This article reviews the factors influencing carburization to improve wear resistance of steel, such as operating temperature, cost, production volume, types of wear, and design criteria. It details the types of wear, namely abrasive wear and adhesive wear. The article discusses the characteristics of carburized steels that affect wear resistance, including hardness, microstructure, retained austenite, and carbides. It also describes the processing considerations for carburization of titanium.

The transformation of austenite of cast irons represents a more complex and less studied subject. This article discusses the general features of the decomposition of austenite into bainite. It describes the heat treatment cycles of austempered cast iron microstructure. The article reviews several factors, such as presence of graphite and austenite grain size, which affect the transformation rate of austenite during austempering of free-graphite cast irons.

This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.

The solidification of hypoeutectic cast iron starts with the nucleation and growth of austenite dendrites, while that of hypereutectic iron starts with the crystallization of primary graphite in the stable system or cementite in the metastable system. This article begins with a discussion on the nucleation and growth of austenite dendrites. It describes the nucleation of lamellar graphite, spheroidal graphite, and austenite-iron carbide eutectic. The article reviews three main graphite morphologies crystallizing from the iron melts during solidification: lamellar (LG), compacted or vermicular (CG), and spheroidal. It discusses the metastable solidification of austenite-iron carbide eutectic and concludes with information on gray-to-white structural transition of cast iron.

The control of the solidification process of cast iron requires understanding and control of the thermodynamics of the liquid and solid phases and of the kinetics of their solidification, including nucleation and growth. This article addresses issues that allow for the determination of probability of formation and relative stability of various phases. These include the influence of temperature and composition on solubility of various elements in iron-base alloys; calculation of solubility lines, relevant to the construction of phase diagrams; and calculation of activity of various components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems, along with saturation degree and carbon equivalent.

This article discusses the characterization of gray iron structures, following the sequence of structure formation, as it applies to unalloyed or low-alloyed gray iron. Austenite grains are the basic crystallographic entities of the metallic matrix in gray cast iron precipitated from the liquid melt. The article describes the macrostructure and dendrite morphology of primary austenite. Eutectoid transformation in the solid state causes the transformation of austenite to pearlite and/or ferrite, producing the as-cast structure. The article discusses the observations of the graphite and ferritic/pearlitic structure in as-cast gray iron.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. This article describes surface hardening of gray irons by flame and induction heating. It provides information on the classification of the gray irons in ASTM specification. The article presents examples that illustrate the use of stress relieving to eliminate distortion and cracking. It describes the three annealing treatments of gray iron: ferritizing annealing, medium (or full) annealing, and graphitizing annealing. The article discusses the parameters of the tensile strength and hardness of a normalized gray iron casting. These include combined carbon content, pearlite spacing, and graphite morphology. The article concludes with a discussion on the induction hardening of gray iron castings.

This article describes the liquidus plots, isothermal plots, and isopleth plots used for a hypothetical ternary phase space diagram. It discusses the single-phase boundary (SPB) line and zero-phase fraction (ZPF) line for carbon-chromium-iron isopleth. The article illustrates the Gibbs triangle for plotting ternary composition and discusses the ternary three-phase phase diagrams by using tie triangles. It describes the peritectic system with three-phase equilibrium and ternary four-phase equilibrium. The article presents representative binary iron phase diagrams, showing ferrite stabilization (iron-chromium) and austenite stabilization (iron-nickel).

The design of a tool-steel part directly affects the susceptibility to shape distortion on heating and cooling. This article provides information on the selection of chemical composition and the effect of composition on size distortion. It explains the various factors considered to control distortion in tools steels, namely, design, initial condition, machining procedure, and heat treatment. Distortion can occur both during and after heat treatment. The article discusses the chief ways to precisely control the extent of distortion by heat treating and auxiliary mechanical methods. Stabilizing treatments, namely, stabilizing by tempering and stabilizing by cold treatment are used to minimize dimensional changes that occur following heat treatment.

This article describes the microstructure, properties, and performance of carburized steels, and elucidates the microstructural gradients associated with carbon and hardness gradients. It provides information on case depth measurement, the factors affecting case depth, and the formation and causes of microcracks. The article discusses the effects of alloying elements on hardenability, the effects of excessive retained austenite and massive carbides on fatigue resistance, the effects of residual stresses and internal oxidation on fatigue performance of carburized steels. In addition, the causes of intergranular fracture at austenite grain boundaries and their prevention methods are explored. The article also describes the major mechanisms of bending fatigue crack initiation in carburized steels.

Low-temperature surface hardening is mostly applied to austenitic stainless steels when a combination of excellent corrosion performance and wear performance is required. This article provides a brief history of low-temperature surface hardening of stainless steel, followed by a discussion on physical metallurgy, including crystallographic identity, thermal stability and decomposition, nitrogen and carbon solubility in expanded austenite, and diffusion kinetics of interstitials. It provides a description of low-temperature nitriding and nitrocarburizing processes for primarily austenitic and, to a lesser extent, other types of stainless steels along with practical examples and industrial applications of these steels.

