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Doru M. Stefanescu, Jacques Lacaze
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Phase diagrams
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Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006503
EISBN: 978-1-62708-207-5
Abstract
This article provides a thorough review of the physical metallurgy of aluminum alloys and its role in determining the properties and from a design and manufacturing perspective. And its role in include the effects of composition, mechanical working, and/or heat treatment on structure and properties. This article focuses on the effects of alloying and the metallurgical factors on phase constituents, structure, and properties of aluminum alloys. Effects from different combinations of alloying elements are described in terms of relevant alloy phase diagrams. The article addresses the underlying alloying and structural aspects that affect the properties and possible processing routes of aluminum alloys. It provides information on the heat treatment effects on the physical properties of aluminum alloys and the microstructural effects on the fatigue and fracture of aluminum alloys. The important alloying elements and impurities are listed alphabetically as a concise review of major effects.
Book Chapter
The Austenite-to-Pearlite/Ferrite Transformation
Available to PurchaseSeries: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006300
EISBN: 978-1-62708-179-5
Abstract
This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.
Book Chapter
Thermodynamics Principles as Applied to Cast Iron
Available to PurchaseSeries: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006295
EISBN: 978-1-62708-179-5
Abstract
The control of the solidification process of cast iron requires understanding and control of the thermodynamics of the liquid and solid phases and of the kinetics of their solidification, including nucleation and growth. This article addresses issues that allow for the determination of probability of formation and relative stability of various phases. These include the influence of temperature and composition on solubility of various elements in iron-base alloys; calculation of solubility lines, relevant to the construction of phase diagrams; and calculation of activity of various components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems, along with saturation degree and carbon equivalent.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006268
EISBN: 978-1-62708-169-6
Abstract
This article describes the effects of alloying and heat treatment on the metastable transition precipitates that occur in age hardenable aluminum alloys. Early precipitation stages are less well understood than later ones. This article details the aging sequence and characteristics of precipitates that occur in the natural aging and artificial aging of Al-Mg-Si-(Cu) alloys, Al-Mg-Cu alloys, microalloyed Al-Mg-Cu-(Ag, Si) alloys, aluminum-lithium-base alloys, and Al-Zn-Mg-(Cu) alloys. Crystal structure, composition, dimensions, and aging conditions of precipitates are detailed. Effects of reversion, duplex annealing, and retrogression and re-aging are included.
Book Chapter
Yb (Ytterbium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006219
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which ytterbium (Yb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Zn (Zinc) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006220
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which zinc (Zn) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Ta (Tantalum) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006209
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which tantalum (Ta) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Rh (Rhodium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006199
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which rhodium (Rh) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Tb (Terbium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006210
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which terbium (Tb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
La (Lanthanum) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006173
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which lanthanum (La) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Ru (Ruthenium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006200
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which ruthenium (Ru) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Te (Tellurium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006211
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which tellurium (Te) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Intermediate Phases
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006229
EISBN: 978-1-62708-163-4
Abstract
In some phase diagrams, the appearance of several reactions is the result of the presence of intermediate phases. These are phases whose chemical compositions are intermediate between two pure metals, and whose crystalline structures are different from those of the pure metals. This article describes the order-disorder transformation that typically occurs on cooling from a disordered solid solution to an ordered phase. It provides a table that lists selected superlattice structures and alloy phases that order according to each superlattice. The article informs that spinodal decomposition has been particularly useful in the production of permanent magnet materials, because the morphologies favor high magnetic coercivities. It also describes the theory of spinodal decomposition with a simple binary phase diagram.
Book Chapter
S (Sulfur) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006201
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which sulfur (S) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Th (Thorium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006212
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which thorium (Th) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Cd (Cadmium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006153
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which cadmium (Cd) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Introduction to Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006221
EISBN: 978-1-62708-163-4
Abstract
The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can exist as a solid, liquid, and/or gas, depending on the specific combination of temperature and pressure. It describes the accomplishment of conversion between weight percentage and atomic percentage in a binary system by the use of formulas. The article analyzes the effects of alloying on melting/solidification and on solid-state transformations. It explains the construction of phase diagrams by the Gibbs phase rule and the Lever rule. The article also reviews the various types of alloy systems that involve solid-state transformations. It concludes with information on the sources of phase diagram.
Book Chapter
Ni (Nickel) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006189
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which nickel (Ni) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Li (Lithium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006174
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which lithium (Li) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Ti (Titanium) Binary Alloy Phase Diagrams
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006213
EISBN: 978-1-62708-163-4
Abstract
This article is a compilation of binary alloy phase diagrams for which titanium (Ti) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
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