Malleable iron is a type of cast iron that has most of its carbon in the form of irregularly shaped graphite nodules instead of flakes, as in gray iron, or small graphite spherulites, as in ductile iron. This article discusses the production of malleable iron based on the metallurgical criteria: to produce solidified white iron throughout the section thickness; and to produce the desired graphite distribution (nodule count) upon annealing. It describes the induction heating and quenching or flame heating and quenching for surface hardening of fully pearlitic malleable iron. Laser and electron beam techniques also have been used for hardening selected areas on the surface of pearlitic and ferritic malleable iron castings that are free from decarburization.

This article presents an overview of common heat treating problems arising due to poor part design, material incapabilities, difficult engineering requirements, incorrect heat treatment practice, and nonuniform quenching with emphasis on distortion and cracking of quenched and tempered steels. It provides useful information on selection of steels for heat treatment, and discusses the causes of residual stresses, distortion (size and shape), and size changes due to hardening and tempering. The article elucidates the control techniques for such distortions. It describes the importance of decarburizing, and discusses the problems caused by heating, cracking, quenching, typical steel grades, and design.

This article focuses on the mechanisms, models, prevention, correction, and effects associated with decarburization inherited from semi-finished product processing prior to induction heating. It discusses the diffusion of carbon in austenitic iron, which has a face-centered cubic crystal structure that provides an interstitial path for the migration of the relatively small carbon atoms. The article describes the evolution of steel microstructure with progressive decarburization (in air) to a steady-state carbon gradient using an iron-iron carbide phase diagram. It provides useful information on the impact of alloying on vulnerability to decarburization, and the impact of decarburization on the mechanical properties of steels and cast irons. The article also describes the technological operations that potentially cause decarburization and the practical implications for induction hardening.

Of the various thermal processing methods for steel, heat treating has the greatest overall impact on control of residual stress and on dimensional control. This article provides an overview of the effects of material- and process-related parameters on the various types of failures observed during and after heat treating of quenched and tempered steels. It describes phase transformations of steels during heating, cooling of steel with and without metallurgical transformation, and the formation of high-temperature transformation products on the surface of a carburized part. The article illustrates the use of carbon restoration on decarburized spring steels. Different geometric models for carbide formation are shown schematically. The article also describes the different microstructural features such as grain size, microcracks, microsegregation, and banding.

This article discusses the important characteristics of fluidized beds. The total space occupied by a fluidized bed can be divided into three zones: grid zone, main zone, and above-bed zone. The article discusses the various types of atmospheres of fluidized beds, such as oxidizing and decarburizing atmosphere; nitrocarburizing and nitriding atmosphere; carburizing and carbonitriding atmosphere; and chemical vapor deposition atmosphere. External resistance heating, external combustion heating, internal resistance heating, direct resistance heating, submerged combustion heating, and internal combustion heating can be used to achieve the heat input for a fluidized bed. The article also describes the operations, design considerations, and applications of fluidized-bed furnaces in heat treating. Thermochemical surface treatments, such as carburizing, carbonitriding, nitriding, and nitrocarburizing, are also discussed. Finally, the article reviews the principles and applications of fluidized-bed heat treatment.

Induction hardening involves multiple processing steps of heating and quenching which presents opportunity for errors and defects. This article discusses the common problems associated with induction hardening of shafts as well as the methods to diagnose, inspect, and prevent them. In addition to the major defects such as laps and seams that remain after induction hardening, microstructural transformation, decarburization, residual stress, and grain size, as well as variations in carbon content, composition, or microstructure can also affect the hardened part.

This article discusses the most common methods of melting steels, namely, electric arc and induction melting. It describes the classification of refractories by an index of the “basicity” of the slag formed on the steel surface. The article provides a discussion on the converter metallurgy, which includes melt refinement in argon oxygen decarburization (AOD) vessels and vacuum oxygen decarburization (VODC) in a converter vessel. It also discusses ladle metallurgy, which includes vacuum induction degassing, vacuum oxygen decarburization, and vacuum ladle degassing.

This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.

The high-temperature corrosion processes that are most frequently responsible for the degradation of furnace accessories are oxidation, carburization, decarburization, sulfidation, molten-salt corrosion, and molten-metal corrosion. This article discusses each corrosion process, along with the corrosion behavior of important engineering alloys. It describes the corrosion of plating, anodizing, and parts of pickling equipment such as tanks, wirings and bus bars, racks, anode splines, pumps, and heaters.