This article is a compilation of more than 35 binary alloy phase diagrams for which cobalt (Co) is the first named element in the binary pair. The diagrams plot alloy composition in terms of weight percent, while indicating atomic percent along a secondary scale. Each diagram is accompanied by a table of crystallographic data that includes composition ranges as well as the Pearson symbol, space group, and prototype for each phase.

This article is a compilation of ternary alloy phase diagrams for which cobalt (Co) is the first-named element in the ternary system. The other elements are Cr, Cu, Fe, Mo, Ni, Ti, V, and W. The diagrams are presented with element compositions in weight percent. The article includes 36 phase diagrams (liquidus projection, solidus projection and isothermal section).

This article discusses the methods and procedures used to extract, purify, and synthesize tungsten carbide powder, metal, and other refractory carbide/nitride powders used in hard metal production. Selection of powders, additives, equipment, and processes for making ready-to-press hard metal powders is also discussed. The article also provides information on the emerging technologies for tungsten carbide synthesis and binders in hard metal production, such as cobalt, iron, and nickel.

This article addresses the cobalt and cobalt-base alloys most suited for aqueous environments and those suited for high temperatures. The performance of cobalt alloys in aqueous environments encountered in commercial applications is discussed. The article provides information on the environmental cracking resistance of the cobalt alloys. Three welding processes that are used for hardfacing with the high-carbon Co-Cr-W alloys, namely, oxyacetylene, gas tungsten arc, and plasma-transferred arc are also discussed. The article examines the effects of various modes of high-temperature corrosion. It describes the applications and fabrication of cobalt alloys for high-temperature service.

Chromate conversion coatings (CCCs) are primarily used to improve adhesion of subsequently applied organic coatings or to impart corrosion resistance during atmospheric exposure. This article describes the factors that affect the formation of CCCs. It provides information on the processing sequence, morphology, composition, and properties of CCCs. The article discusses the electrochemical impedance spectroscopy approach used for evaluating conversion coatings. The test methods for various CCCs properties are also reviewed. The article examines the various coatings associated with chromate-free conversion. These include: titanium and zirconium fluorocomplexes; cerium-base, manganese-base, cobalt-base, and molybdate-base conversion coatings; hydrotalcite coatings; and organic coatings.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

This article focuses on the monolithic form of nonferrous alloys, including aluminum, copper, nickel, cobalt, titanium, zinc, magnesium, and beryllium alloys. Each metal and alloy offers unique combinations of useful physical, chemical, and structural properties that are made available by its particular composition and the proper choice of processing method. The article describes the composition, designation system, properties, and processing method of these metals and alloys. It discusses the effect of alloying elements in these alloys. The article explains microstructure/property relationships that are used to make specific properties available to the designers of structural applications. It provides examples of phase diagrams that illustrate eutectic and peritectic reactions.

Electroforming is the process by which articles or shapes can be exactly reproduced by electrodeposition on a mandrel or form that is later removed, leaving a precise duplicate of the original. This article discusses electroforming applications, and explains electroforming of nickel, cobalt, iron, and copper, providing information on mandrel design and selection, electroforming solutions and operating variables. It discusses the significant aspects of electroforming that demand special considerations, such as metal distribution, internal deposit stress, roughness, and treeing. The article concludes with an overview of alloy electroforming.

This article focuses on alternatives to chromium in both hard chromium plating and chromate conversion coating. These include electroless nickel plating, nickel-tungsten composite electroplating, spray coating applications, and cobalt/molybdenum-base conversion coating. The article discusses the material and process substitutions that can be used to eliminate the use or emissions of chromium in industrial processes. It describes the physical characteristics of each coating, economics, environmental impacts, advantages, and disadvantages of alternative processes.

This article provides a general overview of physical and mechanical properties, alloy compositions, applications, and product forms of cobalt-base alloys as wear-resistant, corrosion-resistant, and/or heat-resistant materials. The discussion is largely focused on cobalt-base alloys for wear resistance, as this is the single largest application area of cobalt-base alloys.