The control of the solidification process of cast iron requires understanding and control of the thermodynamics of the liquid and solid phases and of the kinetics of their solidification, including nucleation and growth. This article addresses issues that allow for the determination of probability of formation and relative stability of various phases. These include the influence of temperature and composition on solubility of various elements in iron-base alloys; calculation of solubility lines, relevant to the construction of phase diagrams; and calculation of activity of various components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems, along with saturation degree and carbon equivalent.

This article briefly discusses the annealing practices for refractory metals such as tungsten, molybdenum, niobium, tantalum, and rhenium and their alloys. It also presents the applications and properties of these metals and their alloys.

This article is a compilation of binary alloy phase diagrams for which thallium (Tl) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which manganese (Mn) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Eutectoid and peritectoid transformations are classified as solid-state invariant transformations. This article focuses primarily on the structures from eutectoid transformations with emphasis on the classic iron-carbon system of steel. It reviews peritectoid phase equilibria that are very common in several binary systems. The addition of substitutional alloying elements causes the eutectoid composition and temperature to shift in the iron-carbon system. The article graphically illustrates the effect of various substitutional alloying elements on the eutectoid transformation temperature and effective carbon content. The partitioning effect of substitutional alloying elements, such as chromium, manganese, and silicon, in pearlitic steel is also illustrated.

Electrical contacts are made of elemental metals, composites, or alloys that are made by the melt-cast method or manufactured by powder metallurgy (PM) processes. PM facilitates combinations of metals that ordinarily cannot be achieved by alloying. This article describes the processing, properties, and performance of electrical contacts based on PM or hybrid composite technologies with refractory metals and compounds. These metals and compounds include tungsten, molybdenum, carbide-based composites, and silver-base composites. The article explains composite manufacturing methods, namely, PM methods, internal oxidation, and hybrid consolidation. The availability of the refractory metals and compounds in various product forms are also reviewed.

The two most important classes of materials that are manufactured via infiltration methods are copper- and silver-infiltrated refractory metals and refractory carbides, and copper-infiltrated steels. This article focuses on copper-infiltrated steels and discusses the basic requirements for infiltration, which is a technique that is only applicable to material systems that meet certain requirements. It addresses these requirements and describes the conventional (partial) infiltration process of powder metallurgy (PM) steel. The materials used in the process, such as matrix and infiltrant, are discussed. The article also details several criteria used to evaluate the performance of an infiltration process. It concludes with information on alloy steels and fully infiltrated steels.

This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium.

Melting with induction crucible furnaces (ICFs) is a well-established and reliable technology, and their maintenance must be performed at regularly scheduled intervals to ensure safe operation. This article discusses monitoring of the refractory lining, and presents an overview of the various wear-indication methods, namely, manual checks, ground leakage indication, evaluation of electrical values of the furnace, and temperature measurement. It also presents the working principle, physical restrictions, limitations, and remarks on these methods.

The crucible induction furnace is growing as an alternative melting unit to the cupola furnace due to its low specific power and reduced power consumption during solid melting material. This article details the process engineering features of the crucible induction furnace. It discusses the various processes involved in melting, holding, and pouring of liquid melt in crucible induction furnaces wherein the holding operation is carried out in channel furnace and pouring operation in pressure-actuated pouring furnaces. The article examines the behavior of furnace refractory lining to defects such as erosion, infiltration, crack formation, and clogging, and the corresponding preventive measures to avoid the occurrence of these defects. It elucidates the overall furnace operations, including commissioning, operational procedures, automatic process monitoring, inductor change, and dealing with disturbances.

A key differentiator between friction stir welding (FSW) and other friction welding processes is the presence of a nonconsumable tool in FSW, often referred to as a pin tool to differentiate it from other tooling associated with the process. This article discusses materials for friction stir welding (FSW) pin tools, various tool geometries that have been used, designs for specific applications, predicting and measuring tool performance, and other considerations in FSW pin tool design. The tool materials include tool steels, superalloys, refractory metals, carbides and ceramics, and superabrasives.

