This article reviews generalized test methodologies for fatigue characterization of polymers and examines fatigue fracture mechanisms in different engineering plastics. It provides detailed micromechanistic images of crack-tip processes for a variety of semicrystalline and amorphous engineering polymers. The article describes fracture mechanics solutions and approaches to the fatigue characterization of engineering polymers when dealing with macroscale fatigue crack growth. It includes mechanistic images for high-density polyethylene, ultrahigh-molecular-weight polyethylene, nylon 6, 6, polycarbonate, and polypropylene. The article describes the micromechanisms of toughening of plastics and uses a macroscale approach of applying fracture mechanics to the fatigue life prediction of engineering polymers, building on the mechanistic concepts. It also describes the factors affecting fatigue performance of polymers.

In general, metal-matrix composites (MMCs) are classified into three broad categories: continuous fiber-reinforced composites, discontinuous or short fiber-reinforced composites, and particle-reinforced composites. This article focuses on stir casting and melt infiltration as the two main methods of MMC solidification processing. It describes the MCC casting methods, such as sand and permanent mold casting, centrifugal casting, compocasting, and high-pressure die casting. The article discusses the MMC infiltration processes in terms of pressure infiltration casting and liquid metal infiltration. It reviews the powder metallurgy processing of aluminum MMCs and deformation processing of discontinuously reinforced aluminum composites. The article concludes with a discussion on the processing of fiber-reinforced aluminum.

This article reviews the steps involved in presurface-preparation inspection: substrate replacement; removal of weld spatter, rounding of sharp edges, and grinding of slivers/laminations; and removal of rust scale, grease, oil, and chemical (soluble salt) contamination. It focuses on surface preparation methods that range from simple solvent cleaning to hand and power tool cleaning, dry and wet abrasive blast cleaning, centrifugal wheel blast cleaning, chemical stripping, and waterjetting for the application of the coating system. In addition, the article provides a description of the Society for Protective Coatings' (SSPC) standards and NACE International standards as well as the International Organization for Standardization (ISO) standards and International Concrete Repair Institute (ICRI) guidelines for surface cleanliness.

This article discusses the concepts of quality control (QC) and quality assurance (QA), and clarifies the differences and similarities in the roles and responsibilities of QC and QA personnel. It describes the inspection procedures used to verify proper surface preparation and installation of the protective coating/lining system. Prior to beginning surface-preparation operations, many specifications will require a presurface-preparation inspection to verify the correction of fabrication defects and removal of surface contamination such as grease, oil, cutting compounds, lubricants, and chemical contaminants. When inspecting concrete prior to coating installation, three areas of concern exist: surface roughness, moisture content in concrete, and acidity/alkalinity of the surface. The article provides information on the industry standards for assessing surface cleanliness. It details postcoating application quality requirements, including measuring of dry-film thickness, assessing intercoat cleanliness, verifying minimum and maximum recoat intervals, performing holiday/pinhole detection, conducting cure/hardness testing, and assessing adhesion of the applied coating system.

This article provides information on the infiltration mechanism of carbide structures. It reviews the basic techniques used for metal infiltration, including dip infiltration, contact filtration, gravity feed infiltration, and external-pressure infiltration. The article highlights various applications of contact infiltration in oil, gas, and blast-hole drilling such as fixed-cutter drill bits and diamond-impregnated coring bits. It also discusses the applications of infiltrated carbide material in erosion-resistant cladding.

Metal matrix composites (MMCs) can be synthesized by vapor phase, liquid phase, or solid phase processes. This article emphasizes the liquid phase processing where solid reinforcements are incorporated in the molten metal or alloy melt that is allowed to solidify to form a composite. It illustrates the three broad categories of MMCs depending on the aspect ratio of the reinforcing phase. The categories include continuous fiber-reinforced composites, discontinuous or short fiber-reinforced composites, and particle-reinforced composites. The article discusses the two main classes of solidification processing of composites, namely, stir casting and melt infiltration. It describes the effects of reinforcement present in the liquid alloy on solidification. The article examines the automotive, space, and electronic packaging applications of MMCs. It concludes with information on the development of select cast MMCs.

This article discusses the solidification of a matrix alloy in cast metal matrix composites (MMCs). It begins with a discussion on the mixing techniques in reinforcement incorporation and wettability of reinforcement. It describes the solidification processes, such as stir mixing and melt infiltration, used in the synthesis of MMCs. The article also considers the fundamentals of the process and presents a computational modeling of particle/solidification front interactions in metal-ceramic systems. The article concludes with information on nanocomposites.

Contour roll forming is a continuous process for forming metal from sheet, strip, or coiled stock into desired shapes of uniform cross section by feeding the stock through a series of roll stations equipped with contoured rolls. This article discusses the materials, roll-forming machines, tooling, and auxiliary equipment used in contour roll forming and its process variables. Tooling used in roll forming includes forming rolls and dies for punching and cutting off the material. The article discusses the additional tooling required in tube mills to weld, size, and straighten the tubes as they are produced on the machine. It describes the roll design for tube rolling and reviews the seam welding operations of pipe and tubing. The article discusses cross-sectional tolerances, the reshaping of round tubing, and factors that affect the quality, accuracy, and surface finish.

