This article provides a brief introduction to abrasive wear-resistant coating materials that contain a large amount of hard phases, such as borides, carbides, or carboborides. It describes some of the commonly used methods of producing thick wear-resistant coatings. The article also provides information on metal-matrix composites and cemented carbides. The three base-alloying concepts, including cobalt-, iron-, and nickel-base alloys used for wear-protection applications, are also described. The article compares the tribomechanical properties of the materials in a qualitative manner, thus allowing a rough materials selection for practitioners. It presents a brief discussion on hot isostatic pressing (HIP) cladding, sinter cladding, and manufacturing of thick wear-resistant coatings by extrusion or ring rolling. The article also discusses the processing sequence of thick wear-resistant coatings, namely, compound casting, deposition welding, and thermal spraying.

Abrasive wear is a surface-damage process with material loss caused by hard asperities or abrasive particles occurring when two surfaces are sliding against each other. There are two types of abrasive wear: two-body abrasion and three-body abrasion. This article discusses the abrasive wear mechanism in ductile materials and commonly used testers for evaluating the resistance of materials to abrasive wear. The testers include pin-on-disk, block-on-ring, block-on-drum, and dry sand/rubber wheel abrasion tester. The article reviews the abrasion resistance of metallic materials, ceramic materials, and polymeric materials. It discusses factors that influence abrasive wear, including the environment, hardness, toughness, microstructure, and lubrication.

Boronizing is a case hardening process for metals to improve the wear life and galling resistance of metal surfaces. Boronizing can be carried out using several techniques. This article discusses the powder pack cementation process for carrying out boronizing. It describes the structures of boride layers in ferrous materials and boride-layer structures in nickel-base superalloys. The primary reason for boriding metals is to increase wear resistance against abrasion and erosion. The article reviews the wear resistance and coefficient of friction of boride layers, as well as galling resistance of borided surfaces. It concludes with a discussion on boronizing plus physical vapor deposition (PVD) overlay coating.

Austempered ductile iron (ADI) results from a specialty heat treatment of ductile cast iron. This article discusses the production of austempered ductile iron by heat treatment. The austempered ductile iron grades, according to ISO 17804 and EN 1564, are presented in a table. For economic reasons, or to avoid metallurgical problems, combinations of alloys are often used to achieve the desired hardenability in austempered ductile iron. The article provides information on the alloy combinations for austempered ductile iron. The mechanical properties, fracture toughness, fatigue, and abrasion resistance of the austempered ductile iron are discussed. The article concludes with information on the applications for austempered ductile iron.

The high-alloyed white irons are primarily used for abrasion-resistant applications and are readily cast into the parts needed in machinery for crushing, grinding, and handling of abrasive materials. This article discusses three major groups of the high-alloy white cast irons: nickel-chromium white irons, chromium-molybdenum irons, and high-chromium white irons. Mechanical properties for three white irons representing each of these three general groups are presented as bar graphs. The article also describes the various heat treatments of a martensitic microstructure, including austenitization, quenching, tempering, annealing, and stress relieving.

This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.

Polyvinylidene fluoride (PVDF)-based coatings are typically used in outdoor applications that require exceptionally high performance and excellent long-term exterior durability with little maintenance. This article provides a background of three fluoropolymers most commonly used for coatings, namely, PVDF, polyvinyl fluoride, and polytetrafluoroethylene. It focuses on general properties, polymerization, resin types, coating formulation, technology of organic coatings, coating properties, and health and related safety considerations of PVDF. The article describes the application and typical end uses of PVDF-based coatings and the opportunities for improvement in PVDF-based coatings as with all organic coatings.

Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.

This article describes the coating materials, surface-preparation requirements, and application techniques used to protect underground pipelines. It provides a valuable insight into the types of polymer-based coatings that are both cost-effective and widely accepted in the pipeline industry.

Independent verification of coating system performance can be based on laboratory testing and/or field exposure. Qualification testing is a critical component to coating system selection. This article focuses on performance evaluations that are used to prequalify coating systems, namely, facility-specific, industry-specific, coating-type-specific, or a combination of these. It describes the standard laboratory tests used to generate performance data, namely, physical, compositional, chemical exposure, and application characteristics tests. The pros and cons of using manufacturer-generated data versus independently generated data are discussed. The article provides information on accelerated corrosion/weathering testing and nuclear level 1/level 2 service coatings qualification. It also describes the procedures for establishing minimum performance requirements and for determining when requalification testing may be required.

Coatings, such as those applied to ships, must be resistant to abrasion, in the case of cargo hold coatings, and cyclic changes of chemicals and tank cleaning, in the case of tank linings. Failures and defects can manifest themselves at various times in the life of a coating. To determine the cause and mechanism of coating failure, all possible contributory factors must be evaluated together with a detailed history from the time of application to the time the failure was first noted. Many coating failures require further evaluation and analysis to be carried out by a qualified chemist or coating specialist, often using specialized laboratory equipment. The article presents examples of coating failures and defects, together with descriptions, probable causes, and suggested preventative measures.

High-alloyed white cast irons are an important group of materials whose production must be considered separately from that of ordinary types of cast irons. The metallic matrix supporting the carbide phase in the high-alloy white cast irons can be adjusted by alloy content and heat treatment to develop proper balance between resistance to abrasion and toughness needed to withstand repeated impact. This article provides a brief discussion on the heat treatment, mechanical properties, and chemical compositions of high-alloy white cast irons such as nickel-chromium white irons and high-chromium white irons.

This article provides a detailed discussion on the effect of boron in heat-treated steel and thermomechanically-simulated steel. It describes the boron hardenability mechanism and the effect of composition and heat treatment parameters on boron hardenability. The article examines the hardening behavior of unalloyed boron steel and low-alloyed boron steel in heat treatment experiments by varying the austenitizing temperatures and cooling conditions. It also discusses the applications of boron steels.

Natural and synthetic rubber linings are used extensively in many industries for their corrosion and/or abrasion resistance. These industries include transportation, chemical processing, water treatment, power, mineral processing, and mining. This article provides information on soft natural rubber, semihard natural rubber, hard natural rubber, neoprene or polychloroprene, chlorobutyl, three-ply linings, nitrile, and ethylene propylene with a diene monomer. Emphasis is placed on advantages, disadvantages, and common uses of each material discussed.

Cemented carbides are extremely important in corrosion conditions in which high hardness, wear resistance, or abrasion resistance is required. This article describes the effect of binder composition and carbide addition on corrosion behavior of cemented carbides. It lists the examples of their uses in corrosion applications. The article provides information on the selection of cemented carbides for corrosion applications and tabulates the corrosion resistance of cemented carbides in various media. It expounds the oxidation resistance of cemented carbides and presents some tips to improve the properties of tungsten carbide cutting tools. The article also details the coating materials and coating processes of cemented carbides.