This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength is affected by the condition of the grain boundaries and, in particular, the grain-boundary carbide morphology and distribution. Vacuum induction melting offers more control over alloy composition and homogeneity than all other vacuum melting processes. The primary purification reaction occurring in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy components is precisely controlled so that the microstructure, which ultimately determines mechanical properties, remains consistent. Heat treating cast superalloys involves homogenization and solution heat treatments or aging heat treatments.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

This article describes the metallurgy and microstructure of high-performance cobalt-base alloys. It discusses metallographic preparation procedures, including sectioning, mounting, grinding, polishing, etching, staining, and heat tinting. It examines the microstructure of cobalt alloys in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys.

Superalloys are nickel, iron-nickel, and cobalt-base alloys generally used for high-temperature applications. Superalloys are used in aircraft, industrial, marine gas turbines, nuclear reactors, spacecraft structures, petrochemical production, orthopedic and dental prostheses, and environmental protection applications. This article discusses the material characteristics, phases, structures, and systems of superalloys. It describes the processing of superalloys, including primary and secondary melting, deformation processing (conversion), powder processing, investment casting, and joining methods. The article also describes the properties, microstructure, and thermal exposure of superalloys. It further discusses the effects of environmental factors on superalloys, including oxidation and hot corrosion. Protective coatings are also discussed. The article provides information on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms.

This article focuses primarily on the various steps involved in the brazing of heat-resistant alloys (nickel- and cobalt-base alloys). The major steps include the selection of brazing filler metals, surface cleaning and preparation, brazing processes and their corresponding atmospheres, and fixturing. The article also provides an overview of the brazing of blow-alloy steels and tool steels and oxide dispersion-strengthened alloys.

This article focuses on common failures of the components associated with the flow path of industrial gas turbines. Examples of steam turbine blade failures are also discussed, because these components share some similarities with gas turbine blading. Some of the analytical methods used in the laboratory portion of the failure investigation are mentioned in the failure examples. The topics covered are creep, localized overheating, thermal-mechanical fatigue, high-cycle fatigue, fretting wear, erosive wear, high-temperature oxidation, hot corrosion, liquid metal embrittlement, and manufacturing and repair deficiencies.

When metal is exposed to an oxidizing gas at elevated temperature, corrosion can occur by direct reaction with the gas, without the need for the presence of a liquid electrolyte. This type of corrosion is referred to as high-temperature gaseous corrosion. This article describes the various forms of high-temperature gaseous corrosion, namely, high-temperature oxidation, sulfidation, carburization, corrosion by hydrogen, and hot corrosion.

The selection of engineered materials is an integrated process that requires an understanding of the interaction between materials properties, manufacturing characteristics, design considerations, and the total life cycle of the product. This article classifies various engineered materials, including ferrous alloys, nonferrous alloys, ceramics, cermets and cemented carbides, engineering plastics, polymer-matrix composites, metal-matrix composites, ceramic-matrix and carbon-carbon composites, and reviews their general property characteristics and applications. It describes the synergy between the elements of the materials selection process and presents a general comparison of material properties. Finally, the article provides a short note on computer aided materials selection systems, which help in proper archiving of materials selection decisions for future reference.

This article focuses on the monolithic form of nonferrous alloys, including aluminum, copper, nickel, cobalt, titanium, zinc, magnesium, and beryllium alloys. Each metal and alloy offers unique combinations of useful physical, chemical, and structural properties that are made available by its particular composition and the proper choice of processing method. The article describes the composition, designation system, properties, and processing method of these metals and alloys. It discusses the effect of alloying elements in these alloys. The article explains microstructure/property relationships that are used to make specific properties available to the designers of structural applications. It provides examples of phase diagrams that illustrate eutectic and peritectic reactions.

This article focuses on the life assessment methods for elevated-temperature failure mechanisms and metallurgical instabilities that reduce life or cause loss of function or operating time of high-temperature components, namely, gas turbine blade, and power plant piping and tubing. The article discusses metallurgical instabilities of steel-based alloys and nickel-base superalloys. It provides information on several life assessment methods, namely, the life fraction rule, parameter-based assessments, the thermal-mechanical fatigue, coating evaluations, hardness testing, microstructural evaluations, the creep cavitation damage assessment, the oxide-scale-based life prediction, and high-temperature crack growth methods.

This article provides a discussion on cutting tools, their materials and design; cutting fluids; and various aspects of machining operations of heat-resistant alloys, with several examples. Operations such as turning, planing and shaping, broaching, drilling, reaming, counterboring and spotfacing, tapping and thread milling, milling, sawing, and grinding are discussed. Nominal compositions of wrought heat-resistant alloys and nickel-base heat-resistant casting alloys, as well as compositions of cobalt-base heat-resistant casting, iron-base heat-resistant casting, and mechanically alloyed (oxide dispersion strengthened) products are also listed.

Analysis of the failure of a metal structure or part usually requires identification of the type of failure. Failure can occur by one or more of several mechanisms, including surface damage (such as corrosion or wear), elastic or plastic distortion, and fracture. This leads to a wide range of failures, including fatigue failure, distortion failure, wear failure, corrosion failure, stress-corrosion cracking, liquid-metal embrittlement, hydrogen-damage failure, corrosion-fatigue failure, and elevated-temperature failure. This article describes the classification of fractures on a macroscopic scale as ductile fractures, brittle fractures, fatigue fractures, and fractures resulting from the combined effects of stress and environment.