Various types of furnaces have been used for cast iron melting. In terms of tonnage, the primary melting methods used by iron casting facilities are cupola and induction furnaces. This article describes the operation and control principles of cupola furnace. It discusses the advantages of specialized cupolas such as cokeless cupola and plasma-fired cupola. Melting in iron foundries is a major application of induction furnaces. The article describes the operations of two induction furnaces: the channel induction furnace and the induction crucible furnace. It explains the teapot principle of pressure-actuated pouring furnaces and provides information on the effect of pouring magnesium-treated melts.

This article begins with the one-component, or unary, diagram for magnesium. The diagram shows what phases are present as a function of the temperature and pressure. When two metals are mixed in the liquid state to produce a solution, the resulting alloy is called a binary alloy. The article describes the various types of solid solutions such as interstitial solid solutions and substitutional solid solutions. Free energy is important because it determines whether or not a phase transformation is thermodynamically possible. The article discusses the thermodynamics of phase transformations and free energy, as well as kinetics of phase transformations. It concludes with a description of solid-state phase transformations that occur when one or more parent phases, usually on cooling, produces a phase or phases.

This article is a compilation of binary alloy phase diagrams for which magnesium (Mg) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out during inoculation and nucleation of molten cast iron, assisting in the formation of cast iron. The different types of cast irons are gray cast iron, nodular cast iron, compacted graphite iron, malleable cast iron, and alloyed cast iron. The article provides an overview of the melt treatment processes carried out in cast steel, wrought and cast aluminum, and copper materials.

This article contains a table that lists the density of metals and alloys. It presents information on aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, and zinc, an their respective alloys. Information on wrought alloys, permanent magnet materials, precious metals, and rare earth metals is also listed.

This article presents a table that lists the linear thermal expansion of selected metals and alloys. These include aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, and zinc and their alloys. Thermal expansion is presented for specific temperature ranges.

This article contains a table that lists the thermal conductivity of selected metals and alloys near room temperature. These include aluminum and aluminum alloys; copper and copper alloys; iron and iron alloys; lead and lead alloys; magnesium and magnesium alloys; nickel and nickel alloys; tin and tin alloys; titanium and titanium alloys; zinc and zinc alloys; and pure metals.

The cold chamber die casting process is used with higher-melting-point alloys such as aluminum and magnesium. This article discusses the component design of the cold chamber high-pressure die casting machine. It reviews the process parameters of cold chamber die casting, incuding the shot profile, intensification phase, and component size.

Gas porosity is a major factor in the quality and reliability of castings. The major cause of gas porosity in castings is the evolution of dissolved gases from melting and dross or slag containing gas porosity. Degassing is the process of removing these gases. This article describes the methods of degassing aluminum, magnesium, and copper alloys. It provides information on the sources of hydrogen in aluminum and gases in copper.

This article reviews the production stages of iron foundry casting, with particular emphasis on the melting practices, molten metal treatment, and feeding of molten metal into sand molds. It discusses the molten metal treatments for high-silicon gray, high-nickel ductile, and malleable irons. Foundry practices are also described for compacted graphite, high-silicon ductile, and high-alloy white irons.

This article focuses on aspects that are important for the commercial production of castings. It discusses the modification process in hypoeutectic and eutectic alloys that differ only in the relative volume fraction of primary aluminum and aluminum-silicon eutectic. The article explains how modification changes porosity formation in a casting. It describes the mechanisms responsible for silicon modification, as well as the modifications and changes in eutectic nucleation and the eutectic grain structure. The article reviews the usage of strontium in foundry practices. The growth of silicon eutectic is described to explain effects ancillary to silicon modification. The article also examines the effects of elements, such as phosphorus, antimony, bismuth, magnesium, boron, and calcium, on the silicon structure.

Die casting is the process most often used for shaping zinc alloys. This article tabulates the compositions of zinc casting alloys and comparison of typical mechanical properties of zinc casting alloys. It discusses additions of alloys to the zinc, including aluminum, magnesium, copper, and iron. The article illustrates a characteristic five-layer microstructure of zinc alloy casings. It discusses the various methods of finishing of zinc alloy die castings, including chromium plating, polishing, painting, and electropainting. The article describes the casting of inserts and their uses in the zinc. It concludes with information on the applications of zinc die castings.

