The metallographic specimen preparation process for microstructural investigations of cast iron specimens usually consists of five stages: sampling, cold or hot mounting, grinding, polishing, and etching with a suitable etchant to reveal the microstructure. This article describes the general preparation of metallographic specimens and the methods of macroscopic and microscopic examination. Usually, gray-scale (black-and-white) metallography is sufficient for microstructural analysis of cast irons. The article discusses the use of color metallography of gray irons and ductile irons. It also presents application examples of color metallography.

Retrogression and reaging (RRA) is an established form of postquench aging heat treatment. RRA treatments can be applied to precipitation-hardened aluminum alloys that are used in aerospace applications. This article provides information on the development background of RRA and the steps involved in the RRA treatments. It discusses the process descriptions, applications, microstructural consequences, and limitations of RRA. In addition, the article describes the influence of RRA on mechanical properties.

This article describes the integration of thermodynamic modeling, mobility database, and phase-transformation crystallography into phase-field modeling and its combination with transformation texture modeling to predict phase equilibrium, phase transformation, microstructure evolution, and transformation texture development during heat treatment of multicomponent alpha/beta and beta titanium alloys. It includes quantitative description of Burgers orientation relationship and path, discussion of lattice correspondence between the alpha and beta phases, and determination of the total number of Burgers correspondence variants and orientation variants. The article also includes calculation of the transformation strain with contributions from defect structures developed at alpha/beta interfaces as a precipitates grow in size. In the CALculation of PHAse Diagram (CALPHAD) framework, the Gibbs free energies and atomic mobilities are established as functions of temperature, pressure, and composition and serve directly as key inputs of any microstructure modeling. The article presents examples of the integrated computation tool set in simulating microstructural evolution.

This article discusses the capabilities and limitations of various material characterization methods that assist in the selection of a proper analytical tool for analyzing particulate materials. Commonly used methods are microanalysis, surface analysis, and bulk analysis. The techniques used for performing microanalysis include scanning electron microscopy and electron probe X-ray microanalysis. The article describes surface analysis techniques, including Auger electron spectroscopy, X-ray photoelectron spectroscopy, and ion-scattering spectroscopy. Bulk analysis techniques, such as X-ray powder diffraction, inductively coupled plasma atomic emission spectroscopy, atomic absorption spectroscopy, and atomic fluorescence spectrometry, are also discussed.

Quality control of cemented carbides includes the evaluation of physical and chemical properties of constituent raw material powders, powder blends/formulations, green compacts, and fully dense finished product. This article provides a summary of the underlying principles and size ranges for the American Society for Testing and Materials (ASTM) standard methods of particle sizing and distribution. It presents the methods used to analyze the chemical composition of cemented carbide materials in a tabular form. The article also presents information on microstructural evaluation and physical and mechanical property evaluation of cemented carbides.

This article describes the mechanisms and characteristics of heat transfer in the quenching of steel. This article describes the characterization of boiling heat transfer, including pool boiling, forced convective boiling, and rewetting, which plays a key role in defining the heat-extraction characteristics of a liquid quenchant. It provides information on heat generated microstructural field evolution and information on the analysis and characterization of heat transfer boundary conditions.

This article reviews the fundamental solidification concepts for understanding microstructural evolution in fusion welds. The common concepts, namely, nucleation, competitive grain growth, constitutional supercooling, solute redistribution, and rapid solidification, depend on the solidification parameters during welding, are discussed. The article discusses important solidification parameters, including temperature gradient, solid/liquid interface growth rate, and cooling rate.

This article is a comprehensive collection of formulas and numerical solutions, addressing many heat-transfer scenarios encountered in welds. It provides detailed explanations and dimensioned drawings in order to discuss the geometry of weld models, transfer of energy and heat in welds, microstructure evaluation, thermal stress analysis, and fluid flow in the weld pool.

This article lists the system parameters of the friction welding process and describes the four categories of monitoring and control of the manufacturing process. It discusses the monitoring methods of a rotary friction welded sample, for determining in-process quality of ferrous alloys, and dissimilar metals using acoustic emission. The article reviews the feasibility of detecting the presence of ferrite during microstructural evolution of friction welding of three austenitic stainless steels: 310, 304, and 255. It also explains the in-process quality control of friction welding.

