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PAN-based carbon fibers

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Book Chapter

By Paul J. Walsh
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0009241
EISBN: 978-1-62708-195-5
... Abstract The earliest commercial use of carbon fibers is often attributed to Thomas Edison's carbonization of cotton and bamboo fibers for incandescent lamp filaments. This article describes the manufacture of PAN-based carbon fibers and pitch-based carbon fibers. It discusses the properties...
Image
Published: 01 January 2001
Fig. 2 The undulating ribbon structure of the graphene layers for a PAN-based carbon fiber with a 400 GPa (600 × 10 6 psi) modulus. The ribbons at the surface have lower amplitude than in the core. There are about 20 graphene layers in the ribbons in the core and about 30 near the surface. More
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003034
EISBN: 978-1-62708-200-6
... strengths, and flexural modulus especially, also closely follow fiber properties. However, compressive-strength properties show a distinct pattern of higher values produced by fiberglass reinforcement, followed by polyacrylonitrile (PAN)-based carbon fiber materials. Aramid fiber compounds have lower...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003064
EISBN: 978-1-62708-200-6
.... These thermal characteristics influence the processing sequences that are used to convert PAN precursors to carbon fiber. Carbon fiber based on a PAN precursor generally has a higher tensile strength than a fiber based on any other precursor. This is due to a lack of surface defects, which act as stress...
Image
Published: 01 January 1990
Fig. 5 Carbon fiber axial modulus versus axial coefficient of thermal expansion for mesophase (pitch-base) and polyacrylonitride-base (pan-base) graphite fibers. Source: Ref 18 More
Book Chapter

Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003370
EISBN: 978-1-62708-195-5
...- (PAN-) based carbon-fiber materials. Aramid- fiber compounds have lower compressive- strength values. PAN-based carbon fibers, being brittle, demonstrate the lowest Izod impact strength. Glass fibers have higher elongation values than aramid fibers, but are notch sensitive. The toughness of aramid...
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006897
EISBN: 978-1-62708-392-8
.... Properties of polyacrylonitrile (PAN) and pitch-based carbon fibers are shown in Table 2 . Carbon fibers are approximately 5 to 10 mm (0.2 to 0.4 in.) in diameter and are usually composed of carbon atoms. Carbon fibers have several benefits, including excessive stiffness, high tensile energy, low weight...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003033
EISBN: 978-1-62708-200-6
... precursors to carbon fiber. Carbon fiber based on a PAN precursor generally has a higher tensile strength than a fiber based on any other precursor. This is due to a lack of surface defects, which act as stress concentrators and therefore reduce tensile strength. Pitch Precursors Pitch precursors...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003031
EISBN: 978-1-62708-200-6
... economical fibers because the carbon yield is higher and because PAN-based fibers do not intrinsically require a final high-temperature “graphitization” step ( Ref 5 ). The patent literature abounds with the wide range of precursor materials that can be used to make carbon fibers. A great hope...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003359
EISBN: 978-1-62708-195-5
... loss of fiber properties. More expansive coverage of these fibers is provided in the article “Ceramic Fibers” in this Volume. Carbon Fibers Two classes of carbon fiber, polyacrylonitrile (PAN) and pitch-based fibers, derive quite different structures and properties: the PAN being higher...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001318
EISBN: 978-1-62708-170-2
... the 1980s, a significant level of research activity focused on the protection of high-performance carbon-carbon that used heat-stabilized polyacrylonitrile (PAN) or pitch-based fibers. These composites have higher strength, higher elastic moduli, and lower thermal expansion coefficients than the rayon-based...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003449
EISBN: 978-1-62708-195-5
... commercially available PAN- based carbon fibers. In C-C composites, the strain-to-failure of the carbon matrix is typically much lower than that of the reinforcing fibers, and as noted earlier the matrix is frequently microcracked as a result of thermal expansion mismatch stresses created during processing...
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006673
EISBN: 978-1-62708-213-6
... of two primary components: a microbalance and a furnace ( Fig. 1 ). The sample is suspended from the balance while heated in conjunction with a thermal program. A ceramic or, more often, a platinum sample pan is used for the evaluation. As part of the TGA evaluation, the sample is usually heated from...
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006939
EISBN: 978-1-62708-395-9
...-based carbon fibers typically exhibit better tensile and compressive properties when compared to fibers made from other sources ( Ref 13 , 19 ). The PAN-based carbon fibers are manufactured from polymerized PAN filaments, which are heated to 300 °C (570 °F) in air ( Ref 19 , 20 ). This process...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003474
EISBN: 978-1-62708-195-5
... in the future until fuel-cell technology is perfected. Fig. 11 Composite fuel storage tank. Reprinted by permission from the Society for the Advancement of Material and Process Engineering (SAMPE) Lower-Cost Carbon Fibers The composite materials supply base has taken initiatives to produce good...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003422
EISBN: 978-1-62708-195-5
..., polyacrylonitrile (PAN), or petroleum pitch and have a wide range of properties. For example, the elastic modulus along the fiber axis ranges from approximately 41.4 GPa (6 × 10 6 psi) for rayon fibers to 414 GPa (60 × 10 6 psi) for heat-stabilized PAN to 690 GPa (100 × 10 6 psi) for pitch fibers. The axial...
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006895
EISBN: 978-1-62708-392-8
.... , Process and Apparatus for Preparing Artificial Threads , Google Patents , 1934 20. Gouma P.-I.P. , Electrospinning: A Novel Nanomanufacturing Technique for Hybrid Nanofibers and Their Non-Woven Mats , Nanomaterials for Chemical Sensors and Biotechnology , Pan Stanford Publishing Pte. Ltd...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003480
EISBN: 978-1-62708-195-5
... heat pipes in transporting heat over relatively short distances. An additional benefit is that solid-state methods of heat transfer are more reliable. Carbon Fibers The most important types of commercial carbon fibers at this time are made from polyacrylonitrile (PAN) and pitches derived from...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003350
EISBN: 978-1-62708-195-5
... carbon structure. Rayon has been largely supplanted as a precursor by polyacrylonitrile (PAN). Polyacrylonitrile precursors produce much more economical fibers because the carbon yield is higher and because PAN-based fibers do not intrinsically require a final high-temperature “graphitization” step...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003019
EISBN: 978-1-62708-200-6
... fabricated by this technique ( Ref 9 , 10 ) is shown in Fig. 6 . Fig. 6 SMC structural floor pan The limitations for using compression molding of SMC-type materials in truly structural applications are not yet well established. Assuming that continuous fiber is strategically incorporated...