This article discusses the importance of friction and wear and the role of lubricants in composites. It highlights the progress and developments in using different forms of carbon allotropes in composites for improved friction and wear performance of materials. The article focuses on the widely used form known as carbon black (CB) and shows how to deal with friction and wear of polymers and composites when gamma irradiation is involved. It also discusses the role of graphite in composite materials, which is widely used as a dry lubricant. The article examines the tribology of carbon nanotubes (CNTs) as components in composite materials. It also highlights some of the most pronounced examples of graphene use as a reinforcement agent for improving tribological performance in composite matrices. The article concludes with a discussion on the progress of research in diamond-containing composites.

This article discusses the characterization of gray iron structures, following the sequence of structure formation, as it applies to unalloyed or low-alloyed gray iron. Austenite grains are the basic crystallographic entities of the metallic matrix in gray cast iron precipitated from the liquid melt. The article describes the macrostructure and dendrite morphology of primary austenite. Eutectoid transformation in the solid state causes the transformation of austenite to pearlite and/or ferrite, producing the as-cast structure. The article discusses the observations of the graphite and ferritic/pearlitic structure in as-cast gray iron.

Malleable iron, like ductile iron, possesses considerable ductility and toughness because of its combination of nodular graphite and low-carbon metallic matrix. There are two basic types of malleable iron: blackheart and whiteheart. This article focuses on the blackheart malleable iron and discusses the chemical composition of malleable iron. A summary of mechanical properties and specifications of malleable iron castings is presented in a table. The article also reviews the mechanical properties of ferritic malleable iron and pearlitic and martensitic-pearlitic malleable irons.

This article discusses the composition of the major components of dental composite resins: organic resin matrix, filler, coupling agents, and initiator-accelerator systems. It describes the properties of composite resins that are related to the amount and type of filler and resin-matrix compositions. The article also discusses the compositions, properties, and clinical applications of polyacid-modified composite resins and resin-modified glass-ionomer cements. It concludes with information on biodegradation and biocompatibility of resin-based restorative materials.

Mounting of the specimen is often desirable or necessary for handling and metallographic polishing after the specimen is cut into an appropriate size. This article illustrates the different mechanical clamps used in mounting small specimens. It provides useful information on compression molded mounts, which are molded with thermoplastic and thermosetting resins. The article reviews several resins and their key factors, which help in the selection of the most appropriate mounting method and resin. It also discusses the characteristics of plastic mounting materials. The article provides information on the molds and resins used for castable mounts, vacuum treatment of mounts, special mount arrangements, and mount marking and storage.

Microstructural analysis of the composite matrix is necessary to understand the performance of the part and its long-term durability. This article focuses on the microstructural analysis of engineering thermoplastic-matrix composites and the influence of cooling rate and nucleation on the formation of spherulites in high-temperature thermoplastic-matrix carbon-fiber-reinforced composites. It also describes the microstructural analysis of a bio-based thermosetting-matrix natural fiber composite system.

This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.

Open molding is the method used in the polymer-matrix composites industry to make thermoset composite products. This article discusses the advantages, disadvantages, and applications of the open molding. It describes the various process of the open molding, such as hand lay-up process and spray-up process. Workmanship for hand lay-up and spray-up processes is reviewed. The article provides information on the matrix-resin materials used for open molding, including unsaturated polyester resins, epoxy vinyl ester resins, and reinforcements. It explains the component design and short- and long-term properties of a fiber reinforced composite laminate depending on material selection and workmanship. The article also presents the basic design guidelines for open molding.

Mechanical and environmental loadings cause a variety of failure modes in composites, including matrix cracking, fiber-matrix debonding, delamination between plies, and fiber breakage. This article summarizes visual analysis and nondestructive testing methods for the failure analysis of composites. These methods include radiography, ultrasonic techniques, acoustic emission, and thermograph. The article also provides information on destructive test techniques.

Metallic matrices are essential constituents for the fabrication of metal-matrix composites (MMCs). This article describes three different classes of aluminum alloys, namely, commercial aluminum alloys, low-density and high-modulus alloys, and high temperature alloys. It presents typical tensile properties and fracture toughness of the selected heat treatable aluminum alloys in a table. Titanium alloys are very attractive for MMC applications, due to their higher strength and temperature capability compared to aluminum alloys. The article tabulates the effect of heat treatment on room-temperature properties and tensile properties of Ti-25Al-17Nb alloy sheet.

This article focuses on the process methods and matrix chemistries of ceramic-matrix composites. These methods include pressure-assisted densification, chemical vapor infiltration, melt infiltration, polymer infiltration and pyrolysis, and sol-gel processing. The article discusses the use of a ceramic, preceramic, or metal phase as a fluid or vapor phase reactant to form the matrix. Emphasis is placed on microstructural features that influence ultimate composite properties.

This article describes the various pure forms of carbon matrices and the corresponding methods used to create them or incorporate them into a matrix of a composite. These forms include graphite, diamond, fullerenes, and nanotubes. The article discusses the three types of liquid precursors, namely, thermoplastic, thermosetting, and evaporative or solvent carriers. It provides a description of the advantages and limitations of various methods involved in chemical vapor infiltration. The article concludes with a discussion on matrix contribution to composite properties.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

This article illustrates typical fractographic features for a number of different composite materials. It describes the differences in fracture characteristics due to different loading, material processing, and environmental conditions. The article presents fractographic data obtained from epoxy matrix materials. Minimal fractographic data from other brittle thermoset resin systems are also presented. The article discusses the interlaminar fracture of composites with ductile thermoplastic matrices. It also provides information on the translaminar fracture features of the composite materials.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

Bulk molding compounds can be molded into a variety of complex shapes by methods that can be readily automated for high volume production. This article describes the formulation and processing (compound formation, and molding methods) of bulk molding compounds. It discusses the effects of fiber type, fiber length, and matrix type on thermoset bulk molding compounds. The markets for long-fiber-reinforced bulk molding compounds are electrical, ordnance, aerospace, industrial, sporting goods, and automotive applications.

The design and analysis of aerospace and industrial composite components and assemblies requires a detailed knowledge of materials properties, which, in turn, depend on the manufacturing, machining, and assembly methods used. This article, through several tables and graphs, provides the mechanical properties, physical properties, and service characteristics of representative composite fiber-resin combinations, including thermoplastic matrix composites such as thermoplastic polyester resins, thermoplastic polyamide resins, and thermoplastic polysulfone resins, and thermoset matrix composites such as thermoset polyester resins, thermoset phenolic resins, thermoset epoxy resins, thermoset polyimide resins, and thermoset bismaleimide resins.

Successful adhesive bonding of organic-matrix composites is dependent on the nature of the adherend surfaces. This article emphasizes the critical importance of proper surface preparation in both thermoset and thermoplastic composites. It provides information on surface preparation for thermoset composite adherends along with a standard technique (water-break test) for verifying the adequacy of surface preparation for metal bonding. In addition, the article provides examples of good and bad adhesive bonds and describes some important process variables that are considered and controlled in bonding process for thermoset adhesives. The article concludes with a discussion on three different approaches for bonding thermoplastic composite composite panels together.