This article addresses some established protocols for characterizing thermoplastics and whether they are homogeneous resins, alloyed, or blended compositions or highly modified thermoplastic composites. It begins with a discussion on characterizing mechanical, rheological, and thermal properties of polymer. This is followed by a section describing molecular weight determination using viscosity measurements. Next, the article discusses the use of cone and plate and parallel plate geometries in melt rheology. It then reviews the processes involved in the analysis of thermoplastic resins by chromatography. Finally, the article covers three operations of thermoanalysis, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.

This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.

This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.

Engineering plastics, as a general class of materials, are prone to the development of internal stresses which arise during processing or during servicing when parts are exposed to environments that impose deformation and/or temperature extremes. Thermal stresses are largely a consequence of high coefficients of thermal expansion and low thermal diffusivities. Although time-consuming techniques can be used to analyze thermal stresses, several useful qualitative tests are described in this article. The classification of internal stresses in plastic parts is covered. The article describes the effects of low thermal diffusivity and high thermal expansion properties, and the variation of mechanical properties with temperature. It discusses the combined effects of thermal stresses and orientation that result from processing conditions. The article also describes the effect of aging on properties of plastics. It explains the use of high-modulus graphite fibers in amorphous polymers.

Failure of structural polymeric materials under cyclic application of stress or strain is a subject of industrial importance. The understanding of fatigue mechanisms (damage) and the development of constitutive equations for damage evolution, leading to crack initiation and propagation as a function of loading or displacement history, represent a fundamental problem for scientists and engineers. This article describes the approaches to predict fatigue life and discusses the difference between thermal and mechanical fatigue failure of polymers.

Wrought 4xxx alloys (extrusions and forgings) exhibit high surface hardness, wear resistance, and a low coefficient of thermal expansion. This article provides a summary of brazing filler metals used to join brazeable aluminum-base metals. It contains tables that list the nominal composition and filler-metal alloys of 4xxx series used in structural forms.

The aluminum alloy 1350 is an electrical conductor grade aluminum alloy with high thermal and electrical conductivities. This datasheet provides information on key alloy metallurgy and processing effects on physical and mechanical properties of this 1xxx series alloy.

The aluminum alloy 336.0 is a high-silicon alloy suitable for applications where good high-temperature strength, low coefficient of thermal expansion, and good resistance to wear are required. This datasheet provides information on key alloy metallurgy, processing effects on physical and mechanical properties, fabrication characteristics, and application characteristics of this 3xxx series alloy.

The purity of aluminum is generally characterized in one of two ways, by terminology or by the Aluminum Association designation system. This article reviews the properties of pure aluminum in purities from 99.99 percent through commercial purity, 99.00 percent. The mechanical properties of aluminum are discussed in terms of tensile properties, stress-strain relationships, and creep. The article also reviews the physical properties of aluminum, such as atomic structure and nuclear properties, atomic spectrum, crystal structure, density, thermal expansion, and thermal conductivity. It discusses the chemical properties of aluminum and presents a summary tabulation of the mechanical strength, ductility, and hardness of pure aluminum.

This article focuses on different aspects of wear particle analysis. It discusses the different wear regimes in the wear rate versus time (bathtub) curve. The article explains the essence of condition monitoring and how to properly sample lubricants for condition monitoring. It also discusses in-service lubricant analysis for condition monitoring, focusing on the spectrometric oil analysis program. The article describes the characteristics of wear particles and analytical techniques for characterizing them. It also describes the characteristics of different types of wear particles and the mechanisms by which they are generated. The article concludes with a summary of the major applications of wear particle analysis.

This article discusses the influence of microstructure and chemical composition on the physical properties of cast iron. The physical properties include density, thermal expansion, thermal conductivity, specific heat, electrical conductivity, magnetic properties, and acoustic properties. The article describes the properties of liquid iron in terms of surface energy, contact angles, and viscosity. The conductive properties such as thermal and electrical conductivity, of the main metallographic phases present in cast iron are presented in a table. The article discusses the magnetic properties of cast iron in terms of magnetic intensity, magnetic induction, magnetic permeability, remanent magnetism, coercive force, and hysteresis loss. It concludes with a discussion on the acoustic properties of cast iron.

