Maraging steels are highly alloyed low-carbon iron-nickel martensite steels that possess an excellent combination of strength and toughness superior to that of most carbon-hardened steels. This article provides a detailed account of the formation of martensite in maraging steels. It discusses the heat treatment of these steels, namely, aging, solution annealing, age hardening, and nitriding. Their hardening during aging has been attributed to two different mechanisms: short-range ordering and precipitation. The article concludes with a discussion on the grain refinement using thermal cycling and transformation-induced plasticity maraging methods.

This article describes the microstructure, properties, and performance of carburized steels, and elucidates the microstructural gradients associated with carbon and hardness gradients. It provides information on case depth measurement, the factors affecting case depth, and the formation and causes of microcracks. The article discusses the effects of alloying elements on hardenability, the effects of excessive retained austenite and massive carbides on fatigue resistance, the effects of residual stresses and internal oxidation on fatigue performance of carburized steels. In addition, the causes of intergranular fracture at austenite grain boundaries and their prevention methods are explored. The article also describes the major mechanisms of bending fatigue crack initiation in carburized steels.

This article provides useful information on the selection of steels for heat treatment in order to achieve the required hardness. It discusses the effects of alloying elements on hardenability using the Grossmann's concept, and presents a discussion on the effects of alloying elements in hot-worked and cold-drawn steels. The article focuses on the selection of carbon and alloy steels based on the function of the alloying elements, and discusses the specific effects of alloying elements in steel in a tabulated form. The depth and degree of hardening (percentage of martensite) are dictated by the engineering stress analysis. Mechanical properties of quenched and tempered steels develop similar tensile properties for all practical purposes for all compositions with the same hardness. The article also provides information on the selection of steels to meet the required hardness, and elucidates the concept of hardenability for wear resistance with the help of graphs.

The heat treatment of steel is based on the physical metallurgical principles that relate to its processing, properties, and structure. The microstructures that result from the heat treatment of steel are composed of one or more phases in which the atoms of iron, carbon, and other elements in steel are associated. This article describes the phases of heat treated steel, and provides information on effect of temperature change and the size of carbon atoms relative to that of iron atoms during the heat treatment.

This article discusses the five basic matrix structures in cast irons: ferrite, pearlite, bainite, martensite, and austenite. The alloying elements, used to enhance the corrosion resistance of cast irons, including silicon, nickel, chromium, copper, molybdenum, vanadium, and titanium, are reviewed. The article provides information on classes of the cast irons based on corrosion resistance. It describes the various forms of corrosion in cast irons, including graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. The cast irons suitable for the common corrosive environments are also discussed. The article reviews the coatings used on cast irons to enhance corrosion resistance, such as metallic, organic, conversion, and enamel coatings. It explains the basic parameters to be considered before selecting the cast irons for corrosion services.

Martensite is a metastable structure that forms during athermal (nonisothermal) conditions. This article reviews the crystallographic theory, morphologies, orientation relationships, habit plane, and transformation temperature of ferrous martensite microstructures. It examines the stages of the tempering process involved in ferrous martensite. The article also describes the formation of the martensite structure in nonferrous systems. It concludes with a discussion on shape memory alloys.

This article describes the fundamentals of titanium metallographic sample preparation. Representative micrographs are presented for each class of titanium alloys, including unalloyed titanium, alpha alloys, alpha-beta alloys, and beta titanium alloys. The article provides information on the macroexamination and microexamination for these alloys. It concludes with a discussion on the several metallographic techniques developed for specific purposes, such as recrystallization studies and microstructure/fracture topography correlations.

The properties of irons and steels are linked to the chemical composition, processing path, and resulting microstructure of the material. Processing is a means to develop and control microstructure by hot rolling, quenching, and so forth. This article describes the role of these factors in both theoretical and practical terms, with particular focus on the role of microstructure in various irons. These include bainite, pearlite, ferfite, martensite, austenite, ferrite-pearlite, ferrite-cementite, ferrite-martensite, graphite, and cementite. The article discusses the evolution of microstructural change in rail steels, cast iron, and steel sheet. It contains tables that list the mechanical properties and compositions of selected steels. The article also discusses the basis of material selection of irons and steels.

This article describes microstructures and microstructure-property relationships in steels. It emphasizes the correlation of microstructure and properties as a function of carbon content and processing in low-alloy steels. The article discusses the iron-carbon phase diagram and the phase transformations that change the structure and properties at varying levels of carbon content. Microstructures described include pearlite, bainite, proeutectoid ferrite and cementite, ferrite-pearlite, and martensite. The article depicts some of the primary processing steps that result in ferrite-pearlite microstructures. It shows the range of hardness levels which may be obtained by tempering at various temperatures as a function of the carbon content of the steel. To reduce the number of processing steps associated with producing quenched and tempered microstructures, new alloying approaches have been developed to produce high-strength microstructures directly during cooling after forging.