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Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006639
EISBN: 978-1-62708-213-6
... Abstract This article focuses on the principles and applications of X-ray photoelectron spectroscopy (XPS) for the analysis of elemental and chemical composition. The discussion covers the nomenclature, instruments, and specimen preparation process of XPS. Some of the factors pertinent...
Abstract
This article focuses on the principles and applications of X-ray photoelectron spectroscopy (XPS) for the analysis of elemental and chemical composition. The discussion covers the nomenclature, instruments, and specimen preparation process of XPS. Some of the factors pertinent to the calibration of materials for accurate measurements using XPS are provided, along with some aspects of the accuracy in quantitative analysis by XPS. In addition, the article presents examples of how XPS data can be used to solve problems with surface interactions.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001771
EISBN: 978-1-62708-178-8
... Abstract This article provides a detailed account of the principles, instrumentation,and applications of x-ray photoelectron spectroscopy (XPS), a technique used for elemental and compositional analysis of surfaces and thin films. It reviews the nomenclature of energy states and sensitivity...
Abstract
This article provides a detailed account of the principles, instrumentation,and applications of x-ray photoelectron spectroscopy (XPS), a technique used for elemental and compositional analysis of surfaces and thin films. It reviews the nomenclature of energy states and sensitivity of electrons at the surface that are capable of producing peaks in XPS. Additionally, it presents information on the instrumentation and the preparation and mounting of samples for XPS analysis. The article explains qualitative analysis, namely, measuring of shifts in the binding energy of core electrons, multiplet splitting, and the Auger parameter; and quantitative analysis such as depth analysis carried out using XPS. It also discusses the applications of XPS with examples.
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X-ray photoelectron spectroscopy survey spectrum of stainless steel surface...
Available to PurchasePublished: 01 January 2002
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X-ray photoelectron spectroscopy high-resolution spectrum of polyethylene t...
Available to PurchasePublished: 01 January 2002
Fig. 5 X-ray photoelectron spectroscopy high-resolution spectrum of polyethylene terephthalate (PET)
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X-ray photoelectron spectroscopy compositional depth profile of stainless s...
Available to PurchasePublished: 01 January 2002
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X-ray photoelectron spectroscopy high-resolution carbon spectrum of stainle...
Available to PurchasePublished: 01 January 2002
Fig. 10 X-ray photoelectron spectroscopy high-resolution carbon spectrum of stainless steel surface
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X-ray photoelectron spectroscopy high-resolution iron spectrum of stainless...
Available to PurchasePublished: 01 January 2002
Fig. 11 X-ray photoelectron spectroscopy high-resolution iron spectrum of stainless steel surface
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X-ray photoelectron spectroscopy high-resolution iron spectrum obtained fro...
Available to PurchasePublished: 01 January 2002
Fig. 12 X-ray photoelectron spectroscopy high-resolution iron spectrum obtained from well-passivated stainless steel surface
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X-ray photoelectron spectroscopy montage display of iron in the first eight...
Available to PurchasePublished: 01 January 2002
Fig. 13 X-ray photoelectron spectroscopy montage display of iron in the first eight sputter cycles of the depth profile (Fig. 6)
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X-ray photoelectron spectroscopy montage display of Cr in the first nine sp...
Available to PurchasePublished: 01 January 2002
Fig. 14 X-ray photoelectron spectroscopy montage display of Cr in the first nine sputter cycles of the depth profile (Fig. 6)
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X-ray photoelectron spectroscopy depth profile of a type 316L stainless ste...
Available to PurchasePublished: 01 January 2006
Fig. 6 X-ray photoelectron spectroscopy depth profile of a type 316L stainless steel surface. The base metal composition is reached at approximately 35 nm, or 100 atoms, from the surface. In this example, the chromium/iron ratio is 7.7, an outstanding value.
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X-ray photoelectron spectroscopy depth profile chart of a type 316L stainle...
Available to PurchasePublished: 01 January 2006
Fig. 7 X-ray photoelectron spectroscopy depth profile chart of a type 316L stainless steel surface with an extremely poor chromium/iron ratio of only 0.13. This material will show rust in only a few hours in a humid environment.
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Published: 01 January 1994
Fig. 4 X-ray photoelectron spectroscopy of the Ti-2 p 1/2, 3/2 doublet in TiN and TiO 2 obtained with a thin oxide layer on TiN. Source: Ref 10
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Angle-resolved x-ray photoelectron spectroscopy spectrum of a 2.3 nm thick ...
Available to PurchasePublished: 01 January 1994
Fig. 10 Angle-resolved x-ray photoelectron spectroscopy spectrum of a 2.3 nm thick Al 2 O 3 layer on aluminum. (a) Al-2 p peak as a function of the takeoff angle φ. (b) Ratio of the peak areas of Al 2 O 3 and aluminum as a function of the emission angle θ = 90° − φ. Source: Ref 47
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Published: 01 June 2016
Fig. 3 X-ray photoelectron spectroscopy peak curve fit (magnesium 2 p peak) in the region of maximum magnesium content within the AlN layer. Aluminum alloy 5083; nitrided at 470 °C, or 880 °F; t N,eff = 4 h
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X-ray photoelectron spectroscopy survey spectrum of stainless steel surface...
Available to PurchasePublished: 15 January 2021
Fig. 5 X-ray photoelectron spectroscopy survey spectrum of stainless steel surface with corrosion present
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X-ray photoelectron spectroscopy high-resolution spectrum of polyethylene t...
Available to PurchasePublished: 15 January 2021
Fig. 6 X-ray photoelectron spectroscopy high-resolution spectrum of polyethylene terephthalate showing curve fitting
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X-ray photoelectron spectroscopy depth profiling using monoatomic argon spu...
Available to PurchasePublished: 15 January 2021
Fig. 7 X-ray photoelectron spectroscopy depth profiling using monoatomic argon sputtering through the oxide of a stainless steel surface
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X-ray photoelectron spectroscopy high-resolution iron spectra overlay of co...
Available to PurchasePublished: 15 January 2021
Fig. 12 X-ray photoelectron spectroscopy high-resolution iron spectra overlay of corroded stainless steel surface and well-passivated stainless steel surface. A metallic iron peak is observed in the well-passivated stainless steel.
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X-ray photoelectron spectroscopy montage display of iron in the first eight...
Available to PurchasePublished: 15 January 2021
Fig. 13 X-ray photoelectron spectroscopy montage display of iron in the first eight sputter cycles of the depth profile ( Fig. 7 )
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