This article reviews various phases and constituents found in the microstructures of low-carbon and coated steels. It provides information on the criteria for selecting proper metallographic procedures. Techniques used to prepare metallographic specimens of low-carbon steels and coated steels, such as sectioning, mounting, grinding, polishing, and etching, are discussed. The article also reviews the simple and proven manual sample preparation techniques of coated steel specimens.

This article describes the microstructure and metallographic practices used for medium- to high-carbon steels as well as for low-alloy steels. It explains the microstructural constituents of plain carbon and low-alloy steels, including ferrite, pearlite, and cementite. The article provides information on how to reveal the various constituents using proven metallographic procedures for both macrostructural and microstructural examination. Emphasis is placed on the specimen preparation procedures such as sectioning, mounting, grinding, and polishing. The article illustrates the use of proven etching techniques for plain carbon and low-alloy steels.

This article outlines the processes by which materials are selected to prevent or control localized corrosion, galvanic corrosion, and intergranular corrosion. It reviews the operating conditions and the design of candidate materials for material selection. The article discusses various corrosion-resistant materials, including ferrous and nonferrous metals and alloys, thermoplastics, reinforced thermosetting plastics, nonmetallic linings, glass, carbon and graphite, and catalyzed resin coatings. It examines an unusual form of intergranular corrosion known as exfoliation, which occurs in aluminum-copper alloys. The article also describes three types of erosion-corrosion: liquid erosion-corrosion, cavitation, and fretting. It concludes with information on the various factors to be considered for material selection, including minimum cost or economic design, minimum corrosion, minimum investment, and minimum maintenance.

This article describes the influence of steel chemical compositions and microstructure on machining processes. It discusses the various microstructural phases of standard carbon and alloy steels, which influence machinability. The article reviews the expected response of several traditional machining operations, such as turning, drilling, milling, shaping, thread cutting, and grinding, to the microstructure of standard steel grades. It also explains the technologies in non-traditional machining processes, such as abrasive waterjet cutting, electrical chemical grinding, and laser drilling.

This article provides an overview of the different classification and designation systems of wrought carbon steel and alloy steel product forms with total alloying element contents not exceeding 5″. It lists the quality descriptors, chemical compositions, cast or heat composition ranges, and product analysis tolerances of carbon and alloy steels. The major designation systems discussed include the Society of Automotive Engineers (SAE)-American Iron and Steel Institute (AISI) designations, Unified Numbering System (UNS) designations, American Society for Testing and Materials (ASTM) designations, Aerospace Material Specification (AMS), and other international designations and specifications.

Macroetching is a procedure for revealing the large-scale structure of a metallic specimen, that is, the structure visible with the unaided eye, by etching an appropriately prepared surface. This article provides information on the basic procedures for macroetching as well as the apparatus used. It discusses selected etchants for efficient macroetching of various metals and their alloys, including iron, steel, high-alloy steels, stainless steels, high-temperature alloys, titanium, titanium alloys, aluminum, aluminum alloys, copper, and copper alloys. The article also describes various conditions that are revealed by the macroetching of aluminum.

Forging of nickel-base alloys results in geometries that reduce the amount of machining to obtain final component shapes and involves deformation processing to refine the grain structure of components or mill products. This article discusses the heating practice, die materials, and lubricants used in nickel-base alloys forging. It describes two major forging processing categories for nickel-base alloys: primary working and secondary working categories. Primary working involves the deformation processing and conversion of cast ingot or similar bulk material into a controlled microstructure mill product, such as billets or bars, and secondary working refers to further forging of mill product into final component configurations.

The production and use of steel plate is aided by a system of standard designations and associated specifications defining composition, property, and performance ranges. This article contains an extensive amount of information on the designations and grades of plate products and how they are made. Although most steel plate is used in the hot-finished condition, some applications require one or more heat treating steps to mitigate imperfections and/or improve relevant qualities. The article discusses these interconnected factors as well as their impact on mechanical properties and critical fabrication issues, including formability, machinability, and weldability.

This article discusses the classification of carbon steels based on carbon content, and tabulates the compositional limits of medium- and high-carbon steels based on the AISI code and other similar codes. It describes recrystallization annealing and spheroidizing of carbon steels, and discusses the classification of carbon steels for heat treatment. The article also discusses the estimation of continuous cooling curves from isothermal transformation curves. It provides information on the Jominy end-quench test and the Grossmann method and the procedures to increase hardenabilty of carbon steels. The article includes information on the purpose of tempering and heat treating guidelines for different grades of steels, including cast carbon steels.

This article addresses the long-term corrosion behavior of high-level waste (HLW) container materials, more specifically of the outer shell of the containers. It discusses time, environmental, and materials considerations for the emplacement of HLW in geological repositories. Environmental corrosion resistance of materials planned for reducing repositories is also discussed. The article reviews the design and characterization of nuclear waste repository with an oxidizing environment surrounding the waste package.

This article addresses classifications and designations for carbon steels and low-alloy steels, particularly high-strength low-alloy (HSLA) steels, based on chemical composition, manufacturing methods, finishing method, product form, deoxidation practice, microstructure, required strength level, heat treatment and quality descriptors. It describes the effects of alloying elements on the properties and characteristics of steels. The article provides extensive tabular data pertaining to domestic and international designations of steels.

Cold-finished steel bars are carbon and alloy steel bar products (round, square, hexagonal, flat, or special shapes) that are produced by cold finishing previous hot-wrought bars. by means of cold drawing, cold forming, turning, grinding, or polishing (singly or in combination) to yield straight lengths or coils that are uniform throughout their length. Cold-finished bars fall into five classifications: cold-drawn bars; turned and polished bars; cold-drawn, ground, and polished bars; turned, ground, and polished bars; cold-drawn, turned, ground, and polished bars. Different size tolerances are applicable to cold-finished products, depending on shape, carbon content, and heat treatment. When used to identify cold-finished steel bars, the various quality descriptors are indicative of many characteristics, such as degree of internal soundness, relative uniformity of chemical composition, and relative freedom from detrimental surface imperfections. Cold drawing significantly increases machinability, tensile and yield strengths of steel bars. Two special die-drawing processes have been developed to give improved properties over those offered by standard drawing practices. These processes are cold drawing using heavier-than-normal drafts, followed by stress relieving; and drawing at elevated temperatures.

The properties of irons and steels are linked to the chemical composition, processing path, and resulting microstructure of the material. Processing is a means to develop and control microstructure by hot rolling, quenching, and so forth. This article describes the role of these factors in both theoretical and practical terms, with particular focus on the role of microstructure in various irons. These include bainite, pearlite, ferfite, martensite, austenite, ferrite-pearlite, ferrite-cementite, ferrite-martensite, graphite, and cementite. The article discusses the evolution of microstructural change in rail steels, cast iron, and steel sheet. It contains tables that list the mechanical properties and compositions of selected steels. The article also discusses the basis of material selection of irons and steels.

This article discusses the classifications, compositions, properties, advantages, disadvantages, limitations, and applications of the most commonly used methods for surface engineering of carbon and alloy steels. These include cleaning methods, finishing methods, conversion coatings, hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment.