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Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006785
EISBN: 978-1-62708-295-2
... of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions...
Abstract
Stress-corrosion cracking (SCC) is a form of corrosion and produces wastage in that the stress-corrosion cracks penetrate the cross-sectional thickness of a component over time and deteriorate its mechanical strength. Although there are factors common among the different forms of environmentally induced cracking, this article deals only with SCC of metallic components. It begins by presenting terminology and background of SCC. Then, the general characteristics of SCC and the development of conditions for SCC as well as the stages of SCC are covered. The article provides a brief overview of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions commonly associated with the development of SCC, although not all, and numerous case studies.
Book Chapter
Effect of Irradiation on Stress-Corrosion Cracking and Corrosion in Light Water Reactors
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004147
EISBN: 978-1-62708-184-9
... of dissolved oxygen. This is consistent with enhanced recombination of oxidizing and reducing species, which occurs in the downcomer region of BWRs ( Ref 56 ) and is relied upon to produce SCC mitigation using hydrogen water chemistry (HWC). In instances where neutrons or protons have been used, a consistent...
Abstract
This article examines the understanding of persistent material changes produced in stainless alloys during light water reactor (LWR) irradiation based on the fundamentals of radiation damage and existing experimental measurements. It summarizes the overall trends and correlations for irradiation-assisted stress-corrosion cracking. The article addresses the effects of various radiation factors on corrosion. These include radiation-induced segregation at grain boundaries, radiation hardening, mode of deformation, radiation creep relaxation, and radiolysis. The article discusses a variety of approaches for mitigating stress-corrosion cracking in LWRs, in categories of water chemistry, operating guidelines, new alloys, design issues, and stress mitigation. It concludes with a discussion on the irradiation effects of irradiation on corrosion of zirconium alloys in LWR environments.
Book Chapter
External Corrosion of Oil and Natural Gas Pipelines
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004213
EISBN: 978-1-62708-184-9
..., the most common causes and contributing factors for corrosion and SCC, as well as prevention, mitigation, detection, and repair are discussed. Differential Cell Corrosion In the case of true general corrosion of a metal, the oxidation and reduction reactions occur physically at or very near the same...
Abstract
This article describes the mechanisms of differential corrosion cells corrosion, microbiologically influenced corrosion, and stray direct current corrosion. It discusses the most common causes and contributing factors for corrosion and stress-corrosion cracking, as well as prevention, mitigation, detection, and repair processes.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003621
EISBN: 978-1-62708-182-5
... and the possibility of fatigue cracking), are also important because of the possibility of stress-corrosion cracking (SCC) in some environments. Geometrical Factors It should be recognized that excess root penetration can interrupt fluid flow close to the wall of a pipe in high-flow-rate operation, leading...
Abstract
Corrosion of carbon steel weldments can be due to metallurgical effects, such as preferential corrosion of the heat-affected zone (HAZ) or weld metal, or it can be associated with geometrical aspects, such as stress concentration at the weld toe, or creation of crevices due to joint design. This article describes the issues related to corrosion of carbon steel weldments and the remedial measures that have proven to be successful in specific cases. It provides useful information on preferential HAZ corrosion, preferential weld metal corrosion, and galvanic corrosion.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004185
EISBN: 978-1-62708-184-9
... <0.01 0.01 Source: Ref 8 Ammonia SCC mitigation measures Table 2 Ammonia SCC mitigation measures Corrosion mitigation scheme Refrigerated tanks Road tankers Eliminate oxygen This is a normal commissioning procedure, but regular inspection reintroduces oxygen. The number...
Abstract
Ammonia and ammonium hydroxide are not particularly corrosive in themselves, but corrosion problems can arise with specific materials, particularly when contaminants are present. This article discusses the corrosion resistance of materials used for the manufacture, handling, and storage of ammonia. These materials include aluminum alloys, iron and steel, stainless steels, nickel and its alloys, copper and its alloys, titanium and its alloys, zirconium and its alloys, niobium, tantalum, and nonmetallic materials.
Book Chapter
Introduction to Corrosion in the Nuclear Power Industry
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004223
EISBN: 978-1-62708-184-9
...-corrosion cracking (PWSCC) of nickel-base alloys in PWRs can be as long as 25 years! Also, while it was well documented at the time that the presence of chloride in the coolant could cause chloride stress-corrosion cracking (SCC) of stainless steel, there was little evidence that only 0.2 ppm of dissolved...
Abstract
This article reviews a series of serious corrosion problems that have plagued the light water reactor (LWR) industry. It discusses the complex corrosion mechanisms involved, and the development of practical engineering solutions for their mitigation. The article contains tables that present the corrosion history of LWRs, and the ten most expensive operation and maintenance costs of corrosion for a particular reactor site.
Book Chapter
Corrosion in Supercritical Water—Waste Destruction Environments
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004132
EISBN: 978-1-62708-184-9
... Ref 18 Highly chlorinated organic 600 1110 Wastage, stress-corrosion cracking (SCC) Ref 19 pH higher than 12 500 930 SCC and other forms Ref 17 Nickel-base alloys Alloys 625 and C276 Deionized water 300–500 570–930 Uniform and pitting Ref 17 Highly chlorinated...
Abstract
Supercritical water oxidation (SCWO) is an effective process for the destruction of military and industrial wastes including wastewater sludge. This article discusses the unique properties of supercritical water and lists the main technological advantages of SCWO. For many waste streams, corrosion continues to be one of the central challenges to the full development of the SCWO technology. The article presents a summary of selected materials exposed to various environments as well as the observed form of corrosion in a table. It also illustrates the necessity to adopt a synergistic approach incorporating feed chemistry control, reactor design modifications, and intelligent materials selection, for mitigating degradation of SCWO systems.
Book Chapter
Components Susceptible to Dew-Point Corrosion
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004159
EISBN: 978-1-62708-184-9
... and ammonium nitrate both are hygroscopic materials that can take up water even above the dew point of a gas. Up to a temperature of 120 °C (250 °F), this can create a very corrosive environment and may result in a severe risk of nitrate SCC in susceptible materials. Mitigation of Dew-Point Corrosion...
Abstract
Dew-point corrosion occurs when gas is cooled below the saturation temperature pertinent to the concentration of condensable species contained by a gas. This article discusses dew-point corrosion problems in the susceptible areas of dry flue gas handling systems. The corrosion problems associated with the nitrate stress-corrosion cracking in heat-recovery steam generators are also discussed. The article presents general comments on the materials selection; plant operation; use of neutralizing additives; and maintenance, good housekeeping, and lagging (insulation). It concludes with information on guidance for maintaining specific sections of the plant.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003553
EISBN: 978-1-62708-180-1
.... Changes in one or more of the three necessary factors—material, stress, and environment—can prevent or mitigate SCC, either in design or after a problem has occurred in the field. Material selection and specification is the first line of defense. Lowering of the applied stresses and elimination...
Abstract
This article commences with a discussion on the characteristics of stress-corrosion cracking (SCC) and describes crack initiation and propagation during SCC. It reviews the various mechanisms of SCC and addresses electrochemical and stress-sorption theories. The article explains the SCC, which occurs due to welding, metalworking process, and stress concentration, including options for investigation and corrective measures. It describes the sources of stresses in service and the effect of composition and metal structure on the susceptibility of SCC. The article provides information on specific ions and substances, service environments, and preservice environments responsible for SCC. It details the analysis of SCC failures, which include on-site examination, sampling, observation of fracture surface characteristics, macroscopic examination, microscopic examination, chemical analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium.
Book Chapter
Failures of Pipelines
Available to PurchaseSeries: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006822
EISBN: 978-1-62708-329-4
... and fracture surfaces have been removed. Magnetic-particle or dye-penetrant examination, particularly if a progressive cracking mechanism such as fatigue or stress-corrosion cracking (SCC) is suspected or if mechanical damage (i.e., gouging or denting) is evident Radiographic inspection of welds...
Abstract
This article discusses the failure analysis of several steel transmission pipeline failures, describes the causes and characteristics of specific pipeline failure modes, and introduces pipeline failure prevention and integrity management practices and methodologies. In addition, it covers the use of transmission pipeline in North America, discusses the procedures in pipeline failure analysis investigation, and provides a brief background on the most commonly observed pipeline flaws and degradation mechanisms. A case study related to hydrogen cracking and a hard spot is also presented.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004177
EISBN: 978-1-62708-184-9
... the typical transgranular lightning strike appearance of ESCC in the pipe. External SCC of austenitic stainless steel is possible when the equipment is contacted by aerated water, and chlorides or contaminants are present in the temperature range 50 to 150 °C (120 to 300 °F) in the presence of tensile...
Abstract
This article provides a detailed discussion on the corrosion of steel and stainless steel under insulation. Stress corrosion cracking mechanism, types of alloys susceptible to corrosion, factors influencing corrosion, and corrosion prevention methods, are also discussed.
Book Chapter
Stress-Corrosion Cracking and Hydrogen Embrittlement
Available to PurchaseBook: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002388
EISBN: 978-1-62708-193-1
... Abstract Stress-corrosion cracking (SCC) is a cracking phenomenon that occurs in susceptible alloys, and is caused by the conjoint action of tensile stress and the presence of a specific corrosive environment. This article provides an overview of the anodic dissolution mechanisms and cathodic...
Abstract
Stress-corrosion cracking (SCC) is a cracking phenomenon that occurs in susceptible alloys, and is caused by the conjoint action of tensile stress and the presence of a specific corrosive environment. This article provides an overview of the anodic dissolution mechanisms and cathodic mechanisms for SCC. It discusses the materials, environmental, and mechanical factors that control hydrogen embrittlement and SCC behavior of different engineering materials with emphasis on carbon and low-alloy steels, high-strength steels, stainless steels, nickel-base alloys, aluminum alloys, and titanium alloys.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004119
EISBN: 978-1-62708-184-9
... in the design phase of weapons systems. Almost all materials used in weapon systems are predictably susceptible to corrosion, stress-corrosion cracking (SCC), and corrosion fatigue (CF) ( Ref 10 , 11 ). They include predominantly aluminum, magnesium, and titanium alloys, steels, and graphite-reinforced...
Abstract
This article reviews corrosion problems in the U.S. Department of Defense (DoD) and discusses management and maintenance aspects of the practices that address the cost and readiness. It describes the plans to institute corrosion prevention and control strategies under DoD directives in engineering design, material selection, and fabrication processes for new acquisitions. The article also suggests a long-term strategy to reduce the cost of corrosion control.
Book Chapter
Corrosion of Magnesium and Magnesium-Base Alloys
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003820
EISBN: 978-1-62708-183-2
... rates can be determined and are meaningful. Localized corrosion involves specific factors that determine the severity of the degradation. Stress-Corrosion Cracking Magnesium alloys containing more than a threshold value of 0.15 to 2.5% Al are susceptible to stress-corrosion cracking (SCC...
Abstract
This article begins with a discussion on the environmental factors that induce corrosion in magnesium alloys. It reviews the factors that determine the severity of different forms of localized corrosion, namely, galvanic corrosion, corrosion fatigue, and stress-corrosion. The article discusses corrosion protection in magnesium assemblies and the protective coating systems used in corrosion protection practices. Protection schemes for specific applications and the production of novel magnesium alloys with improved corrosion resistance are also reviewed. The article concludes with a discussion on the corrosion of bulk vapor-deposited alloys and magnesium-matrix composites.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003666
EISBN: 978-1-62708-182-5
... be tensile. Compressively stressed surfaces are not normally prone to SCC. In fact, shot peening is a practical method for mitigating SCC by imparting a residual compressive stress on the metal surface before exposure to the service environment. Residual-Stress Specimens Most industrial SCC problems...
Abstract
This article describes the incubation, nucleation, and propagation of stress-corrosion cracking and how to evaluate it using standard tests. It discusses constant-strain, constant-load, bending, and uniaxial tension testing and how they compare when evaluating smooth and precracked test specimens under elastic-strain, plastic-strain, and residual-stress conditions. The article provides guidance on specimen selection and preparation, strain rate, and test equipment. It also examines service and laboratory test environments and provides detailed information on how to test various steels and alloys and how to interpret test results.
Book Chapter
Corrosion in Boiling Water Reactors
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004145
EISBN: 978-1-62708-184-9
... internals, and the external recirculation piping. Emphasis is placed on materials degradation due to EAC under various combinations of materials, environmental, and stressing conditions. Under static loading conditions EAC is subcategorized as “stress-corrosion cracking” (SCC), or “irradiation-assisted...
