This article addresses some established protocols for characterizing thermoplastics and whether they are homogeneous resins, alloyed, or blended compositions or highly modified thermoplastic composites. It begins with a discussion on characterizing mechanical, rheological, and thermal properties of polymer. This is followed by a section describing molecular weight determination using viscosity measurements. Next, the article discusses the use of cone and plate and parallel plate geometries in melt rheology. It then reviews the processes involved in the analysis of thermoplastic resins by chromatography. Finally, the article covers three operations of thermoanalysis, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.

Failure analysis is an investigative process in which the visual observations of features present on a failed component and the surrounding environment are essential in determining the root cause of a failure. This article reviews the basic photographic principles and techniques that are applied to failure analysis, both in the field and in the laboratory. It discusses the processes involved in visual examination, field photographic documentation, and laboratory photographic documentation of failed components. The article describes the operating principles of each part of a professional digital camera. It covers basic photographic principles and manipulation of settings that assist in producing high-quality images. The need for accurate photographic documentation in failure analysis is also presented.

This article presents the mechanisms of polymer wear and quantifies wear in terms of wear rate (rate of removal of the material). Interfacial and bulk wear are discussed as well as a discussion on the wear study of "elastomers," "thermosets," "glassy thermoplastics," and "semicrystalline thermoplastics." The article also discusses the effects of environment and lubricant on the wear failures of polymers. It presents a case study on considering nylon as a tribological material and failure examples, explaining wear resistance of polyurethane elastomeric coatings and failure of an acetal gear wheel.

This article discusses technologies focused on processing plastic materials or producing direct tools used in plastics processing. The article focuses on extrusion and injection molding, covering applications, materials and their properties, equipment, processing details, part design guidelines, and special processes. It also covers the functions of the extruder, webline handling, mixing and compounding operations, and process troubleshooting. Thermoforming and mold design are covered. Various other technologies for polymer processing covered in this article are blow molding, rotational molding, compression molding, transfer molding, hand lay-up process, casting, and additive manufacturing.

This article focuses on a study that was performed to understand the effects of powder attributes; process parameters; and hot isostatic pressing (HIP) treatment on the densification, mechanical and corrosion properties, and microstructures of 17-4 PH stainless steel gas- and water-atomized laser-powder bed fusion (LPBF) parts at various energy densities. The results from the study showed the strong dependence of densification, mechanical properties, and microstructures on temperature, pressure, and time during the HIP cycle. The density, ultimate tensile strength, hardness and yield strength of gas and water-atomized LPBF parts increased due to HIP treatment and were higher than as-printed properties. The results also confirmed superior corrosion performance of the HIP treated LPBF parts.

This article endeavors to familiarize the reader with a selection of different ionization designs and instrument components to provide knowledge for sorting the various analytical strategies in the field of solid analysis by mass spectrometry (MS). It begins with a description of the general principles of MS. This is followed by sections providing a basic understanding of instrumentation and discussing the operating requirements as well as practical considerations related to solid sample analysis by MS. Instrumentation discussed include the triple quadrupole mass spectrometer and the time-of-flight mass spectrometer. Inductively coupled plasma and thermal ionization MS provide atomic information, and direct analysis in real-time and matrix-assisted laser-desorption ionization MS are used to analyze molecular compositions. The article describes various factors pertinent to ionization methods, namely glow discharge mass spectrometry and secondary ion mass spectrometry. It concludes with a section on various examples of applications and interpretation of MS for various materials.

This article focuses on wet chemical methods that have stood the test of time in laboratories around the world. It begins with a description of the appropriateness of classical wet methods. This is followed by sections on sampling procedures, basic chemical equilibria, and wet analytical chemistry. Mechanical methods and nonoxidizing acids and/or acid mixtures for dissolving solid samples for wet chemical analysis are then reviewed. Qualitative methods that are used to identify materials by wet chemical reaction are also included. The article provides information on various methods for the separation of chemical mixtures and on the types of gravimetry and titrimetry. Strategies for removing inclusions are also included to aid in their compositional understanding. The article also briefly describes the processes involved in chemical surface studies and partitioning of oxidation states. It ends by presenting some examples of the applications of classical wet methods.

