This article presents the failure of polymer-matrix composites and the methodology for fractography. It provides a detailed discussion on the types of translaminar, interlaminar, and intralaminar failures. The article also presents a discussion on the types of fatigue failures, and the influence of composite architecture. It provides details of the fractography associated with defects and damage.

According to International Organization for Standardization (ISO)/ASTM International 52900, additive manufacturing (AM) can be classified into material extrusion, material jetting, vat photo polymerization, binder jetting, sheet lamination, powder-bed fusion (PBF), and directed-energy deposition. This article discusses the processes involved in polymer powder 3D printing using laser fusion/ sintering and fusing agents and energy, as well as the thermally fused PBF. It provides information on polymer powder parameters and modeling, the powder-handling system, powder characterization, the flowability of powder feedstock, and polymer part characteristics. The article describes the types of polymers in PBF, the processes involved in powder recycling, and the prospects of PBF in AM. In addition, the biomedical application of polyether ether ketone (PEEK) is also covered.

Reinforced polymers (RPs) are widely used in structural, industrial, automotive, and engineering applications due to their ecofriendly nature and the potential to manipulate their properties. This article addresses the technical synthesis of RPs, referring to their tribological behavior, to provide insights into the contribution and interaction of influential parameters on the wear behavior of polymers. It provides a brief discussion on the effects of significant parameters on RP tribology. The article describes abrasive and adhesive wear and provides a theoretical synthesis of the literature regarding the wear mechanisms of RPs. It also describes the synthesis of abrasive wear failure of different types of RPs and highlights the contribution of these influential parameters. The article addresses the synthesis of adhesive wear failure of different types of RPs.

Polymers and polymer composites have become attractive for tribological applications due to their specific material properties. This article begins by discussing the fundamentals of polymer friction and wear. It summarizes the main polymer materials used in tribological applications. The article explains the effects of load, sliding velocity, and temperature on the friction coefficient. It describes three types of wear modes, namely, abrasive, adhesion, and fatigue. The article discusses the frictional behavior of polymer composites and polymer coatings. It concludes by providing information on tribotesting of polymers and polymer composites.

This article provides a broad overview of sliding and adhesive wear, its processes, and its control, with special attention to three general classes of materials: metals, ceramics, and polymers. It discusses the ways in which materials can be damaged and removed during sliding contact. The article explains the physical and chemical nature of sliding surfaces. It presents wear equations, design criteria, and criteria for selection of materials. The article also describes the factors that affect wear performance of hybrid sliding systems. It concludes by providing general guidelines to prevent the sliding and adhesive wear in metals, polymers, and ceramics.

Solid particle erosion (SPE) is the loss of material that results from repeated impact of solid particles energized in a carrier fluid. This article reviews important SPE variables, their effects for different classes of materials, composites and coatings, and the mechanisms and theories proposed to explain SPE. It discusses the SPE of metals, steels, and ceramics, as well as erosion of alloys with coarse, nominally two-phase microstructures in which the second-phase particles (SPPs) are typically large compared with the dimensions of the damage zone created by the impact of one particle. The article summarizes the erosion characteristics of polymer matrix composites (PMCs), metal matrix composites (MMCs), ceramic matrix composites (CMCs), and erosion-resistant coatings. The combination of parameters included in most erosion models is also summarized.

Hydrochloric acid (HCl) may contain traces of impurities that will change the aggressiveness of the solution. This article discusses the effects of impurities such as fluorides, ferric salts, cupric salts, chlorine, and organic solvents, in HCl. It describes the corrosion resistance of various metals and alloys in HCl, including carbon and alloy steels, austenitic stainless steels, standard ferritic stainless steels, nickel and nickel alloys, copper and copper alloys, corrosion-resistant cast iron, zirconium, titanium and titanium alloys, tantalum and its alloys, and noble metals. The article illustrates the effect of HCl on nonmetallic materials such as natural rubber, neoprene, thermoplastics, and reinforced thermoset plastics. It also tabulates the corrosion of various metals in dry hydrogen chloride.

