The characterization, testing, and nondestructive evaluation of ceramics and glasses are vital to manufacturing control, property improvement, failure prevention, and quality assurance. This article provides a broad overview of characterization methods and their relationship to property control, both in the production and use of ceramics and glasses. Important aspects covered include the means for characterizing ceramics and glasses, the corresponding rationale behind them, and relationship of chemistry, phases, and microconstituents to engineering properties. The article also describes the effects that the structure of raw ceramic materials and green products and processing parameters have on the ultimate structure and properties of the processed piece. The effects that trace chemistry and processing parameters have on glass properties are discussed. The article describes mechanical tests and failure analysis techniques used for ceramics.

This article discusses the fundamentals and operating principles of the following acoustic microscopy methods: scanning laser acoustic microscopy, C-mode scanning acoustic microscopy, and scanning acoustic microscopy. It describes the applications of acoustic microscopy for detecting defects in metals, ceramics, glasses, polymers, and composites with examples.

This article provides a brief discussion on the common types of overlayers that can be used on a metal surface to protect it from corrosion. These overlayers include phosphate, chromate, and chromate-free conversion coatings; hot dip galvanizing; cementitious linings; glass and porcelain enamels; electroplating; thermal spray coatings; and rubber linings.

This article provides an overview of the models of two induction heating devices, namely, induction crucible furnace (ICF) and induction furnace with slits, or segmented and water-cooled induction furnace with cold crucible (IFCC). These devices are used for melting with skull formation of low-conductivity materials such as glasses and oxides. The article presents the governing equations and boundary conditions for ICF and IFCC modeling. It includes a discussion on three electromagnetic field models in IFCC, namely, two-dimensional (2-D), quasi-three-dimensional, and three-dimensional (3-D) models. The article provides information on the simulation of skull formation in IFCC, and elucidates the transient axisymmetrical 2-D model and the transient 3-D model, including the primary results achieved for both glasses and skull formation.

The historical use of induction heating relating to glass melting gives some insight into its use in today's glass manufacturing industry. A patent search on induction heating provides historical information about how induction heating was used in the glass melting industry, from both a direct fired or a susceptor/container approach. This article provides review of historical patents, following an introduction to conductivity in glass and electrical heating. The purpose is to show that induction heating has been and is being used in the glass melting industry.

The optical fiber preform is a long cylinder of glass that contains core and cladding glasses. This article describes the relationship between the peak furnace temperature, fiber draw tension, and fiber draw speed. It focuses on temperature requirements such as product viscosity, hot zone length, temperature profile, and heating cycle to draw the glass. The article provides information on process gases in the draw induction furnace, insulation package for induction heating operations, and furnace design and scalability. It reviews the key factors for the selection of susceptor materials, namely, cost, temperature cycling, and the impact on the product.

This article focuses on ceramics, glasses, glass-ceramics, and their derivatives, that is, inorganic-organic hybrids, in the forms of solid or porous bodies, oxide layers/coatings, and particles with sizes ranging from nanometers to micrometers, or even millimetres. These include inert crystalline ceramics, porous ceramics, calcium phosphate ceramics, and bioactive glasses. The article discusses the compositions of ceramics and carbon-base implant materials, and examines their differences in processing and structure. It describes the chemical and microstructural basis for their differences in physical properties, and relates the properties and hard-tissue response to particular clinical applications. The article also provides information on the glass or glass-ceramic particles used in cancer treatments.

The biocompatibility of a material relates to its immunological response, toxicity profile, and ability to integrate with surrounding tissue without undesirable local or systemic effects on a patient. This article underscores the transformation of the medical device design ecosystem engaged as an integral part of the device ecosystem. It discusses the applications of biomaterials, including orthopedic, cardiovascular, ophthalmic, and dental applications. The article describes four major categories of biomaterials such as metals, polymers, glass and ceramics, and composites. A discussion on natural materials, nanomaterials, and stem cells is also provided. The article concludes with examples of biomaterials applications, such as endovascular devices, knee implants, and neurostimulation.

This article provides an overview of the corrosion theory relating to refractories on the basis of acid/base reactions, thermodynamics, and kinetic considerations. The tests to evaluate refractory corrosive wear are reviewed. The article describes the specific refractories used in steel, glass, aluminum, and chemical-resistant applications. Specific material issues that should be considered or evaluated when choosing or using refractory materials are discussed.

