The surface of irons and steels can be hardened by introducing nitrogen (nitriding), nitrogen and carbon (nitrocarburizing), or nitrogen and sulfur (sulfonitriding) into the surface. This article lists the principal reasons for nitriding and nitrocarburizing, and summarizes the typical characteristics of nitriding processes along with a general comparison of carburizing processes in a table. It describes the two most common nitriding methods: gas nitriding and ion (plasma) nitriding. The article discusses the wear behavior of nitrided layers and the wear resistance of selected steels. Rolling-contact fatigue (RCF) occurs in rolling contacts such as bearings, rolls, and gears. The article provides a discussion on rolling-contact fatigue of nitrided steels for aerospace bearing components.

Tool steels are carbon, alloy, and high-speed steels that can be hardened and tempered to high hardness and strength values. This article discusses the classifications of commonly used tool steels: water-hardening tool steels, shock-resisting tool steels, cold-work tool steels, and hot-work tool steels. It describes four basic mechanisms of tool steel wear: abrasion, adhesion, corrosion, and contact fatigue wear. The article describes the factors to be considered in the selection of lubrication systems for tool steel applications. It also discusses the surface treatments for tool steels: carburizing, nitriding, ion or plasma nitriding, oxidation, boriding, plating, chemical vapor deposition, and physical vapor deposition. The article describes the properties of high-speed tool steels. It summarizes the important attributes required of dies and the properties of the various materials that make them suitable for particular applications. The article concludes by providing information on abrasive wear and grindability of powder metallurgy steels.

Cast irons, like steels, are iron-carbon alloys but with higher carbon levels than steels to take advantage of eutectic solidification in the binary iron-carbon system. This article introduces the solid-state heat treatment of iron castings and describes the various processes of heat treatment of cast iron. It provides information on stress relieving, annealing, normalizing, through hardening, and surface hardening of these castings. The article discusses general considerations for the heat treatment of cast iron. Cast irons are occasionally nitrided for various applications with the aim of enhancing surface hardness and corrosion resistance of the products. The article describes molten salt bath cyaniding and ion nitriding of cast iron.

Aluminum and its alloys are characterized by their low hardness and less satisfactory tribological performance. These limits can be overcome by means of load-specific surface engineering. This article provides information on the structure and properties of nitrided layers, and the technologies and mechanisms used for nitriding aluminum and its alloys. It also describes the nitriding behavior of aluminum alloys. The article concludes by describing how a combination of technologies can be utilized to achieve aluminum nitride with the highest tribological properties.

This article describes the nitriding methods of titanium alloys such as plasma nitriding and gas nitriding. It focuses on the interaction of titanium alloys, interaction of titanium with nitrogen, and the interaction of titanium with oxygen, carbon, and hydrogen. The article provides information on the wear and fatigue properties and corrosion resistance of nitrided titanium alloys, as well as the effect of nitriding on the biocompatibility of titanium. It also compares plasma-nitrided titanium alloys with alloy steels. It concludes with a short discussion on the effect of nitriding on the surface properties of titanium and two-phase α + β alloys.

This article provides a detailed discussion on the heating equipment used for austenitizing, quenching, and tempering tool steels. These include salt bath furnaces, controlled atmosphere furnaces, fluidized-bed furnaces, and vacuum furnaces. The article discusses the types of nitriding and nitrocarburizing processes and the equipment required for heat treating tool steels to improve hardness, wear resistance, and thermal fatigue. The various nitriding and nitrocarburizing processes covered are salt bath nitrocarburizing, gas nitriding and nitrocarburizing, and plasma nitriding and nitrocarburizing.

Stainless steels are essential for the modern industrial civilization because of their corrosion resistance, especially in the chemical, petrochemical, and food industries. This article discusses the classification of the various types of stainless steels, including martensitic, ferritic, austenitic, duplex (ferritic-austenitic), and precipitation-hardening stainless steels. It presents a checklist of characteristics to be considered in selecting the proper type of stainless steel for a specific application. The article also outlines the need to promote the formation of an effective protective passive layer in stainless steels. It discusses hardness, fatigue and fretting properties, tribological properties, wear resistance, and corrosion-wear process of the S-phase layer. The article describes two thermochemical nitriding techniques of stainless steels: plasma-assisted nitriding techniques and non-plasma assisted nitriding processes. It also describes the difficulties in stainless steel nitriding/carburizing.

