Hardening and depth of hardening of steel is a critically important material and process design parameter. This article presents a selective overview of experimental and predictive procedures to determine steel hardenability. It also covers the breadth of steel hardenability, ranging from shallow, to very difficult to harden, to air-hardening steels.

This article introduces some of the general sources of heat treating problems with particular emphasis on problems caused by the actual heat treating process and the significant thermal and transformation stresses within a heat treated part. It addresses the design and material factors that cause a part to fail during heat treatment. The article discusses the problems associated with heating and furnaces, quenching media, quenching stresses, hardenability, tempering, carburizing, carbonitriding, and nitriding as well as potential stainless steel problems and problems associated with nonferrous heat treatments. The processes involved in cold working of certain ferrous and nonferrous alloys are also covered.

The general structural alloy 6061 is a balanced alloy containing silicon and magnesium in appropriate proportions to form magnesium silicide, which makes the alloy precipitation hardenable. This datasheet provides information on key alloy metallurgy, processing effects on physical and mechanical properties, and fabrication characteristics of this 6xxx series alloy.

Austempered ductile iron (ADI) results from a specialty heat treatment of ductile cast iron. This article discusses the production of austempered ductile iron by heat treatment. The austempered ductile iron grades, according to ISO 17804 and EN 1564, are presented in a table. For economic reasons, or to avoid metallurgical problems, combinations of alloys are often used to achieve the desired hardenability in austempered ductile iron. The article provides information on the alloy combinations for austempered ductile iron. The mechanical properties, fracture toughness, fatigue, and abrasion resistance of the austempered ductile iron are discussed. The article concludes with information on the applications for austempered ductile iron.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. This article describes surface hardening of gray irons by flame and induction heating. It provides information on the classification of the gray irons in ASTM specification. The article presents examples that illustrate the use of stress relieving to eliminate distortion and cracking. It describes the three annealing treatments of gray iron: ferritizing annealing, medium (or full) annealing, and graphitizing annealing. The article discusses the parameters of the tensile strength and hardness of a normalized gray iron casting. These include combined carbon content, pearlite spacing, and graphite morphology. The article concludes with a discussion on the induction hardening of gray iron castings.

Ductile cast irons are heat treated primarily to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article discusses the most important heat treatments of ductile irons and their purposes. International standards of ductile iron provided by ASTM International, the International Organization for Standardization (ISO), and SAE International are presented in a table. The article explains basic structural differences between the ferritic, pearlitic, martensitic, and ausferritic classes. It presents recommended practices for annealing ductile iron castings for different alloy contents and for castings with and without eutectic carbides. The article discusses the induction surface hardening and remelt hardening of ductile iron. It concludes with information on the effect of heat treatment on fatigue strength of ductile iron.

Quenching is a widely used technique to strengthen titanium alloys. This article presents the metallurgical and structural background underlying the specific techniques applied in the quenching of various titanium alloys, and the ways to control and reduce residual stresses induced from quenching or other thermal or mechanical processes. It discusses the types and microstructures of titanium alloys, namely, alpha, alpha-beta, and beta alloys, and describes the general effects of the various heat treatments. The article provides information on quenching media, quenching rate, section size, and martensitic transformation in quenched titanium alloys. It shows how residual stresses in titanium alloys are evaluated and controlled. Finally, the article describes the stress-relief treatments used to reduce residual stresses.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. The heat treatment of gray irons can considerably alter the matrix microstructure with little or no effect on the size and shape of the graphite achieved during casting. This article provides a detailed account of classes of gray iron, and heat treating methods of gray irons with examples. These methods include stress relieving, annealing, normalizing, transformation hardening, austenitizing, quenching, austempering, martempering, flame hardening, induction hardening, and nitriding.

Ductile cast irons are heat treated to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article provides a detailed account of the general characteristics of ductile irons. It discusses the most important heat treatments of ductile irons, namely, stress relieving, austenitizing, annealing, normalizing, quenching, martempering, austempering, and surface hardening. The article elucidates the effects of these heat treatments on the mechanical properties of the ductile irons.

The choice of heat treatment depends on the service requirements of a given bearing and how the bearing will be made. This article describes the design parameters, material characteristics required to sustain performance characteristics, metallurgical properties, and dimensional stability. It also provides a description of various extensively-used heat treatment processes, namely, carburizing, carbonitriding, induction surface hardening, and nitriding associated with various bearings. In addition, the article explores the factors to be considered in selecting a process and explains why it is optimum for a specific application.

Powder metallurgy (PM) processes include press and sinter hardening, metal injection molding, powder forging, hot isostatic pressing, powder rolling, and spray forming. This article provides an overview of PM processing methods and general considerations of heat treatment of PM parts that are case-hardened to obtain higher hardness, wear, fatigue, and impact properties. It describes the effects of porosity on heat treatment, alloy content on PM hardenability, and starting material on homogenization of PM steels. The article describes the properties, following heat treatment, of low-alloy steels tempered at 175 ºC for one hour, and lists recommended quench and temper parameters to achieve good wear resistance and core strength based on different ranges of porosity.