Abstract
This article focuses on the environmentally assisted cracking (EAC) of structural materials in boiling water reactors (BWRs), reactor pressure vessels, core internals, and ancillary piping. It discusses the effects of water chemistry on materials degradation, mitigation approaches, and their impact on aging management programs. The article reviews the effects of materials, environment, and stress factors on the cracking susceptibility of ferritic and austenitic structural alloys in BWRs. It describes the methods, such as data-based life-prediction approaches and mechanisms-informed life-prediction approaches, for predicting cracking kinetics in BWRs. The article provides information on several EAC mitigation techniques for BWR components, namely material solutions, stress solutions, and environmental solutions.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003540
EISBN: 978-1-62708-180-1
... overload fracture can be influenced by various time- or temperature-dependent mechanisms, such as fatigue, stress-corrosion cracking (SCC), liquid-metal embrittlement, solid-metal embrittlement, hydrogen embrittlement, and creep. In addition, transgranular cracks also can, at some point, follow a grain...
Abstract
This article briefly reviews the various metallurgical or environmental factors that cause a weakening of the grain boundaries and, in turn, influence the occurrence of intergranular (IG) fractures. It discusses the mechanisms of IG fractures, including the dimpled IG fracture, the IG brittle fracture, and the IG fatigue fracture. The article describes some typical embrittlement mechanisms that cause the IG fracture of steels.
Book Chapter
Corrosion in Petroleum Refining and Petrochemical Operations
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004211
EISBN: 978-1-62708-184-9
... (SCC), velocity-accelerated corrosion, erosion-corrosion, and corrosion control is provided herein. Materials Selection The selection of materials of construction has a significant impact on the operability, economics, and reliability of refining units and petrochemical plants. For this reason...
Abstract
This article presents the primary considerations and mechanisms for corrosion and explains how they are involved in the selection of materials for process equipment in refineries and petrochemical plants. It discusses the material selection criteria for a number of ferrous and nonferrous alloys used in petroleum refining and petrochemical applications. The article reviews the mechanical properties, fabricability, and corrosion resistance of refinery steels. It describes low- and high-temperature corrosion, hydrogen embrittlement, and cracking such as stress-corrosion, sulfide stress, and stress-oriented hydrogen-induced cracking. The article considers hydrogen attack, corrosion fatigue, and liquid metal embrittlement and the methods of combating them. It explains the causes of velocity-accelerated corrosion and erosion-corrosion. The article summarizes some corrective measures that can be implemented to control corrosion. The applicable standards for materials used in corrosive service conditions in upstream and downstream petroleum service are presented in a tabular form.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006777
EISBN: 978-1-62708-295-2
... of environmental conditions, such as hydrogen embrittlement, stress-corrosion cracking (SCC), and corrosion. If the process occurs by oxidation or dissolution, it is corrosion. If the cracking is exacerbated by corrosion and the simultaneous presence of an applied or residual tensile stress, then it is regarded...
Abstract
This article briefly reviews the factors that influence the occurrence of intergranular (IG) fractures. Because the appearance of IG fractures is often very similar, the principal focus is placed on the various metallurgical or environmental factors that cause grain boundaries to become the preferred path of crack growth. The article describes in more detail some typical mechanisms that cause IG fracture. It discusses the causes and effects of IG brittle cracking, dimpled IG fracture, IG fatigue, hydrogen embrittlement, and IG stress-corrosion cracking. The article presents a case history on IG fracture of steam generator tubes, where a lowering of the operating temperature was proposed to reduce failures.
Book Chapter
Design for Corrosion Resistance
Available to PurchaseSeries: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002471
EISBN: 978-1-62708-194-8
... in determining potential corrosion mitigation actions. Thus, a brief review of the equilibrium thermodynamics at the metal/solution interface is given below, because it is relevant to the arguments that are given in a later section of this article, “Forms of Corrosion and General Mitigation Approaches...
Abstract
This article discusses the principles of corrosion and the basis of the various prevention measures that can be taken for different corrosion modes. It describes aqueous corrosion phenomena in terms of the electrochemical reactions that occur at the metal-environment interface. The article explains the specific forms of corrosion, including general corrosion, localized attack, and environmentally assisted cracking. It provides a discussion on the engineering aspects of design that can, without due care and attention, precipitate unexpected premature failure. The article reviews ways to improve corrosion awareness and prevent corrosion/degradation. It describes a life prediction method with an example of environmental degradation in light-water nuclear reactors. The article concludes with a discussion on the validation of life-prediction algorithms and their applications.
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