The properties of copper alloys occur in unique combinations found in no other alloy system. This article focuses on the major and minor alloying additions and their impact on the properties of copper. It describes major alloying additions, such as zinc, tin, lead, aluminum, silicon, nickel, beryllium, chromium, and iron. The article discusses minor alloying additions, including antimony, bismuth, selenium, manganese, and phosphorus. Copper alloys can be cast by many processes, including sand casting, permanent mold casting, precision casting, high-pressure die casting, and low-pressure die casting. The article provides information on the types of copper castings and tabulates the nominal chemical composition and mechanical properties of several cast alloys.

This article focuses on the forging characteristics of different types of refractory metals and alloys, namely, niobium and niobium alloys, molybdenum and molybdenum alloys, tantalum and tantalum alloys, and tungsten and tungsten alloys.

This article describes various procedures used in the metallographic preparation of niobium, tantalum, molybdenum, and tungsten alloys. It provides information on sectioning, grinding, mounting, polishing, and electrolytic etching as well as alternate procedures that have been used on refractory metals. The article presents and analyzes several micrographs, provides etchant formulas for various materials, and discusses the unique characteristics of rhenium and its alloys.

This article addresses the general effects of the composition, mechanical treatment, surface treatment, and processing on the corrosion resistance of aluminum and aluminum alloys. There are five major alloying elements: copper, manganese, silicon, magnesium, and zinc, which significantly influence the properties of aluminum alloys. There are organic coatings or paints that provide a barrier between a corrosive environment and aluminum surface. Inorganic coatings, including claddings, and enhanced oxides, such as anodized films, Boehmite films, and conversion coatings also help in corrosion prevention. The article assists in the information on selection of fabrication operations, as they play an important role in corrosion resistance.

Chromate conversion coatings (CCCs) are primarily used to improve adhesion of subsequently applied organic coatings or to impart corrosion resistance during atmospheric exposure. This article describes the factors that affect the formation of CCCs. It provides information on the processing sequence, morphology, composition, and properties of CCCs. The article discusses the electrochemical impedance spectroscopy approach used for evaluating conversion coatings. The test methods for various CCCs properties are also reviewed. The article examines the various coatings associated with chromate-free conversion. These include: titanium and zirconium fluorocomplexes; cerium-base, manganese-base, cobalt-base, and molybdate-base conversion coatings; hydrotalcite coatings; and organic coatings.

This article provides an overview of the classification of hydrogen damage. Some specific types of the damage are hydrogen embrittlement, hydrogen-induced blistering, cracking from precipitation of internal hydrogen, hydrogen attack, and cracking from hydride formation. The article focuses on the types of hydrogen embrittlement that occur in all the major commercial metal and alloy systems, including stainless steels, nickel-base alloys, aluminum and aluminum alloys, titanium and titanium alloys, copper and copper alloys, and transition and refractory metals. The specific types of hydrogen embrittlement discussed include internal reversible hydrogen embrittlement, hydrogen environment embrittlement, and hydrogen reaction embrittlement. The article describes preservice and early-service fractures of commodity-grade steel components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also reviewed.

Characteristics of stainless steel that affect its formability include yield strength, tensile strength, and ductility, in addition to the effect of work hardening on these properties. This article discusses the forming process of stainless steel, heat-resistant alloys and refractory metals, detailing the major aspects of forming, including formability, lubrication, and forming methods and tools. The effect of factors such as alloy condition, cold reduction, forming direction (in the case of heat-resistant alloys) and temperature (in the case of refractory metals) on formability is also discussed.

The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. They are readily degraded by oxidizing environments at moderately low temperatures. Protective coating systems have been developed, mostly for niobium alloys, to permit their use in high-temperature oxidizing aerospace applications. This article discusses the properties, processing, applications, and classes of refractory metals and its alloys, namely molybdenum, tungsten, niobium, tantalum and rhenium. It also provides an outline of the coating processes used to improve their oxidation resistance.

Heat treating of stainless steel produces changes in physical condition, mechanical properties, and residual stress level and restores maximum corrosion resistance when that property has been adversely affected by previous fabrication or heating. This article focuses on annealing of different types of stainless steels such as austenitic, ferritic, duplex, martensitic, and precipitation-hardening, and on the heat treatment of superalloys and refractory metals. It discusses the recommended procedures for solution annealing, austenite conditioning, transformation cooling, and age tempering of precipitation-hardening stainless steels. The article also lists general recommendations for the annealing temperatures of tantalum, niobium, molybdenum, tungsten, and their alloys.