This article explains the main types and characteristic causes of failures in boilers and other equipment in stationary and marine power plants that use steam as the working fluid with examples. It focuses on the distinctive features of each type that enable the failure analyst to determine the cause and suggest corrective action. The causes of failures include tube rupture, corrosion or scaling, fatigue, erosion, and stress-corrosion cracking. The article also describes the procedures for conducting a failure analysis.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

The presence of certain impurities in coal and oil is responsible for the majority of fireside corrosion experienced in utility boilers. In coal, the primary impurities are sulfur, alkali metals, and chlorine. The most detrimental impurities in fuel oil are vanadium, sodium, sulfur, and chlorine. This article describes the two categories of fireside corrosion based on location in the furnace: waterwall corrosion in the lower furnace and fuel ash corrosion of superheaters and reheaters in the upper furnace. It discusses prevention methods, including changes to operating parameters and application of protective cladding or coatings.

This article describes the corrosion modes in a waste-to-energy boiler. It discusses the corrosion protection and alloy performance with an emphasis on two main areas of the boiler: furnace water walls and super heaters.

Failures in boilers and other equipment taking place in power plants that use steam as the working fluid are discussed in this article. The discussion is mainly concerned with failures in Rankine cycle systems that use fossil fuels as the primary heat source. The general procedure and techniques followed in failure investigation of boilers and related equipment are discussed. The article is framed with an objective to provide systematic information on various damage mechanisms leading to the failure of boiler tubes, headers, and drums, supplemented by representative case studies for a greater understanding of the respective damage mechanism.

This article discusses the specimen preparation of three types of cast and wrought heat-resistant alloys: iron-base, nickel-base, and cobalt-base. Specimen preparation involves sectioning, mounting, grinding, polishing, and etching. The article illustrates the microstructural constituents of cast and wrought heat-resistant alloys. It describes the identification of ferrite by magnetic etching. The transmission electron microscopy examination of the fine strengthening phases in wrought alloys and bulk extraction in heat-resistant alloys are included. The article also reviews the gamma prime phase, gamma double prime phase, eta phase, laves phase, sigma phase, mu phase, and chi phase in wrought heat-resistant alloys.

This article describes metallographic preparation and examination techniques for stainless steels and maraging steels. It presents a series of micrographs demonstrating microstructural features of these alloys. Procedures used to prepare stainless steels for macroscopic and microscopic examination are similar to those used for carbon, alloy, and tool steels. Cutting and grinding must be carefully executed to minimize deformation because the austenitic grades work harden readily. The high-hardness martensitic grades that contain substantial undissolved chromium carbide are difficult to polish while fully retaining the carbides. Unlike carbon, alloy, and tool steels, etching techniques are more difficult due to the high corrosion resistance of stainless steels and the various second phases that may be encountered. The microstructures of stainless steels can be quite complex. Matrix structures vary according to the type of steel, such as ferritic, austenitic, martensitic, precipitation hardenable, or duplex.