This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

This article describes the dispersed-phase toughening of thermoset matrices by the development of multiphase-structure thermosetting matrices using rubber and/or thermoplastic materials. It discusses two main methods for manufacturing prepregs, namely, single-pass impregnation and double-pass impregnation. The article illustrates reflected-light optical microscopy techniques to evaluate the morphology of thermoplastic materials for determining the material quality and correlating key microstructural features with material performance.

This article describes methods for analyzing impact-damaged composites in the aircraft industry. These include C-scan and x-radiography methods and optical microscopy. The article reviews brittle-matrix composite and tough-matrix composite failures. It explains the different types of composite failure mechanisms such as thermoplastic-matrix composite failure mechanisms, untoughened thermoset-matrix composite failure mechanisms, toughened thermoset-matrix composite failure mechanisms, dispersed-phase and rubber-toughened thermoset-matrix composite failure mechanisms, and particle interlayer-toughened composite failure mechanisms.

This article describes the general root causes of failure associated with wrought metals and metalworking. This includes a brief review of the discontinuities or imperfections that may be the common sources of failure-inducing defects in bulk working of wrought products. The article discusses the types of imperfections that can be traced to the original ingot product. These include chemical segregation; ingot pipe, porosity, and centerline shrinkage; high hydrogen content; nonmetallic inclusions; unmelted electrodes and shelf; and cracks, laminations, seams, pits, blisters, and scabs. The article provides a discussion on the imperfections found in steel forgings. The problems encountered in sheet metal forming are also discussed. The article concludes with information on the causes of failure in cold formed parts.

This article presents the importance of progressing from post-manufacturing inspection/verification to in-process inspection/verification methods. It lists the various quality assurance factors considered for typical composite laminate lay-up process. The article provides information on composite cure tooling that is fabricated from steel, aluminum, or high-temperature composite materials. The quality assurance for commercial applications is reviewed. The article concludes with a discussion on data fusion systems designed to provide nondestructive analysis data from fabrication and assembly processes for each individual composite part.

In-process inspection during composite material lay-up is essential if the structural, dimensional, and environmental performance designed into a part is to be consistently achieved. This article discusses the requirements to be met by the facilities and equipment to produce high-quality composites. It reviews the procedures that are allowed and prohibited in controlled-contamination areas of lay-up. The article emphasizes significant areas, such as material control and lay-up process, in which quality-control personnel can be effective in preventing production problems. It concludes with a discussion on automated tape laying and fiber placement, as well as the numerically aided lay-up process.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.

This article describes processes and equipment that are used to produce composite tubular parts. The processes include sheeting, pattern cutting, tube rolling, shrink tape debulking, and finishing. The article provides a discussion on materials that are most suitable for tube rolling: preimpregnated materials and unidirectional tapes. The article also discusses wrapping techniques of cylindrical and tapered tubes, such as convolute and spiral wrapping.

This article discusses three typical repair types for composite structures: temporary repairs, adhesively bonded repairs, and bolted repairs. It contains a table that lists general design requirements and considerations for the repair of composite structures. The article describes ten steps for an engineering repair approach to effectively restore structural integrity to damaged composite components. Management, validation and certification of repairs are also discussed. The article presents the design guidelines for analyzing the damage and possible strategies for making a repair. It reviews three repair schemes used in repair design analysis, namely, core replacement, adhesively bonded patch, and mechanically fastened patch. The article also emphasizes the various pitfalls and problems in repair design for composite structures.

Open molding is the method used in the polymer-matrix composites industry to make thermoset composite products. This article discusses the advantages, disadvantages, and applications of the open molding. It describes the various process of the open molding, such as hand lay-up process and spray-up process. Workmanship for hand lay-up and spray-up processes is reviewed. The article provides information on the matrix-resin materials used for open molding, including unsaturated polyester resins, epoxy vinyl ester resins, and reinforcements. It explains the component design and short- and long-term properties of a fiber reinforced composite laminate depending on material selection and workmanship. The article also presents the basic design guidelines for open molding.

This article discusses the attempts made by the industry to create sensing approaches for modeling a process, part, and chemistry and kinetics. It reviews microwave curing of thick-section composites and the resin cure sensors that are used for resin cure monitoring. These include dielectric cure sensors, fiberoptics-based resin cure sensors, ultrasonics-based resin cure sensors, and dosimetry-based resin cure sensors. The article provides information on the resin cure control flow sensing, flow modeling, flow mapping, and resin flow. It addresses some practical issues in sensing resin cure and flow.

This article describes the chemistry of phenolic resins and reviews their characteristics and properties for various composites fabrication processes. The fabrication processes include solution/hot-melt process, pultrusion, vacuum infusion, filament winding, sheet molding, and hand lay-up. The article illustrates the manufacturing process of phenolic honeycomb and provides information on the applications of phenolic composites.