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Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003556
EISBN: 978-1-62708-180-1
... coatings designed to prevent wear or corrosion in an operating system, or the alteration of flow regimes and heat-transfer coefficients due to the biological fouling of metal surfaces. Given the potential impact of MIC on a wide range of industrial operations, it is not surprising that microbiological...
Abstract
This article focuses on the mechanisms of microbially induced or influenced corrosion (MIC) of metallic materials as an introduction to the recognition, management, and prevention of microbiological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It discusses the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling and analysis of conditions usually achieved by the installation of removable coupons in the target system. The article also explains the prevention and control strategies of MIC in industrial systems.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006788
EISBN: 978-1-62708-295-2
... Abstract This article focuses on the mechanisms of microbiologically influenced corrosion as a basis for discussion on the diagnosis, management, and prevention of biological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It begins with an overview of the scope...
Abstract
This article focuses on the mechanisms of microbiologically influenced corrosion as a basis for discussion on the diagnosis, management, and prevention of biological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It begins with an overview of the scope of microbial activity and the corrosion process. Then, various mechanisms that influence corrosion in microorganisms are discussed. The focus is on the incremental activities needed to assess the role played by microorganisms, if any, in the overall scenario. The article presents a case study that illustrates opportunities to improve operating processes and procedures related to the management of system integrity. Industry experience with corrosion-resistant alloys of steel, copper, and aluminum is reviewed. The article ends with a discussion on monitoring and preventing microbiologically influenced corrosion failures.
Image
Anaerobic biological corrosion of cast iron. (a) Cast iron pipe section exh...
Available to PurchasePublished: 01 January 2003
Fig. 13 Anaerobic biological corrosion of cast iron. (a) Cast iron pipe section exhibiting external pitting caused by bacteria. (b) Cast iron pipe showing penetration by bacteria-induced pitting corrosion. Source: Ref 10
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Image
Localized biological corrosion of austenitic stainless steel. (a) Crevice c...
Available to PurchasePublished: 01 January 2003
Fig. 16 Localized biological corrosion of austenitic stainless steel. (a) Crevice corrosion of type 304 stainless steel flange from a cooling water system. Staining shows evidence of adjacent biomounds. The corrosion attack reached a depth of 6 mm ( 1 4 in.). Courtesy of W.K. Link
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Image
Rate of corrosion of unprotected steel in biologically active soil as a fun...
Available to PurchasePublished: 01 January 2002
Fig. 5 Rate of corrosion of unprotected steel in biologically active soil as a function of iron sulfide present
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003637
EISBN: 978-1-62708-182-5
... of the documented cases in which biological organisms are the sole cause of, or an accelerating factor in, corrosion involve localized forms of attack. One reason for this is that organisms usually do not form in a continuous film on the metal surface. Additional information on biofilms can be found in the section...
Abstract
This article focuses on the effects of microscopic organisms and the by-products they produce on the electrochemical corrosion of metals. The general characteristics of the microorganisms that facilitate their influence on the electrochemistry of corrosion are discussed. The industries most often reported as being affected by microbiological corrosion are listed, along with the organisms usually implicated in the attack. The article explains that the influence of organisms can be addressed successfully for a corrosion control program by using four types of evidence: metallurgical, microbiological, chemical, and electrochemical. It provides information on the microbiologically influenced corrosion (MIC) of irons and steels, passive alloys (austenitic stainless steels), aluminum alloys, copper alloys, and composites. The article reviews the formation of microbial biofilms and macrofouling films. It also describes the general approaches taken to prevent MIC.
Book Chapter
Corrosion Performance of Stainless Steels, Cobalt, and Titanium Alloys in Biomedical Applications
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004207
EISBN: 978-1-62708-184-9
.... The article illustrates the interfacial structure of a biomaterial surface contacting with the biological environment. It describes the corrosion behavior of stainless steel, cobalt-base alloy, and titanium alloys. The electrochemical methods used for studying metallic biomaterials corrosion are also...
Abstract
This article tabulates the chemical composition of iron-base, titanium-base, and cobalt-base alloys and illustrates the microstructures of these materials. It discusses the surface morphology and chemistry of oxide-film-covered alloys and provides insights into the interaction. The article illustrates the interfacial structure of a biomaterial surface contacting with the biological environment. It describes the corrosion behavior of stainless steel, cobalt-base alloy, and titanium alloys. The electrochemical methods used for studying metallic biomaterials corrosion are also discussed. The article concludes with information on the biological consequences of in vivo corrosion and biocompatibility.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004105
EISBN: 978-1-62708-184-9
... of biological fouling organisms take place directly at the metal/water interface where the corrosion occurs, not in the bulk water. This means that the chemical environment in which the corrosion reactions occur in the presence of a micro- or macrofouling film may bear little resemblance to that of the bulk...
Abstract
This article discusses the general properties of ocean water and their effects on corrosion. It describes the major and minor features of the ocean water on corrosion, including the effects of variability, pollutants, and fouling organisms. Effects of water flow velocity on marine corrosion are also reviewed.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004106
EISBN: 978-1-62708-184-9
... of corrosion standards proposed by the International Standards Organization (ISO). This article focuses on the important variables associated with atmospheric corrosion in marine atmospheres, namely, moisture, temperature, winds, airborne contaminants, alloy content, location, and biological organisms along...
