements, and the heat treatment processes of various nickel alloys for applications requiring corrosion resistance and/or high-temperature strength. These processes are homogenization, annealing, solution annealing, solution treating, stabilization treatment, age hardening, stress relieving, and stress equalizing. Discussion of furnaces, fixtures, and atmospheres is included. Nickel alloys used for the heat treatment processes include corrosion-resistant nickel alloys, heat-resistant nickel alloys, nickel-beryllium alloys, special-purpose alloys such as nitinol shape memory alloys, low-expansion alloys, electrical-resistance alloys and soft magnetic alloys. Finally, the article focuses on heat treatment modeling for selecting the appropriate heat treatment process.

Cast irons may be compared with steels in their reactions to hardening. However, because cast irons (except white iron) contain graphite and substantially higher percentages of silicon, they require higher austenitizing temperatures. This article describes the effect of heat treatment processes such as annealing, normalizing, surface hardening, tempering, stress relieving, quenching, and austempering, on hardness and tensile properties of cast irons, namely gray irons, ductile irons, malleable irons, and austenitic irons.

This article describes the heat treatment of wrought solid-solution and precipitation-hardening alloys with a focus on the major families of wrought nickel alloys. It also provides information on the heat treatment of some representative solid-solution alloys in the Monel (Ni-Cu), Inconel (Ni-Cr-Mo), Hastelloy (Ni-Mo-Cr), and Incoloy (Ni-Fe-Cr) families of alloys. The heat treatment processes for gamma prime nickel alloys, gamma prime nickel-iron superalloys, and gamma double-prime nickel-iron superalloys are also included. The article also provides information on age-hardenable alloys, and the effects of cold work on aging response and grain growth with examples.

Ferritic stainless steels are essentially chromium containing steel alloys with at least 10.5% Cr. They can be grouped based on their chromium content: low chromium (10.5 to 12.0%), medium chromium (16 to 19%), and high chromium (greater than 25%). This article provides general information on the metallurgy of ferritic stainless steels. It describes two types of heat treatments to avoid sensitization and embrittlement. They are annealing and stress relieving. The article also provides information on casting and stabilization of ferritic stainless steels to avoid precipitation of grain boundary carbides.

Heat treating of stainless steel produces changes in physical condition, mechanical properties, and residual stress level and restores maximum corrosion resistance when that property has been adversely affected by previous fabrication or heating. This article focuses on annealing of different types of stainless steels such as austenitic, ferritic, duplex, martensitic, and precipitation-hardening, and on the heat treatment of superalloys and refractory metals. It discusses the recommended procedures for solution annealing, austenite conditioning, transformation cooling, and age tempering of precipitation-hardening stainless steels. The article also lists general recommendations for the annealing temperatures of tantalum, niobium, molybdenum, tungsten, and their alloys.

This article discusses three distinct mechanisms of bonding for solid-state (forge) welding processes, namely, contaminant displacement/interatomic bonding, dissociation of retained oxides, and decomposition of the interfacial structure. It explains the processes that can be characterized as having two stages: heating and forging. The article also includes a table that illustrates weld strengths as a function of annealing temperature for a range of materials.

This article discusses some elevated-temperature properties of carbon steels and low-alloy steels with ferrite-pearlite and ferrite-bainite microstructures for use in boiler tubes, pressure vessels, and steam turbines. The selection of steels to be used at elevated temperatures generally involves compromise between the higher efficiencies obtained at higher operating temperatures and the cost of equipment, including materials, fabrication, replacement, and downtime costs. The article considers the low-alloy steels which are the creep-resistant steels with 0.5 to 1.0% Mo combined with 0.5 to 9.0% Cr and perhaps other carbide formers. The factors affecting mechanical properties of steels include the nature of strengthening mechanisms, the microstructure, the heat treatment, and the alloy composition. The article describes these factors, with particular emphasis on chromium-molybdenum steels used for elevated-temperature service. Although the mechanical properties establish the allowable design-stress levels, corrosion effects at elevated temperatures often set the maximum allowable service temperature of an alloy. The article also discusses the effects of alloying elements in annealed, normalized and tempered, and quenched and tempered steels.

This article reviews the influence of local strains and corrosion fatigue on the initiation of fatigue cracks in duplex stainless steels. It provides useful information on fatigue crack growth, fatigue strength, and fracture toughness of duplex stainless steels. The article discusses the fatigue and fracture behavior of duplex stainless steels during stress-corrosion cracking. It details the elevated-temperature properties of duplex stainless steels, such as creep-fatigue behavior and thermal cycling properties.

Understanding the high-temperature corrosion behavior of alloys is an important step toward the selection of appropriate alloys for process equipment. This article briefly describes the high-temperature corrosion modes that are frequently encountered in the chemical process industry. These modes include oxidation, carburization, metal dusting, nitridation, halogen corrosion, and sulfidation.

This article provides information on fracture toughness and fatigue crack growth of structural steels. It describes fatigue life behavior in terms of unnotched fatigue limits, notch effects, axial strain-life fatigue, and mean stress effects. The article analyzes the mechanisms of corrosion fatigue crack initiation and prevention of corrosion fatigue. It presents case histories of fatigue failure of various steel components. The article reviews the failure of coiled tubing in a drilling application and the failure of coiled tubing due to hydrogen sulfide exposure, with examples.

This article begins with a discussion of the basic fracture modes, including dimple ruptures, cleavages, fatigue fractures, and decohesive ruptures, and of the important mechanisms involved in the fracture process. It then describes the principal effects of the external environment that significantly affect the fracture propagation rate and fracture appearance. The external environment includes hydrogen, corrosive media, low-melting metals, state of stress, strain rate, and temperature. The mechanism of stress-corrosion cracking in metals such as steels, aluminum, brass, and titanium alloys, when exposed to a corrosive environment under stress, is also reviewed. The final section of the article describes and shows fractographs that illustrate the influence of metallurgical discontinuities such as laps, seams, cold shuts, porosity, inclusions, segregation, and unfavorable grain flow in forgings and how these discontinuities affect fracture initiation, propagation, and the features of fracture surfaces.