Gas quenching is one of the standard quenching technologies used in fabricating metallic components. The gas quenching process is usually performed at elevated pressures and is therefore mostly referred to as high-pressure gas quenching (HPGQ). This article presents the physical principles of HPGQ and also presents the equipment for gas quenching. The article describes the three types of gas that are mainly used for HPGQ: nitrogen, helium, and argon. It provides the mathematical model for heat fluxes and temperatures during HPGQ. The article also presents typical industrial applications for HPGQ in addition to equipment process and safety.

This article provides readers with a brief review of the applications of thermography in additive manufacturing (AM), which still is largely a research and development (R&D) effort. There is a particular focus on metals-based laser powder-bed fusion (L-PBF), although applications in directed-energy deposition (DED) and electron beam PBF (E-PBF) also are mentioned. The metrological basis of thermography is discussed in the article. Background information on radiation thermometry is provided, including how the various equations are applied. Finally, specific examples and lessons learned from various AM thermographic studies at the National Institute of Standards and Technology (NIST) are provided.

With any polymeric material, chemical exposure may have one or more different effects. Some chemicals act as plasticizers, changing the polymer from one that is hard, stiff, and brittle to one which is softer, more flexible, and sometimes tougher. Often these chemicals can dissolve the polymer if they are present in large enough quantity and if the polymer is not crosslinked. Other chemicals can induce environmental stress cracking (ESC), an effect in which brittle fracture of a polymer will occur at a level of stress well below that required to cause failure in the absence of the ESC reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface embrittlement and temperature on polymer performance.

This article focuses on various vacuum heat treating processes for additively manufactured parts, namely annealing and stress relieving, solid-solution annealing, and solution treating and aging. It addresses several practical concerns involved in using vacuum heat treatment, including temperature measurement, unvented cavities, loose powder, and direct contact of metals in the high-temperature vacuum. The article provides a short discussion on sintering and evaporation of metals in vacuum furnaces.

This article is a compilation of tables that present information on austenitizing temperatures for direct-hardening carbon and alloy steels, case depth of steels for different carburizing times and temperatures, typical heat treatments for case hardening of carbon and carburizing of alloy steels, as well as direct hardening of carbon steels and alloy steels.

This article describes the effects of furnace atmospheric elements on steels. These elements are air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide. The article provides useful information on six groups of commercially important prepared atmospheres classified by the American Gas Association on the basis of method of preparation or on the original constituents employed. These groups are designated and defined as follows: Class 100, exothermic base; Class 200, prepared nitrogen base; Class 300, endothermic base; Class 400, charcoal base; Class 500, exothermic-endothermic base; and Class 600, ammonia base. These are subclassified and numerically designated to indicate variations in the method by which they are prepared. The article also contains a table that lists significant furnace atmospheres and their typical applications.

The atmosphere within a furnace chamber is a basic factor in achieving the desired chemical reactions with metals during heat treating. This article presents the fundamentals of heat treating atmospheres, and describes two groups of atmosphere control, namely, furnace atmosphere control and supply atmosphere control. The two basic types of atmospheric supply systems are generated atmospheres and nitrogen-base atmospheres. The article provides a brief overview of the gas reactions associated with oxidation and carbon control to ensure either carburization, or to prevent decarburization. It demonstrates how the carbon potential control is achieved by controlling water vapor concentration, carbon dioxide concentration, or oxygen partial pressure. The article also describes the various devices and analyzers used to monitor sampled gas from furnace atmospheres, namely, chromatographs, oxygen probes, Orsat analyzers, infrared analyzers, dewpoint analyzers, and hot-wire analyzers. Finally, it discusses the advantages, disadvantages, and limitations of these analyzers.

This article discusses special considerations relative to induction heating of stainless steels and nickel-base superalloys. It focuses on the various industrial and high-temperature applications of induction heating to stainless steel and superalloy components, namely, primary melting processes, preheating for primary and secondary forming processes, heat treatments, brazing, and thermal processing for fusion welds. The article also provides information on computational modeling of induction heating processes for super alloys and stainless steels.

This article describes the metallurgy and process specifics of subcritical annealing, which involves heating below the lower critical temperature such that austenite does not form during subcritical annealing. It provides information on the nominal subcritical annealing temperatures of plain carbon, low-alloy and high-alloy steels and temperature-time relations of subcritical annealing. Practical implications for induction annealing and induction normalizing are included. The article concludes by describing induction softening, which softens the threaded area on carburized components such as hypoid pinion gears, to prevent the occurrence of delayed fractures from occurring.

This article reviews the classical models for the pseudo-steady-state temperature distribution of the thermal field around moving point and line sources. These include thick- and thin-plate models and the medium-thick-plate model. The analytical solutions to the differential heat flow equation under conditions applicable to fusion welding are provided. The article also provides an overview of the factors affecting heat flow in a real welding situation using the analytical modeling approach because this makes it possible to derive relatively simple equations that provide the required background for an understanding of the temperature-time pattern.