This article discusses the classification of carbon steels based on carbon content, and tabulates the compositional limits of medium- and high-carbon steels based on the AISI code and other similar codes. It describes recrystallization annealing and spheroidizing of carbon steels, and discusses the classification of carbon steels for heat treatment. The article also discusses the estimation of continuous cooling curves from isothermal transformation curves. It provides information on the Jominy end-quench test and the Grossmann method and the procedures to increase hardenabilty of carbon steels. The article includes information on the purpose of tempering and heat treating guidelines for different grades of steels, including cast carbon steels.

This article commences with a brief introduction on the hardenability of carburized steels, and then reviews the factors used in the selection of carburizing steels and heat treatment methods. The factors include quench medium, stress considerations, case depth, and type of case. The article provides information on steels for carburized gears with emphasis on gear design requirements, selection process, selection of carbon content, case and core hardness, microstructure, and toughness and short-cycle fatigue.

Hardenable steels with high-alloy content includes a family of nickel-cobalt steels with high strength and high toughness. This article describes various heat treatments, namely, normalizing, annealing, hardening, tempering, stress relieving, overaging, quenching, refrigeration, and straightening treatment, applied to HP9-4-20, HP9-4-25, HP9-4-30, and HP9-4-45 steels. These steels have high fracture toughness when heat treated to very high strength levels. The article also describes heat treatments applied to other alloys such as AF 1410, AerMet 100, AerMet 310, and AerMet 340, which provide a good combination of high strength and toughness that make them attractive for aerospace application. It also presents tables that provide information on the effect of aging temperatures and heat treatment on mechanical properties and impact energy of these steels.

This article provides a detailed discussion on the effect of boron in heat-treated steel and thermomechanically-simulated steel. It describes the boron hardenability mechanism and the effect of composition and heat treatment parameters on boron hardenability. The article examines the hardening behavior of unalloyed boron steel and low-alloyed boron steel in heat treatment experiments by varying the austenitizing temperatures and cooling conditions. It also discusses the applications of boron steels.

This article focuses on various heat-treating practices, namely, normalizing, annealing, stress relieving, preheating, austenitizing, quenching, tempering, and nitriding for cold-work tool steels. The cold-work tool steels include medium-alloy air-hardening tool steels, high-carbon high-chromium tool steels, and high-vanadium-powder metallurgy tool steels. The article also describes the properties, types, nominal compositions and designations of these cold-work tool steels.

This article provides useful information on the selection of steels for heat treatment in order to achieve the required hardness. It discusses the effects of alloying elements on hardenability using the Grossmann's concept, and presents a discussion on the effects of alloying elements in hot-worked and cold-drawn steels. The article focuses on the selection of carbon and alloy steels based on the function of the alloying elements, and discusses the specific effects of alloying elements in steel in a tabulated form. The depth and degree of hardening (percentage of martensite) are dictated by the engineering stress analysis. Mechanical properties of quenched and tempered steels develop similar tensile properties for all practical purposes for all compositions with the same hardness. The article also provides information on the selection of steels to meet the required hardness, and elucidates the concept of hardenability for wear resistance with the help of graphs.

This article is a comprehensive collection of graphs that present information on the hardenability bands of various grades of alloy steels. It also includes figures showing correlations of Jominy equivalent cooling rates, plots of end-quench bands of carbon steels, and logarithmic plots of relative hardenability of carbon steels.

Hardenability of steel depends on carbon content and other alloying elements as well as on the grain size of the austenite phase. This article provides information on the calculation of high-carbon (carburized) steel hardenability. It contains tables that list multiplying factors that are used for the calculation of case hardenability of carburizing steels and the hardenability of high-carbon steels hardened after a prior normalize or quench treatment. The article reviews the derivation and limitations of multiplying factors.

Hardenability is a composition-dependent property of steel and depends on carbon content and other alloying elements as well as the grain size of the austenite phase. This article provides an overview of a wide range of testing procedures used to determine and quantify hardenability of shallow-hardening, low-carbon, plain carbon, and low-alloy medium-carbon steels ranging from classical fracture and etching, Grossmann hardenability, and Jominy end-quench testing to manual and computerized computational methods. The article then uses this as a backdrop for the implementation of the core concepts of hardenability in a variety of predictive tools for calculating hardenability. The Caterpillar 1E0024 Hardenability Calculator, a personal computer-based program, calculates the Jominy curve based on the steel composition. The article also describes the method for boron and nonboron steels, with calculation examples for 8645 steel and 86B45 steel.