Nitriding is a general term for all processes based on the addition of nitrogen to the surface of steel. When carbon is added along with the nitrogen, the process is called nitrocarburizing. This article provides a detailed discussion on the functional and structural properties of nitrided layers. It describes the structural changes on the surface of carbon steels, alloy steels, and austenitic stainless steels. The article explains the effects of the various nitriding processes, namely, gaseous nitriding, plasma nitriding, gaseous nitrocarburizing, and salt bath nitrocarburizing, on the structure and properties of nitrided layers.

Plasma (ion) nitriding is a method of surface hardening using glow-discharge technology to introduce nascent (elemental) nitrogen to the surface of a metal part for subsequent diffusion into the material. This article describes the procedures and applications of plasma nitriding methods of steel. These methods include direct-current plasma nitriding, pulsed-current plasma nitriding, and active-screen plasma nitriding. The article reviews cold-walled and hot-walled furnaces used for plasma nitriding. It provides information on the importance of controlling three process parameters: atmosphere, pressure, and part temperature. The article includes a discussion on the influence of nitrogen concentration on case structure formation on nitrided steel, and explains the significance of microstructure, hardness, and fatigue strength on nitrided case. It also discusses processing, laboratory studies, and applications of nitrocarburizing of steel.

This article summarizes the terminology for gas reactions, and discusses low-temperature nitriding and nitrocarburizing of stainless steels. It describes the various nitriding processes, namely, high- and low-pressure nitriding, oxynitriding, sulfonitriding, oxysulfonitriding, ferritic nitrocarburizing and austenitic nitrocarburizing. The article includes a discussion on the difficulties in specimen cleaning, importance of furnace purge, uses of pre and post oxidation, depassivation, or activation, and requirements for perfect nucleation in nitriding process. In nitriding, the successful atmosphere control depends on various potentials. The article summarizes the methods of measuring potentials in nitriding and nitrocarburizing, provides useful information on the furnaces used, and the safety precautions to be followed in the nitriding process. It also describes the sample preparation procedures and testing methods to ensure the quality of the sample.

This article describes the uses of the liquid carburizing process carried out in low and high temperature cyanide-containing baths, and details the noncyanide liquid carburizing process which can be accomplished in a bath containing a special grade of carbon. It presents a simple formula for estimating total case depth, and illustrates the influence of carburizing temperature, duration of carburizing, quenching temperature, and quenching medium with the aid of typical hardness gradients. The article provides information on controlling of cyaniding time and temperature, bath composition, and case depth, and presents examples that relate dimensional change to several shapes that vary in complexity. It also provides information on the quenchant removal and salt removal processes, lists the applications of liquid carburizing in cyanide baths, and discusses the process and importance of cyanide waste disposal in detail.

Case hardening is defined as a process by which a ferrous material is hardened in such a manner that the surface layer, known as the case, becomes substantially harder than the remaining material, known as the core. This article discusses the equipment required, process variables, carbon and hardness gradients, and process procedures of different types of case hardening methods: carburizing (gas, pack, liquid, vacuum, and plasma), nitriding (gas, liquid, plasma), carbonitriding, cyaniding and ferritic nitrocarburizing. An accurate and repeatable method of measuring case depth is essential for quality control of the case hardening process and for evaluation of workpieces for conformance with specifications. The article also discusses various case depth measurement methods, including chemical, mechanical, visual, and nondestructive methods.

Sputtering is a nonthermal vaporization process in which atoms are ejected from the surface of a solid by momentum transfer from energetic particles of atomic or molecular size. Ionized gases in plasma nitriding chambers often possess enough energy to sputter atoms from workload, fixturing, and racking surfaces that are then redeposited to the benefit or detriment of the nitriding process. This article explains how and why sputtering occurs during plasma nitriding and how to recognize and control its effects. It reviews the factors that influence the intensity of sputtering and its effects, whether positive or negative, on treated parts. It also provides recommendations for improving outcomes when nitriding titanium alloys, ferrous metals, particularly stainless steels, and components with complex geometries.