Maraging steels are highly alloyed low-carbon iron-nickel martensite steels that possess an excellent combination of strength and toughness superior to that of most carbon-hardened steels. This article provides a detailed account of the formation of martensite in maraging steels. It discusses the heat treatment of these steels, namely, aging, solution annealing, age hardening, and nitriding. Their hardening during aging has been attributed to two different mechanisms: short-range ordering and precipitation. The article concludes with a discussion on the grain refinement using thermal cycling and transformation-induced plasticity maraging methods.

This article provides useful information on the selection of steels for heat treatment in order to achieve the required hardness. It discusses the effects of alloying elements on hardenability using the Grossmann's concept, and presents a discussion on the effects of alloying elements in hot-worked and cold-drawn steels. The article focuses on the selection of carbon and alloy steels based on the function of the alloying elements, and discusses the specific effects of alloying elements in steel in a tabulated form. The depth and degree of hardening (percentage of martensite) are dictated by the engineering stress analysis. Mechanical properties of quenched and tempered steels develop similar tensile properties for all practical purposes for all compositions with the same hardness. The article also provides information on the selection of steels to meet the required hardness, and elucidates the concept of hardenability for wear resistance with the help of graphs.

This article focuses on the mechanisms, models, prevention, correction, and effects associated with decarburization inherited from semi-finished product processing prior to induction heating. It discusses the diffusion of carbon in austenitic iron, which has a face-centered cubic crystal structure that provides an interstitial path for the migration of the relatively small carbon atoms. The article describes the evolution of steel microstructure with progressive decarburization (in air) to a steady-state carbon gradient using an iron-iron carbide phase diagram. It provides useful information on the impact of alloying on vulnerability to decarburization, and the impact of decarburization on the mechanical properties of steels and cast irons. The article also describes the technological operations that potentially cause decarburization and the practical implications for induction hardening.

Of the various thermal processing methods for steel, heat treating has the greatest overall impact on control of residual stress and on dimensional control. This article provides an overview of the effects of material- and process-related parameters on the various types of failures observed during and after heat treating of quenched and tempered steels. It describes phase transformations of steels during heating, cooling of steel with and without metallurgical transformation, and the formation of high-temperature transformation products on the surface of a carburized part. The article illustrates the use of carbon restoration on decarburized spring steels. Different geometric models for carbide formation are shown schematically. The article also describes the different microstructural features such as grain size, microcracks, microsegregation, and banding.

In the case of steels, heat treatment plays a fundamental role because no other process step can manipulate the microstructure in order to fulfill such a wide variety of possible in-service conditions. This article addresses heat treatment with regard to hardening and subsequent tempering of steel components in order to optimize tribological properties. It focuses on the heat treatment of tempering and bearing steels and on volume changes that take place due to phase transformations. Plastic deformations that occur due to shrinking and phase transformation are also discussed. The article also describes the generation of thermal, transformation, and hardening residual stresses.

This article provides information on single-shot and scanning, the two types of induction heat treating processes that are based on whether the induction coil is moving relative to the part during the heating process. It describes the effect of the frequency of induction heating current on the induction coil and process design, and the control of heating in different areas of the inductor part. The article reviews three main tools for adjustment of coil design and fabrication: coupling gap, coil copper profile, and magnetic flux controllers. It examines the method of holding a part and presenting it to the inductor during the initial inductor design. The article provides information on coil leads/busswork and contacts that mechanically and electrically connect the induction coil head to the power supply. It concludes with a discussion on flux and oxide removal, leak and flow checking, silver plating, and electrical parameter measurement.

This article provides a discussion on the analytical modeling and simulation of residual stress states developed in steel parts and the reasons for these varied final stress states. It illustrates how the metallurgical phase transformation of steel alloys can be applied in the simulation of induction hardening processes and the role of these phase transformations in affecting stress and distortion. Emphasis is placed on induction surface hardening, which is the main application of induction heating in steel heat treatment. The article concludes with examples of induction surface-hardened shafts and through-hardened shafts made of plain carbon steel, alloy steel, and limited hardenability steel.

This article describes the thermodynamics and kinetics of gas carburizing reactions, and details the mass transfer mechanism during gas carburizing. It discusses the various considerations involved in carburizing process planning, and reviews successful operation of the gas carburizing process based on the control of three principal variables: temperature, atmosphere composition or carbon potential, and time. The article also describes the selection criteria for alloy, carbon sources, atmosphere types, and carbon monoxide level for endothermic carburizing atmospheres. It provides information on carburizing modeling, case depth prediction, case depth measurement, and case depth evaluation as well as on carburizing equipment, and also covers the factors affecting distortion after carburizing.

Cold treating of steel can be used to enhance the transformation of austenite to martensite and improve the stress relief of castings and machined parts. Cryogenic treatment of steel is a distinct process that uses extreme cold to modify the performance of materials. This article explains the practices employed and equipment used in the cold treatment of steel. It also presents the results of using cryogenic treatment to enhance steel properties.