Abstract
Several factors contribute to marine-atmospheric corrosion with the local environment being the single most important factor. Therefore, assessing a local environment, which is essential to reduce the gross expenditure, is assisted by modeling of the local environment and by a set of corrosion standards proposed by the International Standards Organization (ISO). This article focuses on the important variables associated with atmospheric corrosion in marine atmospheres, namely, moisture, temperature, winds, airborne contaminants, alloy content, location, and biological organisms along with their corresponding assessing methods. It also examines the ISO CORRAG program for modeling the corrosion rate of atmospheric corrosion that is represented as equations modeling.
Book Chapter
Corrosion Fatigue and Stress-Corrosion Cracking in Metallic Biomaterials
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004208
EISBN: 978-1-62708-184-9
... Abstract This article provides information on biomedical aspects such as active biological responses and the chemical environment characterizing the internal physiological milieu, as well as electrochemical fundamentals needed for characterizing corrosion fatigue (CF) and stress-corrosion...
Abstract
This article provides information on biomedical aspects such as active biological responses and the chemical environment characterizing the internal physiological milieu, as well as electrochemical fundamentals needed for characterizing corrosion fatigue (CF) and stress-corrosion cracking (SCC). It discusses some of the mechanical and electrochemical phenomena related to the in vivo degradation of materials used for biomedical applications. These materials include stainless steels, cobalt and titanium-base alloy systems, and dental amalgam. The article addresses key issues related to the simulation of the in vivo environment, service conditions, and data interpretation. The factors influencing susceptibility to CF and SCC are reviewed. The article describes the testing methodology of CF and SCC. It also summarizes findings from laboratory testing, in vivo testing and retrieval studies related to CF and SCC.
Image
Rate of corrosion for steel sustained over a six-week period in biologicall...
Available to PurchasePublished: 15 January 2021
Fig. 5 Rate of corrosion for steel sustained over a six-week period in biologically active, wet, high-clay soil as a function of iron sulfide present under anaerobic conditions in laboratory tests. SRB, sulfate-reducing bacteria
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Book Chapter
Accelerated Life Testing and Aging
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006909
EISBN: 978-1-62708-395-9
...., alkalis and acids), ionizing radiation, and biological degradation, along with the combined effects of mechanical stress, temperature, and moisture (including environmental stress corrosion). The article also includes information on the use of accelerated testing for predicting material property...
Abstract
Accelerated life testing and aging methodologies are increasingly being used to generate engineering data for determining material property degradation and service life (or fitness for purpose) of plastic materials for hostile service conditions. This article presents an overview of accelerated life testing and aging of unreinforced and fiber-reinforced plastic materials for assessing long-term material properties and life expectancy in hostile service environments. It considers various environmental factors, such as temperature, humidity, pressure, weathering, liquid chemicals (i.e., alkalis and acids), ionizing radiation, and biological degradation, along with the combined effects of mechanical stress, temperature, and moisture (including environmental stress corrosion). The article also includes information on the use of accelerated testing for predicting material property degradation and long-term performance.
Image
Cracks emanating from pits in a type 304 stainless steel tank that was plac...
Available to PurchasePublished: 01 January 2003
Fig. 18 Cracks emanating from pits in a type 304 stainless steel tank that was placed in hot demineralized water service with an operating temperature that fluctuated from 75 to 90 °C (165 to 195 °F). (a) Micrograph of a section through a typical biological deposit and pit in the wall
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Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005659
EISBN: 978-1-62708-198-6
... ), such as heparin, an anticoagulant. Materials The number of materials used in currently approved implant devices is relatively small because of the requirement for stability in the biological milieu (resistance to corrosion and degradation) and minimal inflammation in the local tissue response, in addition...
Abstract
This article provides a summary of the biocompatibility or biological response of metals, ceramics, and polymers used in medical implants, along with their clinical issues. The polymers include ultrahigh-molecular-weight polyethylene, nonresorbable polymer, and resorbable polymers.
Book Chapter
Protective Coatings for Corrosion Control in Municipal Wastewater Systems
Available to PurchaseSeries: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006059
EISBN: 978-1-62708-172-6
... amine-cured epoxy coatings. Fig. 5 Concrete attack in sewer. Courtesy of Corrosion Probe, Inc. Secondary Treatment Secondary treatment mainly involves biological treatment of wastewater. Currently, the most extensively used biological processes involve suspended-growth biological...