This article discusses three distinct mechanisms of bonding for solid-state (forge) welding processes, namely, contaminant displacement/interatomic bonding, dissociation of retained oxides, and decomposition of the interfacial structure. It explains the processes that can be characterized as having two stages: heating and forging. The article also includes a table that illustrates weld strengths as a function of annealing temperature for a range of materials.

This article is a compilation of tables that provide information on preheat and interpass temperatures and the postweld heat treatment for selected carbon steels, as well as steel pressure vessels and pipe welds. Information is also provided for preheat and interpass temperatures of heat treatable steels, namely, low-alloy steels and ultra high-strength steels.

This article provides information on metals that can be cast in permanent molds. It describes the advantages, disadvantages, applications, and design of permanent castings. Following a discussion on the factors considered in mold design and material selection, the article details the application of mold coatings and examines the effects of major processing variables on mold life. The variables that determine mold temperature and measures for controlling it are reviewed, and the effects of short-term and long-term variables on the dimensional accuracy of permanent mold castings are explained. The article concludes with a discussion on the factors influencing the surface finish on permanent mold castings.

Constitutive relations for metal-working include elements of behavior at ambient temperature as well as high-temperature response. This article presents the equations for the strain hardening and strain-rate-sensitive flow, with alternate sections on empirically determined properties, followed by models of constitutive behavior. These models include the isothermal constitutive model and the physical model for superplastic flow. A formal description of the superposition of the operative mechanisms for dynamic recovery at hot-working strain rates is also provided. The article describes creep mechanisms that are useful for illustrating the strong stress dependence of dislocation and diffusional flow.

This article describes the laboratory techniques for direct measurement and quantification of die wear in verifying a proprietary die-wear predictor methodology. This method is based on a theoretical formula that can be used to predict the rate of die wear and the life of a die surface coating, applicable to both mild steel and high-strength steels stampings. The article discusses the behavior of the surface conditions through quantitative measurements and surface analyses conducted throughout the wear tests. The surface conditions include surface roughness, surface morphology, microstructure, interfacial friction, surface temperatures, and wear rate.

Nitric acid is a strongly oxidizing acid that is aggressively corrosive to many metals. Its oxidizing nature is affected by acid temperature and concentration, and composition of the alloy exposed to it. This article focuses on the corrosion behavior of various ferrous and nonferrous metals and alloys when exposed to a nitric acid environment. The ferrous and nonferrous metals and alloys discussed are carbon and alloy steels, stainless steels, aluminum alloys, titanium, zirconium alloys, niobium and tantalum, and nonmetallic materials.

Plastic deformation can occur in metals from various mechanisms, such as slip, twinning, diffusion creep, grain-boundary sliding, grain rotation, and deformation-induced phase transformations. This article emphasizes on the mechanism of slip and twinning under cold working conditions. It discusses the factors on which the structures developed during plastic deformation depend. These factors include crystal structure, amount of deformation, composition, deformation mode, and deformation temperature and rate. The article illustrates the microstructural features that appear after substantial deformation when revealed through metallographic investigation.

The constitutive relations for metalworking include elements of behavior at ambient temperature as well as high-temperature response. This article presents equations for strain hardening and strain-rate-sensitive flow, with alternate sections on empirically determined properties, followed by the models of constitutive behavior. It provides a discussion on creep mechanisms involving dislocation and diffusional flow, such as the Nabarro-Herring creep and the Coble creep. The equations for the several creep rates are also presented. Research on the mechanism of the superplastic flow in fine-grain metals has encompassed many ideas, such as the diffusional creep, dislocation creep with diffusional accommodation at grain boundaries, and concepts of grain-mantle deformation. The article concludes with information on the kinetics of superplastic deformation processes, including low stress behavior, concurrent grain growth, and high stress behavior.

This article provides a description of the classification, industrial applications, microstructures, physical, chemical, corrosion, and mechanical properties of zirconium and its alloys. It discusses the formation of oxide films and the effects of water, temperature, and pH on zirconium. The delayed hydride cracking of zirconium is also described. The article provides information on the resistance of zirconium to various types of corrosion, including pitting corrosion, crevice corrosion, intergranular corrosion, galvanic corrosion, microbiologically induced corrosion, erosion-corrosion, and fretting corrosion. The article explains the effects of tin content in zirconium and effects of fabrication on corrosion. Corrosion control measures for all types of corrosion are also highlighted. The article concludes with information on the safety precautions associated with handling of zirconium.

Mechanical properties are often the most important properties in the design and selection of engineering plastics. Temperature, molecular structure, crystallinity, viscoelasticity, and effects of environment, fillers and reinforcements are considered as the basic factors affecting the mechanical properties of engineering plastics. The testing methods for determining mechanical properties, including stress-strain test, modulus-directed tensile test, strength test, strength-directed tensile test, impact test, and dynamic mechanical test are discussed.