This article is a compilation of binary alloy phase diagrams for which hydrogen (H) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Sintering atmosphere protects metal parts from the effects of contact with air and provides sufficient conduction and convection for uniform heat transfer to ensure even heating or cooling within various furnace sections, such as preparation, sintering, initial cooling, and final cooling sections. This article provides information on the different zones of these furnace sections. It describes the types of atmospheres used in sintering, namely, endothermic gas, exothermic gas, dissociated ammonia, hydrogen, and vacuum. The article concludes with a discussion on the furnace zoning concept and the problems that arise when these atmospheres are not controlled.

This article provides members of the thermal spray community with practical recommendations for the safe installation, operation, and maintenance of gas equipment used in the thermal spray process. It focuses on safety issues concerning gas equipment used in conjunction with thermal spray equipment at consumer sites. The article covers the gas sources (bulk or gaseous), the piping (hard and soft) leading to the gas console or the torch, and the specific safety devices used to help ensure safe operation. It discusses the characteristics and safety hazards of gases such as oxygen, compressed air, nitrogen, helium, argon, carbon dioxide, hydrogen, acetylene, kerosene, propylene, propane, and natural gas. The article also provides information on the maintenance and safety practices involved in the plumbing configurations of cylinder gas supply units and bulk gas supply units.

The shielding gas used in an arc welding process has a significant influence on the overall performance of the welding system. These gases are argon, helium, oxygen, hydrogen, nitrogen, and carbon dioxide. This article discusses the shielding gas selection criteria for plasma arc welding, gas metal arc welding, and flux cored arc welding. It describes the basic properties of shielding gases, namely, dissociation, recombination, reactivity potential, oxidation potential, and gas purity. The article also provides information on the influence of the shielding gas on weld mechanical properties and self-shielded flux cored arc welding.

This article contains a table that lists the properties of various fuel gases, namely, acetylene, hydrogen, methane, methyl acetylene propadiene, propane, propylene, and natural gas. It discusses shielding gases, their mixtures and uses in gas metal arc welding, flux cored arc welding, gas tungsten arc welding, and plasma arc welding.

Hydrogen damage is a form of environmentally assisted failure that results from the combined action of hydrogen and residual or applied tensile stress. This article classifies the various forms of hydrogen damage and summarizes the theories that seek to explain these types of degradation. It reviews hydrogen degradation in specific ferrous and nonferrous alloys, namely, iron-base alloys, nickel alloys, aluminum alloys, copper alloys, titanium alloys, zirconium alloys, and vanadium, niobium, tantalum, and their alloys. An outline of hydrogen damage in intermetallic compounds is also provided.

When metal is exposed to an oxidizing gas at elevated temperature, corrosion can occur by direct reaction with the gas, without the need for the presence of a liquid electrolyte. This type of corrosion is referred to as high-temperature gaseous corrosion. This article describes the various forms of high-temperature gaseous corrosion, namely, high-temperature oxidation, sulfidation, carburization, corrosion by hydrogen, and hot corrosion.

This article begins with a discussion on the classification of hydrogen embrittlement and likely sources of hydrogen and stress. The article describes several hydrogen embrittlement test methods, including cantilever beam tests, wedge-opening load tests, contoured double-cantilever beam tests, rising step-load tests, and slow strain rate tensile tests. It also describes the interpretation of test results and how to control hydrogen embrittlement during production.

This article provides an overview of the classification of hydrogen damage. Some specific types of the damage are hydrogen embrittlement, hydrogen-induced blistering, cracking from precipitation of internal hydrogen, hydrogen attack, and cracking from hydride formation. The article focuses on the types of hydrogen embrittlement that occur in all the major commercial metal and alloy systems, including stainless steels, nickel-base alloys, aluminum and aluminum alloys, titanium and titanium alloys, copper and copper alloys, and transition and refractory metals. The specific types of hydrogen embrittlement discussed include internal reversible hydrogen embrittlement, hydrogen environment embrittlement, and hydrogen reaction embrittlement. The article describes preservice and early-service fractures of commodity-grade steel components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also reviewed.

Oxyfuel gas welding (OFW) is a manual process in which the metal surfaces to be joined are melted progressively by heat from a gas flame, with or without a filler metal. This article discusses the capabilities, advantages, and limitations of OFW. It describes the role of gases, such as oxygen, acetylene, hydrogen, natural gas, propane, and proprietary gases, in OFW. The article discusses the important elements of an OFW system, such as gas storage facilities, pressure regulators, hoses, torches, related safety devices, and accessories. It describes the sequence for setting up a positive-pressure welding outfit. The article provides information on forehand welding and backhand welding, as well as various joints used. It concludes with a discussion on repairs and alterations, as well as the safety aspects.