Additive manufacturing (AM) has been growing as a significant research interest in academic and industry research communities. This article presents flexible and biocompatible energy-harvesting devices using AM technology. First, it discusses material selection for achieving piezoelectricity and triboelectricity. Then, the article highlights the structures of energy harvesters and describes their working mechanisms. Next, it covers the additively manufactured implantable piezoelectric and triboelectric energy harvesters. Further, the article describes the 3D-printed wearable energy harvesters as well as their applications. An overview of additively manufactured self-powered sensors is highlighted. Finally, the article discusses the issues for 3D-printed energy harvesters and their roadmap.