This article presents the mechanisms of polymer wear and quantifies wear in terms of wear rate (rate of removal of the material). Interfacial and bulk wear are discussed as well as a discussion on the wear study of "elastomers," "thermosets," "glassy thermoplastics," and "semicrystalline thermoplastics." The article also discusses the effects of environment and lubricant on the wear failures of polymers. It presents a case study on considering nylon as a tribological material and failure examples, explaining wear resistance of polyurethane elastomeric coatings and failure of an acetal gear wheel.

Polymers and polymer composites have become attractive for tribological applications due to their specific material properties. This article begins by discussing the fundamentals of polymer friction and wear. It summarizes the main polymer materials used in tribological applications. The article explains the effects of load, sliding velocity, and temperature on the friction coefficient. It describes three types of wear modes, namely, abrasive, adhesion, and fatigue. The article discusses the frictional behavior of polymer composites and polymer coatings. It concludes by providing information on tribotesting of polymers and polymer composites.

This article focuses on technologies in the protective coatings field, namely, polysiloxane hybrids and related materials. Industrial maintenance topcoats, including silicone alkyds, silicone epoxies, and polysiloxanes are reviewed. The article discusses two major application areas of protective coatings, namely, architectural coatings and automotive clear coats.

Acrylic coatings are one of the major generic classes of organic coatings and are prevalent in both architectural and industrial applications. This article provides information on the chemistry of acrylic polymers, the methods used in their manufacture, the relationship between structure and properties when they are formulated into coatings, and how they are being used in coatings. The main discussion points are the differences between solventborne and waterborne technologies and some of the challenges in formulating and applying waterborne acrylic coatings. The article describes the mechanism of film formation of acrylic latex polymers and its effect on final coating properties. It discusses the types of waterborne acrylic latex coatings based on chemical properties and based on applications such as primers, intermediate coats, topcoats, stains, and direct-to-substrate finishes. The article concludes with a description of the advances in the development of waterborne acrylic coatings for maintenance and protective applications.

Polyaspartic coating technology has found utility in a variety of coating applications, including corrosion protection and flooring topcoats, as these coatings are based on aliphatic polyisocyanates and aliphatic diamines. This article describes the chemistry of polyaspartic esters and curing characteristics and performance properties of polyaspartic coatings. It also provides information on curing corrosion protection coating systems, polyaspartic floor coatings, and safe-use recommendations for handling isocyanates.

Phenols are a class of aromatic organic compounds in which one or more hydroxyl groups are attached directly to the aromatic benzene ring, C6H6. This article describes the development of phenolic resin and the formation of novolac resin and resol resin. Phenolic resol resins are used in interior can coatings and tank linings as well as for heat exchanger tube coatings because of their high chemical and thermal resistance. The article concludes with a description of the concerns that a specifier, user, or applicator should be aware of regarding the use of phenolic coatings.

Polyurethane is any polymer consisting of a chain of repeating organic units joined by urethane linkages. Polyurethane polymers are formed through step-growth polymerization by making a monomer containing at least two isocyanate functional groups to react with another monomer containing at least two hydroxyl (alcohol) groups. This article provides a detailed account of the protective coatings used in the building, infrastructure, and architectural markets. It focuses on the various types of polyurethane coatings used in these applications: moisture-cure and two-pack aromatic coatings as primers and topcoats, moisture-cure aromatic elastomeric high-build coatings, moisture-cure aliphatic topcoats, two-pack aliphatic polyurethane coatings as topcoats, and one- and two-pack polyurethane dispersion coatings as sealers and topcoats. It also includes a section on the health effects of isocyanates.

Polyvinylidene fluoride (PVDF)-based coatings are typically used in outdoor applications that require exceptionally high performance and excellent long-term exterior durability with little maintenance. This article provides a background of three fluoropolymers most commonly used for coatings, namely, PVDF, polyvinyl fluoride, and polytetrafluoroethylene. It focuses on general properties, polymerization, resin types, coating formulation, technology of organic coatings, coating properties, and health and related safety considerations of PVDF. The article describes the application and typical end uses of PVDF-based coatings and the opportunities for improvement in PVDF-based coatings as with all organic coatings.

Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals for corrosion and decorative areas, and some plastics. This article discusses the formulation basics of polyurea technology and compares the technology to that of polyurethane and polyurethane/polyurea systems. It addresses performance issues and describes application processing considerations and safety practices of polyurea coating/lining systems.

Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.

An alkyd is an ester-based polymer derived from the polycondensation reaction of polyhydric alcohol and polybasic acid. This article provides useful information on the chemistry, production, coating formulations, modification, commercial products, and application methods of alkyd resins. It also provides a section on drying oil, which is used in the manufacture of resins. The article describes the three categories of metals that have been used in drier compounds: primary driers (active or oxidation driers), secondary driers (through-driers), and auxiliary driers. It also provides information on the oil length of an alkyd resin and on solvents, which play a critical role in the formulation and use of the coating. The article concludes with a description of the concerns that a user, specifier, or applicator should be aware of when using alkyd coatings.

This article describes the coating materials, surface-preparation requirements, and application techniques used to protect underground pipelines. It provides a valuable insight into the types of polymer-based coatings that are both cost-effective and widely accepted in the pipeline industry.

Organic coatings are the principal means of corrosion control for the hulls and topsides of ships and for the splash zones on permanent offshore structures. This article describes surface preparation which is the most important consideration in determining the performance of organic coating systems. It contains a table that lists the uses and applicable standards for various surface preparation techniques. The article provides information on organic coatings in topside coating systems and reviews the importance of primers in the protection of steel substrates. It also explains the property requirements and the common types of immersion coatings.

Bridges and highways are core components of transportation system and range from pavements with earth, gravel, or stone covered by a thin bituminous surface course to a continually reinforced Portland cement concrete (PCC) roadway with or without a bituminous wear course. This article provides information on bridges and dowels and the reinforcement used in PCC roadways that suffer from corrosion. An overview is provided on the rise in awareness of the corrosion issues affecting bridges and highways. The chemistry and structure of concrete and its role as an electrolyte in promoting corrosion are also discussed. The article addresses reinforcement, including conventional, prestressed, cable stays, and corrosion-resistant reinforcement. It deals with the electrochemical methods for the inspection and corrosion control of embedded reinforcement. The article also reviews the corrosion of metal bridges and corrosion control, including the use of weathering steels and coating systems.

This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.

This article presents a detailed discussion on the relative performance properties of principal rubber types used in lining applications together with their application, vulcanization and inspection techniques, and material and installation costs.

This article outlines the processes by which materials are selected to prevent or control localized corrosion, galvanic corrosion, and intergranular corrosion. It reviews the operating conditions and the design of candidate materials for material selection. The article discusses various corrosion-resistant materials, including ferrous and nonferrous metals and alloys, thermoplastics, reinforced thermosetting plastics, nonmetallic linings, glass, carbon and graphite, and catalyzed resin coatings. It examines an unusual form of intergranular corrosion known as exfoliation, which occurs in aluminum-copper alloys. The article also describes three types of erosion-corrosion: liquid erosion-corrosion, cavitation, and fretting. It concludes with information on the various factors to be considered for material selection, including minimum cost or economic design, minimum corrosion, minimum investment, and minimum maintenance.

This article provides an overview of thermal spray processes. It describes the microstructural character of thermal spray coatings as well as the criteria for coating selection. The optimization, parameterization, and surface preparation and treatments for the thermal spray coatings are also discussed. The article illustrates the adhesion of polymer coatings and the thermal spray process used to remove lead-base paint. It provides information on the specifications, standardization, and guidelines for thermal spray applicators.

This article describes elastomeric coatings that are suitable for painting flexible plastic substrates. It focuses on coatings systems that find utility in automotive exterior applications, where the requirements of appearance and durability are most severe. The article discusses acrylic polyols, condensation polymers, vapor curing systems, water-based coatings, and coatings for thermoplastic olefins.