In cast iron, residual stresses normally arise due to hindered thermal contraction, meaning that they are associated with the presence of constraints that prevent the natural, free volumetric variation of the material upon solid-state cooling. This article explains their mechanism of formation by introducing the scalar relation, known as the additive strain decomposition. The main factors influencing casting deformation are volume changes during solidification and cooling, phase transformations, alloy composition, thermal gradients, casting geometry, and mold stability. The article reviews the dimensional stability in cast iron and discusses macroscopic and microscopic stresses in cast iron.

The high-alloy irons can be categorized into two main groups: the high-alloy graphitic irons (covering both gray and ductile grades) and the high-alloy white irons. High-alloy irons are used in applications with demanding requirements, such as high resistance to wear, heat, and corrosion, or for combined properties. This article discusses the specification and selection of high-alloy irons. The common alloying elements and their effect on the stable and metastable eutectic temperatures are listed in a table. The article provides information on the compositions, properties and applications of high-alloy graphitic irons and high-alloy white irons.

According to the ISO 16112 standard for compacted graphite cast irons (CGIs), the graphite particles in CGIs shall be predominantly in the vermicular form when viewed on a two dimensional plane of polish. This article begins with a schematic illustration of compacted graphite microstructures with nodularity. It describes the tensile properties, hardness and compressive properties, and impact properties of CGI. The article concludes with a discussion on the fatigue strength and thermal conductivity of CGI.

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

The presence of macroscopic residual stresses in heat treatable aluminum alloys can give rise to machining distortion, dimensional instability, and increased susceptibility to in-service fatigue and stress-corrosion cracking. This article details the residual-stress magnitudes and distributions introduced into aluminum alloys by thermal operations associated with heat treatment. The available technologies by which residual stresses in aluminum alloys can be relieved are also described. The article shows why thermal stress relief is not a feasible stress-reduction technology for precipitation-hardened alloys. It examines the consequences of aging treatments on the residual stress, namely, annealing, precipitation heat treatment, and cryogenic treatment. The article provides information on uphill quenching, which attempts to reverse thermal gradients encountered during quenching. It examines how quench-induced residual stresses in heat treatable aluminum alloys are reduced when sufficient load is applied to cause plastic deformation. The article also shows how plastic deformation reduces residual stress.

This article provides information on nickel alloying elements, and the heat treatment processes of various nickel alloys for applications requiring corrosion resistance and/or high-temperature strength. These processes are homogenization, annealing, solution annealing, solution treating, stabilization treatment, age hardening, stress relieving, and stress equalizing. Discussion of furnaces, fixtures, and atmospheres is included. Nickel alloys used for the heat treatment processes include corrosion-resistant nickel alloys, heat-resistant nickel alloys, nickel-beryllium alloys, special-purpose alloys such as nitinol shape memory alloys, low-expansion alloys, electrical-resistance alloys and soft magnetic alloys. Finally, the article focuses on heat treatment modeling for selecting the appropriate heat treatment process.

Surface coatings are essential in all facilities that process nuclear materials or use nuclear fission for power generation. This article describes the coatings used in two basic types of Generation 3 nuclear reactor designs in the United States and their containment size. These reactors are the boiling water reactor (BWR) and pressurized water reactor (PWR). The article provides information on the loss-of-coolant accident (LOCA) identified as the design basis accident (DBA), which can rapidly de-water the core of an operating nuclear reactor. To avoid LOCA, both the BWR and the PWR include emergency core cooling systems. The article describes a DBA test and other coating performance parameters necessary for safety-related coating systems. It provides a detailed account of the selection criteria of coating types in a nuclear plant. The article concludes by highlighting protective coating strategies in Generation 3 Plants.

This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.