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Daniel J. Benac, V.P. Swaminathan, Ph.D.
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Oxide scales
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Image
Published: 31 October 2011
Fig. 18 Oxide scales cut with O 2 assist gas have a shiny, dark-blue appearance and flake off from the cut edge. They are detrimental to downstream painting and welding operations. Gouging leaves deep crevices that flare in the direction of the assist gas flow; they usually indicate excess
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Image
Parabolic oxidation rate of various oxide scales (Arrhenius plot). The rela...
Available to PurchasePublished: 01 January 1997
Fig. 1 Parabolic oxidation rate of various oxide scales (Arrhenius plot). The relationship between k ″ and k p (parabolic rate constant described by Eq 3 ) is k ″ = (8/V) 3 k p , where V is the equivalent volume of the oxide. Source: Ref 1
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Image
Distribution map of yttrium in the oxide scale of an iron-base oxide-disper...
Available to PurchasePublished: 01 December 2004
Fig. 12 Distribution map of yttrium in the oxide scale of an iron-base oxide-dispersion-strengthened superalloy. During annealing at high temperatures (1100 °C, or 2010 °F) in air, yttrium diffuses along cracks to the surface of the oxide scale. In the alloy, yttrium is distributed
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Image
Variation of the oxidation rate and oxide scale structure with alloy chromi...
Available to PurchasePublished: 01 January 2003
Fig. 6 Variation of the oxidation rate and oxide scale structure with alloy chromium content (based on isothermal studies at 1000 °C, or 1832 °F, in 0.13 atm oxygen)
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Image
Steamside oxide scale buildup thickness versus thermocouple measurements fo...
Available to Purchase
in Elevated-Temperature Life Assessment for Turbine Components, Piping, and Tubing
> Failure Analysis and Prevention
Published: 01 January 2002
Fig. 37 Steamside oxide scale buildup thickness versus thermocouple measurements for a 2 1 4 Cr-1Mo tube compared to predicted values using a code
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Image
Effect of thickness of surface oxide scale on the heat-transfer coefficient...
Available to PurchasePublished: 01 August 2013
Fig. 35 Effect of thickness of surface oxide scale on the heat-transfer coefficient during spray cooling of hot steel plate. Source: Ref 110
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Image
Flaking of oxide scale during water quenching of S45C carbon steel. Water t...
Available to PurchasePublished: 01 August 2013
Fig. 37 Flaking of oxide scale during water quenching of S45C carbon steel. Water temperature is 30 °C (85 °F). Test specimen is a solid cylinder 10 mm (0.4 in.) in diameter by 30 mm (1.2 in.) in length. (a) Light oxide coating after heating for 3 min at 860 °C (1580 °F) in air in argon gas
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Image
Backscattered electron image of oxide scale layer on steel. Note the phases...
Available to Purchase
in Metallography and Microstructures of Carbon and Low-Alloy Steels[1]
> Metallography and Microstructures
Published: 01 December 2004
Fig. 29 Backscattered electron image of oxide scale layer on steel. Note the phases in the layer. Unetched. Original magnification 360×
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Image
Classic chemical compositions and structures of oxide scale on carbon and s...
Available to PurchasePublished: 31 December 2017
Fig. 19 Classic chemical compositions and structures of oxide scale on carbon and stainless steels. Source: Ref 78
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Illustration of oxide scale growth on hot-rolled carbon steel strip in five...
Available to PurchasePublished: 31 December 2017
Fig. 20 Illustration of oxide scale growth on hot-rolled carbon steel strip in five-stand finishing rolling mill. FET, finishing-mill entry temperature; FXT, finishing-mill exit temperature; ROT, run-out table. Source: Ref 74
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Image
Mechanism of oxide-scale deformation behavior in the roll bite in hot rolli...
Available to PurchasePublished: 31 December 2017
Fig. 23 Mechanism of oxide-scale deformation behavior in the roll bite in hot rolling of stainless steel with ZDDP (zinc dialkyl dithio phosphate) lubricant films. Source: Ref 108
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Photographs illustrating the oxide scale (a) partly separated from the spec...
Available to PurchasePublished: 01 December 2009
Fig. 7 Photographs illustrating the oxide scale (a) partly separated from the specimen and (b) transferred to the tool after being in contact during compression test at 870 °C. (c) Oxide scale pattern predicted at exit from the roll gap. Note the pick-up effect. Source: Ref 102
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Image
Closer view of elbow inner surface. (a) Overview, uniform oxide scale, and ...