This article outlines the processes by which materials are selected to prevent or control localized corrosion, galvanic corrosion, and intergranular corrosion. It reviews the operating conditions and the design of candidate materials for material selection. The article discusses various corrosion-resistant materials, including ferrous and nonferrous metals and alloys, thermoplastics, reinforced thermosetting plastics, nonmetallic linings, glass, carbon and graphite, and catalyzed resin coatings. It examines an unusual form of intergranular corrosion known as exfoliation, which occurs in aluminum-copper alloys. The article also describes three types of erosion-corrosion: liquid erosion-corrosion, cavitation, and fretting. It concludes with information on the various factors to be considered for material selection, including minimum cost or economic design, minimum corrosion, minimum investment, and minimum maintenance.

Fractography is the means and methods for characterizing a fractured specimen or component. This includes the examination of fracture-exposed surfaces and the interpretation of the fracture markings as well as the examination and interpretation of crack patterns. This article describes the former of these two parts of fractography. It presents the techniques of fractography and explains fracture markings using glass and ceramic examples. The article also discusses the fracture modes in ceramics and provides examples of fracture origins.

This article describes the fatigue mechanism and behavior of environmentally induced fatigue and cyclic fatigue. It discusses three basic strength test methods, namely, static, dynamic, and cyclic, along with their analytical relations for determining the fatigue parameters and behavior of ceramics and glasses. The article explains the double torsion and double-cantilever beam fracture mechanics methods, which employ test specimens with relatively large, induced cracks. Crack growth data are typically determined directly by the observation of the crack or by devices that monitor test specimen compliance, such as clip gages and strain gages.

This article reviews the fundamental relationships between microstructure and mechanical properties for major classes of nonmetallic engineering materials: metals, ceramics and glasses, intermetallic compounds, polymers, and composites. It details the structures of inorganic crystalline solids, inorganic noncrystalline solids, and polymers. The article describes the various strengthening mechanisms of crystalline solids, namely, work hardening, solid-solution hardening, particle/precipitation hardening, and grain size hardening. Deformation and strengthening of composite materials, polymers, and glasses are reviewed. The article concludes with information on the two important aspects of the mechanical behavior of any class of engineering material: fatigue response and fracture resistance.

A newly developed theory on plasticity makes it possible to include elastic effects, which play a major role when using blunt hardness indenters. This article reviews the new theory and explains several phenomena associated with practical hardness testing. In the indentation hardness test, a blunt indenter that approximates a flat punch is forced into a plane surface. The effective cone angle for most indenters is such that some upward flow results even when there is sufficient material surrounding the indenter to provide a full elastic constraint. When loaded by a blunt indenter, materials with high values of Young's Modulus of Elasticity/uniaxial flow stress (E/Y) (metals) appear to develop a Hertzian stress distribution over the contact. In contrast, materials with low values of E/Y (glasses and polymers) develop a uniform distribution of stress.

This article explores the possibilities and limitations imposed by manufacturing processes and materials. Detailed design rules for the processes are presented. The article lists the main features of process groups in a tabular form. The physical characteristics and ratings of relative cost and production factors are also tabulated. The process groups include casting; deformation; powder processing; machining; noncutting; joining; ceramic, glass, and polymer processing; and composites manufacturing.

This article provides a discussion on various types of glasses: traditional glasses, specialty glasses, and glass ceramics. It provides information on glazes and enamels and reviews the broad classes of ceramic materials. These include whitewares, structural clay products, technical ceramics, refractories, structural ceramics, engineering ceramics, and electronic and magnetic ceramics. General processing variables that can affect structure and compositional homogeneity are discussed. Traditional ceramics that include both oxide and nonoxide ceramics are also reviewed. The article concludes with several examples of engineering ceramics.

This article discusses the fracture behavior of silicate glasses, more specifically, soda-lime-silicate glass, borosilicate glass and vitreous silica. It analyzes the testing and calculation of dynamic fatigue and slow-crack-growth for lifetime prediction of glasses. The article illustrates the phenomenon of static fatigue and concludes with a discussion on the role of surface damage in strength and fatigue behavior.

This article provides an overview of the types, properties, and applications of traditional and advanced ceramics and glasses. Principal product areas for traditional ceramics include whitewares, glazes, porcelain enamels, structural clay products, cements, and refractories. Advanced ceramics include electronic ceramics, optical ceramics, magnetic ceramics, and structural ceramics.

This article is a comprehensive collection of engineering property data in tabulated form for ceramics and glasses. Data are provided for physical and mechanical properties of ceramic materials and color of ceramics fired under oxidizing and reducing conditions. The article also lists the materials characterization techniques for ceramics and glasses.