Abstract
This article provides information on the municipal wastewater system components such as piping, pump stations, headworks, clarifiers, aeration structures, digesters, biosolids dewatering equipment, and sludge stabilization. It explains the major corrosion damage mechanisms to which those component parts of the system are exposed. It presents useful guidelines for selecting and using protective coatings in municipal sewerage collection systems and water reclamation facilities in wastewater treatment plants. The article includes annotated flow diagrams of a wastewater collection system, wastewater treatment plants, and spreadsheets listing the most widely used generic coating systems by structure and substrate material. It concludes with a section on quality watchouts when selecting or using protective coatings in municipal wastewater systems.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005666
EISBN: 978-1-62708-198-6
... addresses the biologic aspects of implant debris, both locally and systemically. It describes debris-induced local effects, particle-induced proinflammatory responses, and debris-induced systemic effects. The article concludes with a discussion on the four systemic effects of implant debris, namely...
Abstract
Implant debris is known to cause local inflammation, local osteolysis, and, in some cases, local and systemic hypersensitivity. The debris can be stainless steel, cobalt alloy, and titanium alloy, and soluble debris obtained due to wear from all orthopedic implants. This article addresses the biologic aspects of implant debris, both locally and systemically. It describes debris-induced local effects, particle-induced proinflammatory responses, and debris-induced systemic effects. The article concludes with a discussion on the four systemic effects of implant debris, namely, neuropathic effects, hypersensitivity effects, carcinogenicity, and general toxicity.
Book Chapter
Additive Manufacturing of Cobalt-Chromium Alloy Biomedical Devices
Available to PurchaseSeries: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006889
EISBN: 978-1-62708-392-8
... between electroanalytical techniques, biological-based testing, and tribological characterization is needed and has been performed. This form of testing is done using an electrochemical (corrosion) cell, a potentiostat, a tribometer, and in-vitro-based media. Some tests are idle; that is, no potential...
Abstract
This article discusses some of the additive manufacturing (AM) based fabrication of alloys and their respective mechanical, electrochemical, and in vivo performance. Firstly, it briefly discusses the three AM techniques that are most commonly used in the fabrication of metallic biomedical-based devices: binder jetting, powder-bed fusion, and directed-energy deposition. The article then characterizes the electrochemical properties of additive-manufactured/processed cobalt-chromium alloys. This is followed by sections providing an evaluation of the biological response to CoCr alloys in terms of the material and 3D printing fabrication. Discussion on the biological response as a function of direct cellular activity on the surface of CoCr alloys in static conditions (in vitro), in dynamic physiological conditions (in vivo), and in computer-simulated conditions (in silico) are further discussed in detail. Finally, the article provides information on the qualification and certification of AM-processed medical devices.
Book Chapter
Biocompatibility, Metals Ions, and Corrosion Products
Available to PurchaseSeries: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005665
EISBN: 978-1-62708-198-6
... Mechanism of Ion Release Various bearing materials release different metallic ions in biological environments. Cobalt-chromium alloys release ions through crevice corrosion, pitting corrosion, or uniform dissolution. Mechanical corrosion, which disrupts the passive layer, can also precipitate...
Abstract
This article describes the corrosion resistance and ion release from main transition metallic bearings used as medical devices. It discusses the main issues associated with the in vivo presence of ions and their biocompatibility during the exposure of patients to different aspects of ion toxicity. These include ion concentration and accumulation in organisms, reactive oxygen species and oxidative stress, and carcinogenicity stimulated by the corrosion process and toxic ions release.
Book Chapter
Biocompatibility of Ceramics
Available to PurchaseSeries: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005655
EISBN: 978-1-62708-198-6
... defined by Williams as “non-viable materials used in a medical device, intended to interact with biological systems” ( Ref 1 ). Ceramics used in such biological applications are commonly referred to as bioceramics. History of Bioceramics Biocompatibility has been defined by Williams as “the ability...
Abstract
Ceramics are used widely in a number of different clinical applications in the human body. This article provides a brief history of the bioceramics field and discusses the classification of bioceramics. These include bioinert ceramics, bioactive ceramics, and bioresorbable ceramics. The article describes third-generation bioceramics, classified by Hench and Polak, such as silicate-substituted hydroxyapatite and bone morphogenic protein-carrying calcium phosphate coatings. It reviews several examination methods used to test the biocompatibility of ceramics, namely, biosafety testing, biofunctionality testing, bioactivity testing, and bioresorbability testing.
Book Chapter
Material Aspects of Additively Manufactured Orthopedic Implants of Titanium Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006908
EISBN: 978-1-62708-392-8
..., printing characteristics and parameters as well as postprinting validation; removal of the many manufacturing material residues and sterilization; physical, chemical, and mechanical assessments of the final devices; and biological considerations of all the final devices including biocompatibility...
Abstract
Additive manufacturing, or three-dimensional printing technologies, for biomedical applications is rather different from other engineering components, particularly for biomedical implants that are intended to be used within the human body. This article contains two sections: "Design and Manufacturing Considerations of 3D-Printed, Commercially Pure Titanium and Titanium Alloy-Based Orthopedic Implants" and "Device Testing Considerations Following FDA Guidance" for additive-manufactured medical devices. These are further subdivided into five major focus areas: materials; design, printing, printing characteristics and parameters as well as postprinting validation; removal of the many manufacturing material residues and sterilization; physical, chemical, and mechanical assessments of the final devices; and biological considerations of all the final devices including biocompatibility.
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