This article focuses on the variety of alloys, furnaces, and associated melting equipment as well as the casting methods available for manufacturing magnesium castings. These methods include sand casting, permanent mold casting, die casting, thixomolding, and direct chill casting. The article discusses the flux process and fluxless process for the melting and pouring of magnesium alloys. It describes the advantages and disadvantages of green sand molding and tabulates typical compositions and properties of magnesium molding sands. The article provides information on the machining characteristics of magnesium and the applications of magnesium alloys.

In terms of forming, magnesium alloys are much more workable at elevated temperatures due to their hexagonal crystal structures. This article describes the deformation mechanisms of magnesium and provides information on the hot and cold forming processes of magnesium alloys and the lubricants used in the processes. It discusses the various forming processes of magnesium alloys. These include press-brake forming, deep drawing, manual and power spinning, rubber-pad forming, stretch forming, drop hammer forming, and precision forging.

The rate and form of corrosion that occur in a particular situation depend on many complex variables. This article discusses the rate of corrosion of lead in natural and domestic water depending on the degree of water hardness caused by calcium and magnesium salts. Lead exhibits consistent durability in all types of atmospheric exposure, including industrial, rural, and marine. The article tabulates the corrosion of lead in various natural outdoor atmospheres and the corrosion of lead alloys in various soils. It explains the factors that influence in initiating or accelerating corrosion: galvanic coupling, differential aeration, alkalinity, and stray currents. The resistance of lead and lead alloys to corrosion by a wide variety of chemicals is attributed to the polarization of local anodes caused by the formation of a relatively insoluble surface film of lead corrosion products. The article also provides information on the corrosion rate of lead in chemical environments.

This article begins with the discussion on the background of metal-matrix composites (MMC) and moves into a broad description of the general parameters affecting the corrosion of MMC. It discusses the primary sources of MMC corrosion that include galvanic corrosion between MMC constituents, chemical degradation of interphases and reinforcements, microstructure-influenced corrosion, and processing-induced corrosion. The article elaborates on the corrosion behavior of specific aluminum, magnesium, titanium, copper, stainless steel, lead, depleted uranium, and zinc MMCs systems. It concludes with a description on the corrosion control of MMCs using protective coatings and inhibitors.

Density allows for the conversion of uniform corrosion rates from units of weight (or mass) loss per unit area per time to thickness per unit time. This article contains a table that lists the density of metals, such as aluminum, copper, iron, stainless steel, magnesium, and lead, and their alloys.

This article begins with a discussion on the environmental factors that induce corrosion in magnesium alloys. It reviews the factors that determine the severity of different forms of localized corrosion, namely, galvanic corrosion, corrosion fatigue, and stress-corrosion. The article discusses corrosion protection in magnesium assemblies and the protective coating systems used in corrosion protection practices. Protection schemes for specific applications and the production of novel magnesium alloys with improved corrosion resistance are also reviewed. The article concludes with a discussion on the corrosion of bulk vapor-deposited alloys and magnesium-matrix composites.

This article discusses the specimen preparation techniques for zinc and its alloys and zinc-coated specimens, namely, sectioning, mounting, grinding and polishing, and etching. It describes the characteristics of lead, cadmium, iron, copper, titanium, aluminum, magnesium, and tin, which are present in the microstructure of zinc alloys. The article also provides information on microexamination that helps to determine the dendrite arm spacing, as well as the grain size, grain boundaries, and grain counts.

Magnesium and its alloys are among the most difficult metals to prepare for metallographic examination. This article describes specimen preparation processes, including sectioning, mounting, grinding, and polishing. It discusses macro and microexamination techniques as well as related etching processes, including macroetching and color etching based on polarized light enhancement. The article concludes with an overview of the effects of alloying elements, including aluminum, beryllium, calcium, copper, iron, lithium, manganese, rare earth metals, silicon, silver, strontium, thorium, tin, zinc, and zirconium.