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X-ray absorption

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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001764
EISBN: 978-1-62708-178-8
... Abstract This article provides an introduction to extended x-ray absorption fine structure (EXAFS). It describes the fundamentals of EXAFS with an emphasis on the physical mechanism, the single-scattering approximation, and multiple-scattering effects. The article discusses the use...
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006665
EISBN: 978-1-62708-213-6
... Abstract This article provides a detailed account of extended x-ray absorption fine structure (EXAFS). It begins with a description of the fundamentals of EXAFS, providing information on the physical mechanism, single-scattering approximation, and multiple-scattering effects. This is followed...
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Published: 01 January 1986
Fig. 2 X-ray absorption curve for uranium as a function of wavelength. More
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Published: 15 December 2019
Fig. 1 Experimental extended x-ray absorption fine structure scan of nickel metal taken by using synchrotron radiation above the K-absorption edge of nickel at 8332.8 eV. The energy is labeled regarding the K-edge of nickel as zero. More
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Published: 15 December 2019
Fig. 2 Experimental extended x-ray absorption fine structure scan of germanium in GeCl 4 molecule taken by using synchrotron radiation above the K-absorption edge of germanium at 11,103.3 eV. Source: Ref 13 More
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Published: 15 December 2019
Fig. 3 Experimental K-edge extended x-ray absorption fine structure spectrum of germanium in crystalline and glassy GeO 2 . The energy is labeled regarding the K-edge of germanium at 11,103.3 eV as zero. Source: Ref 15 More
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Published: 15 December 2019
Fig. 4 Schematic representation of extended x-ray absorption fine structure event. The excited electronic state is centered about the A-atom. The solid-line circles represent the crests of the outgoing part of the electronic state. The surrounding B-atoms backscatter the outgoing part More
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Published: 15 December 2019
Fig. 6 Extended x-ray absorption fine structure experimental apparatus at the Stanford Synchrotron Radiation Laboratory. (a) Transmission mode of detection. (b) Fluorescence mode of detection. SPEAR, Stanford Position Electron Accelerator Ring. Source: Ref 35 More
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Published: 15 December 2019
Fig. 7 Typical extended x-ray absorption fine structure (EXAFS) data analysis. (a) Experimental scan of nickel K-edge EXAFS in pure nickel at 90 K. The broken line denotes a spline fit of the smooth post-edge background absorption above the absorption edge. (b) Normalized EXAFS plotted as χ More
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Published: 15 December 2019
Fig. 8 Experimental (line) and simulated (points) extended x-ray absorption fine structure of the first shell of 12 neighbors from 1 to 2.8 Å about a nickel atom in face-centered cubic nickel at 90 K More
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Published: 15 December 2019
Fig. 9 The vanadium K-edge x-ray absorption near-edge structure spectra of a series of vanadium oxides. The zero of energy is taken at the K-edge of vanadium metal at 5465 eV in all cases. More
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Published: 15 December 2019
Fig. 12 Normalized nickel K-edge extended x-ray absorption fine structure plotted as χ · k versus k and corresponding Fourier transform. (a) Nickel impurity in synthetic diamond. (b) Face-centered cubic nickel. (c) Ni 3 B. r is the radial distance (phase shift not included) from More
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Published: 15 December 2019
Fig. 8 X-ray absorption curve for uranium as a function of wavelength More
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Published: 15 May 2022
Fig. 5 Typical energy-dispersive x-ray spectroscopy spectrum showing absorption features indicative of unique elements and the quantitation of those elements. cps, counts per second More
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003710
EISBN: 978-1-62708-182-5
... spectroscopy, Auger electron spectroscopy, X-ray photoelectron spectroscopy, ion scattering spectroscopy, reflectance Fourier transform infrared absorption spectroscopy, Raman and surface enhanced Raman spectroscopy, and extended X-ray absorption fine structure analysis. corrosion corrosion inhibition...
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001733
EISBN: 978-1-62708-178-8
... Abstract This article provides an introduction to x-ray spectrometry, and discusses the role of electromagnetic radiation, x-ray emission, and x-ray absorption. It focuses on the instrumentation of wavelength-dispersive x-ray spectrometers, and energy dispersive x-ray spectrometers (EDS...
Book Chapter

By S. Lampman
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006645
EISBN: 978-1-62708-213-6
...-dispersive spectrometer (WDS) and energy-dispersive spectrometer (EDS). This is followed by a discussion on the mechanism and effects of X-ray radiation, X-ray emission, and X-ray absorption. The article then discusses components used, operation, and applications of WDS and EDS. Some of the factors...
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Published: 15 December 2019
Fig. 10 Oxidation state versus energy positions of various absorption features in the vanadium K-edge x-ray absorption near-edge structure spectra of various vanadium oxides shown in Fig. 9 More
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Published: 15 December 2019
Fig. 11 Body-centered cubic (bcc) iron-nickel alloy containing 80 at.% Fe. (a) Experimental extended x-ray absorption fine structure (EXAFS) spectra above the K-edges of iron and nickel. (b) Normalized EXAFS plotted as χ · k versus k for the EXAFS. (c) Fourier transform of (b). The peaks More
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0005693
EISBN: 978-1-62708-178-8
... ESCA electron spectroscopy for chemical analysis ESR electron spin resonance EXAFS extended x-ray absorption fine structure FIM field ion microscopy FNAA fast neutron activation analysis FMR ferromagnetic resonance FT-IR Fourier transform infrared...