Available to Purchase
in Failures of Pressure Vessels and Process Piping
> Analysis and Prevention of Component and Equipment Failures
Published: 30 August 2021
Fig. 71 Closer view of elbow inner surface. (a) Overview, uniform oxide scale, and corroded areas. USGW, upstream girth weld; DSGW, downstream girth weld. (b) Severe corrosion occurred around the DSGW at 12 o’clock. (c) Brittle oxide scale chipped by flow/particle impingement. (d) Mill
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Image
Paralinear oxidation. Scale growth (mass) is initially parabolic and become...
Available to PurchasePublished: 01 January 2003
Fig. 1 Paralinear oxidation. Scale growth (mass) is initially parabolic and becomes linear with time.
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Image
Multilayer oxide scale formed on Co-10Cr alloy at 1100 °C (2012 °F). Outer ...
Available to PurchasePublished: 01 January 2003
Fig. 7 Multilayer oxide scale formed on Co-10Cr alloy at 1100 °C (2012 °F). Outer layer is CoO; inner (mottled gray) layer is CoO containing dissolved chromium and particles of Co-Cr spinel. The chromium level in this alloy is insufficient to form a fully protective Cr 2 O 3 scale. Courtesy
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Image
Topography (a) and cross section (b) of oxide scale formed on Fe-18Cr alloy...
Available to PurchasePublished: 01 January 2003
Fig. 8 Topography (a) and cross section (b) of oxide scale formed on Fe-18Cr alloy at 1100 °C (2012 °F). The bright areas on the alloy surface (a) are areas from which scale has spalled. The buckled scale and locally thickened areas (b) are iron-rich oxide. The thin scale layer adjacent
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Image
Published: 01 June 2024
Fig. 65 Top-left portion of Fig. 64 . Gray high-temperature oxide scale is present inside the crack. 2% nital etch. Original magnification: 400×. Source: Ref 28
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003590
EISBN: 978-1-62708-182-5
... Abstract This article examines the characteristics and behavior of scale produced by various types of oxidation. The basic models, concepts, processes, and open questions for high-temperature gaseous corrosion are presented. The article describes the development of geometrically induced growth...
Abstract
This article examines the characteristics and behavior of scale produced by various types of oxidation. The basic models, concepts, processes, and open questions for high-temperature gaseous corrosion are presented. The article describes the development of geometrically induced growth stresses, transformation stresses, and thermal stresses in oxide scales. It discusses the ways in which stresses can be relieved. The article provides information on catastrophic oxidation, internal oxidation, sulfidation, alloy oxidation, selective oxidation, and concurrent oxidation. It illustrates the relationships between scale morphologies on binary alloys and concludes with a discussion on metal dusting and chlorine corrosion.
Book Chapter
Interface Effects for Deformation Processes
Available to PurchaseSeries: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005417
EISBN: 978-1-62708-196-2
.... The article describes the behavior of oxide scale on the surface of hot metal undergoing thermomechanical processing. It concludes with information on the effects of process and material parameters on interfacial phenomena. deformation metal-forming microforming surface interactions friction...
Abstract
This article examines the deformation processes in metal-forming operations and considers the effects introduced by scale factors when microforming. It discusses the process parameters and variables affecting surface interactions, including temperature, speed, reduction, stiffness, and dynamic response of equipment. The article reviews the determination of friction coefficient using laboratory monitoring methods, indirect measurements, and the inverse method. It considers the determination of the interface heat-transfer coefficient by using the ring test and computer simulations. The article describes the behavior of oxide scale on the surface of hot metal undergoing thermomechanical processing. It concludes with information on the effects of process and material parameters on interfacial phenomena.
Book Chapter
Elevated-Temperature Life Assessment for Turbine Components, Piping, and Tubing
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003517
EISBN: 978-1-62708-180-1
... evaluations, the creep cavitation damage assessment, the oxide-scale-based life prediction, and high-temperature crack growth methods. coating evaluation creep cavitation damage assessment elevated-temperature failure gas turbine blade hardness testing high-temperature crack growth methods life...
Abstract
This article focuses on the life assessment methods for elevated-temperature failure mechanisms and metallurgical instabilities that reduce life or cause loss of function or operating time of high-temperature components, namely, gas turbine blade, and power plant piping and tubing. The article discusses metallurgical instabilities of steel-based alloys and nickel-base superalloys. It provides information on several life assessment methods, namely, the life fraction rule, parameter-based assessments, the thermal-mechanical fatigue, coating evaluations, hardness testing, microstructural evaluations, the creep cavitation damage assessment, the oxide-scale-based life prediction, and high-temperature crack growth methods.
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