This article discusses a set of experimental and computational studies aimed at understanding the effect of various processing parameters on the extent of burr and other defect formation during sheet edge-shearing and slitting processes. It describes the development of experimentally validated finite-element models for analyzing the classes of shearing processes. The article also discusses the use of microstructural characterization with stereology to render three-dimensional volumetric parameters. It concludes with information on the numerical simulation of an edge-shearing process, along with sensitivity studies with respect to process and tool parameters.

This article summarizes the general features of microstructure evolution during the thermomechanical processing (TMP) of nickel-base superalloys and the challenges posed by the modeling of such phenomena. It describes the fundamentals and implementations of various modeling methodologies. These include JMAK (Avrami) models, topological models, and mesoscale physics-based models.

This article reviews the general aspects of microstructure evolution during thermomechanical processing. The effect of thermomechanical processing on microstructure evolution is summarized to provide insight into the aspect of process design. The article provides information on hot working and key processes that control microstructure evolution: dynamic recovery, static recovery, recrystallization, and grain growth. Some of the key phenomenological descriptions of plastic flow and microstructure evolution are also summarized. The article concludes with a discussion on the modeling of microstructure evolution.

This article describes the microstructure of copper alloys, including copper-zinc (brasses), bronzes, copper-nickel, and copper-nickel-zinc, and examines the effect of oxygen content on alloy phases observed in different product forms. The article also discusses inclusions, etchants, and the effect of composition and processing on grain structure and growth rates.

This article discusses the principles of physical metallurgy and metallography of depleted uranium. It describes the techniques involved in the preparation of thin foils for transmission electron microscopy and illustrates the resulting microstructure of uranium and uranium alloys, with the aid of black and white images. The article also provides information on the applications of etching and examination of uranium alloys, at both macro and micro scales, in characterizing the grain structures, segregation patterns, inclusions, and the metal flow geometries produced by solidification and mechanical working processes.

This article describes the metallographic specimen preparation procedures for cast iron test samples, including mounting, grinding, polishing, and etching. It discusses the makeup and use of black-and-white and selective color etchants and where one might be preferred over the other. The article provides information on nearly 100 micrographs, discussing the microstructure of flake graphite in gray iron, nodular graphite in ductile iron, and temper graphite in malleable iron. It also examines the matrix microstructures of gray, ductile, compacted, and malleable cast iron samples.

This article reviews how process variations influence the characteristics of thermal spray coatings. It describes various specimen preparation techniques, which allow accurate microstructural analysis. These techniques include sectioning, cleaning, mounting, planar grinding, fine grinding, rough polishing, and etching. The article provides information on the problems associated with specimen preparation. It concludes with a discussion on the various methods of analysis for thermal spray coatings.

This article provides an overview of the origin of metallography. It presents information on how to select a section from a specimen and prepare it for macroscopic analysis. The article describes the macroscopic analysis of steel fracture surfaces with emphasis on ductile, brittle, and fatigue fracture with illustrations. It discusses microanalysis with a focus on the method of light microscopy and includes information of scanning electron microscope in fractography. The article also explains the characteristics of solidification, transformation, deformation structures, and discontinuities that are present in a microstructure. It concludes with information on image analysis.

This article discusses the specimen preparation techniques for zinc and its alloys and zinc-coated specimens, namely, sectioning, mounting, grinding and polishing, and etching. It describes the characteristics of lead, cadmium, iron, copper, titanium, aluminum, magnesium, and tin, which are present in the microstructure of zinc alloys. The article also provides information on microexamination that helps to determine the dendrite arm spacing, as well as the grain size, grain boundaries, and grain counts.

Microstructural analysis reveals many important details about the qualities and capabilities of high-performance ceramics. This article explains how to prepare ceramic samples for imaging and the imaging technologies normally used. It describes sectioning, mounting, grinding, and polishing as well as ceramographic etching. It discusses common imaging approaches, including scanning electron microscopy and thin-section polarized light techniques, a type of optical microscopy. The article also addresses microstructural classification, examining detailed micrographs from samples of aluminum oxide, zirconium dioxide, aluminum nitride, silicon carbide, and piezoelectric ceramics.

Archaeometallurgists use metallography to reveal and interpret the microstructures of objects, in conjunction with the results of their chemical analyses and microanalyses. This article describes a number of special problems that occur while performing metallographic analyses on archaeological materials. It also presents case studies, with examples that illustrate situations where metallography has contributed to archaeometallurgical studies.