This article focuses on the principles and applications of X-ray photoelectron spectroscopy (XPS) for the analysis of elemental and chemical composition. The discussion covers the nomenclature, instruments, and specimen preparation process of XPS. Some of the factors pertinent to the calibration of materials for accurate measurements using XPS are provided, along with some aspects of the accuracy in quantitative analysis by XPS. In addition, the article presents examples of how XPS data can be used to solve problems with surface interactions.

This article illustrates the relationships among commonly used 2xxx series alloys. It contains tables that list values for composition limits of aluminum-lithium alloys, and aerospace alloys and their temper conditions according to primary design requirements.

The extrusion alloy 7349 was developed by Pechiney and introduced in 1994 to provide higher strength properties than incumbent 7x75 and 7150 alloys. This datasheet provides information on composition limits and processing effects on mechanical properties of this aluminum alloy. Performance comparisons of alloys 7349-T6511 with 7175-T76511 and 7349-T7651 with 7175-T77511 are also illustrated.

The extrusion and sheet alloy 6056 was developed to provide weldable thin extrusions with an excellent balance between high strength and corrosion resistance. This datasheet provides information on composition limits, processing effects on mechanical properties, and applications of this 6xxx series alloy. It provides a material performance comparison of aluminum alloys 6056-T6511 with 2024-T3511 and 6056-T8511 with 2024-T3511.

Alloy 2196 is a higher Li-containing alloy registered in 2000 for various aircraft extrusion parts. This datasheet provides information on composition limits and applications of alloy 2196 and 2296 as well as processing effects on mechanical properties of 2196-T8511 extrusions. A performance comparison of 2196-T8511 extrusion with alloy 2024 is also presented.

This datasheet provides information on composition limits, fabrication characteristics, processing effects on physical and mechanical properties, and application performance of thick plate and forging alloy 7085. It presents the specified minimum strength and fracture properties for plate, die, and hand forgings. The datasheet provides a comparison of the strength, fracture toughness, and fatigue crack growth resistance of alloy 7085 plate with those of the legacy plate alloy 7050. It shows tensile yield and ultimate strength at elevated temperature for various temperatures and exposure times for 7085-T7452 die forgings.

Alloy 2198 is an Al-Cu-Li alloy that is used in combination with 2196-T8 stringers for the fuselage skins of the Bombardier C-Series. This datasheet provides information on composition limits of the alloy 2198 and provides a performance comparison of 2198-T8 and 2024-T351 alloys.

This datasheet provides information on composition limits, fabrication characteristics, processing effects on physical and mechanical properties, and applications of aluminum alloy 7039.

This datasheet provides information on composition limits for aluminum alloy 7255, with emphasis on the minimum static properties of aluminum alloy 7255 plate and fracture toughness of aluminum alloy 7255-T7751. Fatigue crack growth resistance of alloy 7255 plate is compared with those of legacy alloy 7055 plate.

Aluminum and its alloys are highly corrosion resistant, protected by a self-healing oxide film that effectively passivates the underlying surface. This article examines the various processes by which the protective layer can be breached and the types of corrosion that can occur. It describes pitting, galvanic, and atmospheric corrosion as well as stress-corrosion cracking, corrosion fatigue, and erosion corrosion. It also covers intergranular, exfoliation, filiform, deposition, and crevice corrosion and special cases of corrosion in soils, seawater, and automotive coolant systems. The article provides an extensive amount of data as well as information on coatings, claddings, and cathodic protection methods; the effects of composition, microstructure, and surface treatments; and the compatibility of aluminum with food and various household and industrial chemicals.

This article contains tables that provide values for compositions and physical and mechanical properties of 1xxx series aluminum alloys. Emphasis is placed on highly refined aluminum (1199) and high-purity aluminum (1060). Examples of common 1xxx series aluminum alloys specified in products standards are also presented. A figure illustrates the effect of purity on strength and hardness of unalloyed aluminum.

This datasheet provides information on key alloy metallurgy, fabrication characteristics, processing effects on physical and mechanical properties, and applications of Al-Cu-Si general-purpose casting alloy 208.0 (aluminum alloy 2xxx).