This article provides an overview of the environmental performance of the most commonly used nonmetallic materials, including elastomers, plastics, thermosetting resins, resin-matrix composites, organic coatings, concrete, refractories, and ceramics. It also discusses the applications and uses of these materials.

This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

This article describes the dispersed-phase toughening of thermoset matrices by the development of multiphase-structure thermosetting matrices using rubber and/or thermoplastic materials. It discusses two main methods for manufacturing prepregs, namely, single-pass impregnation and double-pass impregnation. The article illustrates reflected-light optical microscopy techniques to evaluate the morphology of thermoplastic materials for determining the material quality and correlating key microstructural features with material performance.

This article describes methods for analyzing impact-damaged composites in the aircraft industry. These include C-scan and x-radiography methods and optical microscopy. The article reviews brittle-matrix composite and tough-matrix composite failures. It explains the different types of composite failure mechanisms such as thermoplastic-matrix composite failure mechanisms, untoughened thermoset-matrix composite failure mechanisms, toughened thermoset-matrix composite failure mechanisms, dispersed-phase and rubber-toughened thermoset-matrix composite failure mechanisms, and particle interlayer-toughened composite failure mechanisms.

Microstructural analysis of the composite matrix is necessary to understand the performance of the part and its long-term durability. This article focuses on the microstructural analysis of engineering thermoplastic-matrix composites and the influence of cooling rate and nucleation on the formation of spherulites in high-temperature thermoplastic-matrix carbon-fiber-reinforced composites. It also describes the microstructural analysis of a bio-based thermosetting-matrix natural fiber composite system.

Polymer composite materials are subject to degradation if not appropriately protected from the environment. This article describes the effects of heat and atomic oxygen and ultraviolet-light on composite material surfaces, with illustrations.

Lightning damage in polymer composites is manifested by damage at both the macroscopic or visual level and within the material microstructure. This article illustrates the effects of the laboratory-generated lightning strikes on polymeric composites.

This article outlines the processes by which materials are selected to prevent or control localized corrosion, galvanic corrosion, and intergranular corrosion. It reviews the operating conditions and the design of candidate materials for material selection. The article discusses various corrosion-resistant materials, including ferrous and nonferrous metals and alloys, thermoplastics, reinforced thermosetting plastics, nonmetallic linings, glass, carbon and graphite, and catalyzed resin coatings. It examines an unusual form of intergranular corrosion known as exfoliation, which occurs in aluminum-copper alloys. The article also describes three types of erosion-corrosion: liquid erosion-corrosion, cavitation, and fretting. It concludes with information on the various factors to be considered for material selection, including minimum cost or economic design, minimum corrosion, minimum investment, and minimum maintenance.

This article reviews the abrasive and adhesive wear failure of several types of reinforced polymers, including particulate-reinforced polymers, short-fiber reinforced polymers (SFRP), continuous unidirectional fiber reinforced polymers (FRP), particulate-filled composites, mixed composites (SFRP and particulate-filled), unidirectional FRP composites, and fabric reinforced composites. Friction and wear performance of the composites, correlation of performance with various materials properties, and studies on wear-of failure mechanisms by scanning electron microscopy are discussed for each of these types.

Reinforcing fibers are a key component of polymer-matrix composites (PMCs), ceramic-matrix composites (CMCs), and metal-matrix composites (MMCs). This article discusses the mechanical and nonmechanical properties of these composites. It presents an overview of PMC, CMC, and MMC reinforcing fibers. The article describes cost-considered value-in-use of the ultimate-use temperature of selected fibers in three fiber categories: metal fibers or wires, oxide ceramic fibers, and non-oxide ceramic fibers.

Open molding is the method used in the polymer-matrix composites industry to make thermoset composite products. This article discusses the advantages, disadvantages, and applications of the open molding. It describes the various process of the open molding, such as hand lay-up process and spray-up process. Workmanship for hand lay-up and spray-up processes is reviewed. The article provides information on the matrix-resin materials used for open molding, including unsaturated polyester resins, epoxy vinyl ester resins, and reinforcements. It explains the component design and short- and long-term properties of a fiber reinforced composite laminate depending on material selection and workmanship. The article also presents the basic design guidelines for open molding.