This article briefly discusses the annealing practices for refractory metals such as tungsten, molybdenum, niobium, tantalum, and rhenium and their alloys. It also presents the applications and properties of these metals and their alloys.

This article is a compilation of ternary alloy phase diagrams for which niobium (Nb) is the first-named element in the ternary system. The diagrams are presented with element compositions in weight percent. The article includes 2 phase diagrams: Nb-Ti-W isothermal section at 600 °C; and Nb-Ti-W isothermal section at 1000 °C.

This article is a compilation of binary alloy phase diagrams for which niobium (Nb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Refractory metals are typically processed from powders into ingots that are subsequently swaged into round bars or rolled into plates. Secondary operations are required to fabricate more complex refractory metal components. This article discusses two such secondary operations, namely, machining and joining processes for tungsten, tungsten heavy alloys, molybdenum, tantalum, niobium, and rhenium components. It describes the various types of metal joining processes, including mechanical fastening, brazing, and welding.

This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium.

This article describes the formability and surface contamination of the refractory metals such as niobium, tantalum, molybdenum, tungsten, and titanium-zirconium-molybdenum alloys. It reviews the factors that affect mechanical properties and formability during rolling and heat treatment. The effect of temperature on the formability of refractory metals is discussed. The article provides a description of the forming methods of sheet and preformed blanks using refractory metals. It also discusses the types of lubricants, including oils, soaps, waxes, silicones, graphite, and molybdenum disulphide, used in the forming of refractory metals.

Ammonia and ammonium hydroxide are not particularly corrosive in themselves, but corrosion problems can arise with specific materials, particularly when contaminants are present. This article discusses the corrosion resistance of materials used for the manufacture, handling, and storage of ammonia. These materials include aluminum alloys, iron and steel, stainless steels, nickel and its alloys, copper and its alloys, titanium and its alloys, zirconium and its alloys, niobium, tantalum, and nonmetallic materials.

Nitric acid is a strongly oxidizing acid that is aggressively corrosive to many metals. Its oxidizing nature is affected by acid temperature and concentration, and composition of the alloy exposed to it. This article focuses on the corrosion behavior of various ferrous and nonferrous metals and alloys when exposed to a nitric acid environment. The ferrous and nonferrous metals and alloys discussed are carbon and alloy steels, stainless steels, aluminum alloys, titanium, zirconium alloys, niobium and tantalum, and nonmetallic materials.

For chemical processing, niobium resists a wide variety of corrosive environments, including mineral acids, many organic acids, liquid metals, and most salt solutions. This article focuses on the mechanisms of corrosion resistance of niobium alloys in these environments. The niobium alloys include Nb-1Zr, Nb-55Ti, Nb-50Ta, and Nb-40Ta. The article describes the use of these corrosion resistant niobium alloys, and provides information on applications of niobium in various industries.

This article focuses on the forging characteristics of different types of refractory metals and alloys, namely, niobium and niobium alloys, molybdenum and molybdenum alloys, tantalum and tantalum alloys, and tungsten and tungsten alloys.

This article describes various procedures used in the metallographic preparation of niobium, tantalum, molybdenum, and tungsten alloys. It provides information on sectioning, grinding, mounting, polishing, and electrolytic etching as well as alternate procedures that have been used on refractory metals. The article presents and analyzes several micrographs, provides etchant formulas for various materials, and discusses the unique characteristics of rhenium and its alloys.

Hydrogen damage is a form of environmentally assisted failure that results from the combined action of hydrogen and residual or applied tensile stress. This article classifies the various forms of hydrogen damage and summarizes the theories that seek to explain these types of degradation. It reviews hydrogen degradation in specific ferrous and nonferrous alloys, namely, iron-base alloys, nickel alloys, aluminum alloys, copper alloys, titanium alloys, zirconium alloys, and vanadium, niobium, tantalum, and their alloys. An outline of hydrogen damage in intermetallic compounds is also provided.

This article addresses surface cleaning, finishing, and coating operations that have proven to be effective for molybdenum, tungsten, tantalum, and niobium. It describes standard procedures for abrasive blasting, molten caustic processing, acid cleaning, pickling, and solvent and electrolytic cleaning as well as mechanical grinding and finishing. The article also provides information on common plating and coating methods, including electroplating, anodizing, and oxidation-resistant coatings.

This article discusses special metallurgical considerations during the fusion welding of refractory metal alloys. These considerations are: microstructure, interstitial impurities, and welding conditions that are considered during the fusion welding of refractory metal alloys, including tantalum, niobium, rhenium, molybdenum, and tungsten. Refractory metal alloys are discussed in the order of decreasing weldability: tantalum, niobium, rhenium, molybdenum, and tungsten.

This article provides a discussion on filler metal selection, brazing procedures, and brazing equipment for brazing refractory metals. These include molybdenum, tungsten, niobium, and tantalum, and reactive metals. Commercially pure and alpha titanium alloys, alpha-beta alloys, zirconium alloys, and beryllium alloys are some reactive metals discussed in the article.

Coextrusion welding (CEW) is a solid-state process that produces a weld by heating two or more workpieces to the welding temperature and forcing them through an extrusion die. This article describes cold and hot CEW for common metals such as low-carbon steel, aluminum, aluminum alloys, copper, and copper alloys. Additional applicable materials include nickel, nickel-base alloys, zirconium, titanium, tantalum, and niobium.

Two high-strength low-alloy (HSLA) families, acicular-ferrite steels and pearlite-reduced steels, contain microalloying additions of vanadium and niobium. Vanadium, niobium, and titanium combine preferentially with carbon and/or nitrogen to form a fine dispersion of precipitated particles in the steel matrix. This article summarizes the metallurgical effects of vanadium, niobium, molybdenum, and titanium. The metallurgical fundamentals were first applied to forgings in the early 1970s. The ultimate strength of first- and second-generation microalloy steels is adequate for many engineering applications, but these steels do not achieve the toughness of conventional quenched and tempered alloys under normal hot-forging conditions. Third-generation microalloy steels differ from their predecessors in that they are direct quenched from the forging temperature to produce microstructures of lath martensite with uniformly distributed temper carbides. Without subsequent heat treatment, these materials achieve properties, including toughness, similar to those of standard quenched and tempered steels.

This article describes various machining techniques of refractory metals, namely, niobium, molybdenum, tantalum, and tungsten. These include turning, boring, trepanning, reaming, milling, tapping, drilling, and sawing. Parameters for the machining of the refractory metals are also tabulated. In addition, the article provides information on cutting fluids and tools that are used in machining of the refractory metals as well as on the safety precautions to be followed in the machining process.