This article provides information on the metallurgy of austenitic stainless steels, and the formation of their intermediate phases (Sigma, Chi, and Laves). It discusses sensitization, a major problem associated with the austenitics, and solutions to avoid the problem. The article describes heat treatments applied to austenitic stainless steels, namely, soaking for homogenization and preparation for hot working; annealing to remove the effects of cold work and to put alloying elements into solid solution; and stress relieving. It provides information on the stabilizing anneal process, which is conducted on stabilized alloys, and discusses the metallurgical characteristics of austenitic stainless steels that may affect the selection of a stress-relieving treatment and prevention of stress corrosion by stress relieving. The article also discusses the heat treatments applied to duplex stainless steels, which involve soaking and annealing, achieving the austenite-ferrite balance, precipitation of intermetallics, and alpha prime precipitation.

This article discusses the procedures used for pickling nickel and nickel alloys. Nickel alloys can be divided into four groups: high-nickel alloys, nickel-copper alloys, nickel-chromium alloys, and nickel-iron-chromium alloys. Alloys within each composition group that has similar surface conditions are pickled in the same solutions using the same procedures. The article discusses three different surface conditions for pickling these nickel alloys: bright annealed white surface requiring removal of tarnish by flash pickling; bright annealed oxidized surface requiring removal of a layer of reduced oxide, sometimes followed by a flash pickle to brighten; and black or dark-colored surface requiring removal of adherent oxide film or scale. The article also reviews specialized pickling operations of nickel alloys and various cleaning and finishing operations, including grinding, polishing, buffing, brushing, and blasting.