Aggregate molding, or sand casting, is the gravity pouring of liquid metal into a mold that is made of a mixture molded against a permanent pattern. This article summarizes the most important materials in the process of sand casting of cast iron, including different types of molding aggregates, clays, water, and additives in green sand, chemically bonded organic resins, and inorganic binders in self-setting, thermosetting, and gas-triggered systems. It discusses three main types of reclamation systems: wet, dry, and thermal. The article concludes with a description of both nonpermanent and permanent mold processes.

This article provides a brief discussion on the common types of overlayers that can be used on a metal surface to protect it from corrosion. These overlayers include phosphate, chromate, and chromate-free conversion coatings; hot dip galvanizing; cementitious linings; glass and porcelain enamels; electroplating; thermal spray coatings; and rubber linings.

This article discusses the composition of the major components of dental composite resins: organic resin matrix, filler, coupling agents, and initiator-accelerator systems. It describes the properties of composite resins that are related to the amount and type of filler and resin-matrix compositions. The article also discusses the compositions, properties, and clinical applications of polyacid-modified composite resins and resin-modified glass-ionomer cements. It concludes with information on biodegradation and biocompatibility of resin-based restorative materials.

This article describes the process and advantages of no-bond methods of vacuum molding and magnetic molding, with schematic illustrations. It also discusses the characteristics of plastic film and dimensional specifications of vacuum molding.

No-bake sand molds are based on the curing of inorganic or organic binders with either gaseous catalysts or liquid catalysts. This article reviews the major aspects of no-bake sand bonding in terms of coremaking, molding methods, and sand processing. It discusses the points to be noted in handling sand-resin mixtures for no-bake molds or cones and lists some advantages of no-bake air-set cores and molds. The article describes the process procedures, advantages, and disadvantages of gas curing and air-setting hardening of sodium silicates. It examines the members of the air-setting organic binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation.

Casting can be done with either expendable molds for one-time use or permanent molds for reuse many times. This article lists the various methods used to fabricate expendable molds from permanent patterns. The methods include molding of sand with clay, inorganic binders, or organic resins; shell molding of sand with a thin resin-bonded shell; no-bond vacuum molding of sand; plaster-mold casting; ceramic-mold casting; rammed graphite molding; and magnetic (no-bond) molding of ferrous shot. The article tabulates a general comparison of casting methods and discusses the basic requirements of foundry molds.

This article focuses on the three basic groups of flexible-die forming methods: rubber pad, fluid cell, and fluid forming. It provides information on the Guerin process, the Verson-Wheelon process, the trapped-rubber process, the Marform process, the Hydroform process, the SAAB process, and the Demarest process. The article provides a discussion on the procedures of these processes, as well as the presses and tools used. It describes the methods of hydraulic forming of thin metal parts, namely, hydraulic forming with diaphragm, hydraulic forming with gasket and pressure control, and hydrobuckling.

This article provides an overview of the environmental performance of the most commonly used nonmetallic materials, including elastomers, plastics, thermosetting resins, resin-matrix composites, organic coatings, concrete, refractories, and ceramics. It also discusses the applications and uses of these materials.

Natural and synthetic rubber linings are used extensively in many industries for their corrosion and/or abrasion resistance. These industries include transportation, chemical processing, water treatment, power, mineral processing, and mining. This article provides information on soft natural rubber, semihard natural rubber, hard natural rubber, neoprene or polychloroprene, chlorobutyl, three-ply linings, nitrile, and ethylene propylene with a diene monomer. Emphasis is placed on advantages, disadvantages, and common uses of each material discussed.

This article describes how composite specimens are sectioned, documented, and labeled during sample preparation. The mounting procedures for the specimen are summarized. The article explains sample clamping, which involves not mounting the specimens using an adhesive or casting resin and corresponds to clamped samples used in automated polishing heads. It details that cavity molds involve mounting the composite specimens using a casting resin in a preset mold. The article also discusses the mounting of composite materials for hand polishing.

This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.

Anodizing is one of the most common surface treatments of aluminum and is performed for corrosion protection. This article describes the structure and growth characteristics of the types of anodic oxide films such as a barrier-type oxide film and a porous-type anodic oxide film. It discusses each step involved in the anodizing process of an aluminum or aluminum alloy specimen. The anodizing process includes pretreatments (degreasing, etching, and polishing), anodizing, coloring, and sealing. The article provides an observation of the morphology of the anodic oxide films by transmission electron microscopy and the scanning electron microscopy for testing properties of anodic oxide films.

The article commences with an overview of short-term and long-term mechanical properties of polymeric materials. It discusses plasticization, solvation, and swelling in rubber products. The article further describes environmental stress cracking and degradation of polymers. It illustrates how surface degradation of a plain strain tension specimen alters the ductile brittle transition in polyethylene creep rupture. The article concludes with information on the effects of temperature on polymer performance.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.

This article discusses the properties and applications of two types of polyimide resins: condensation polyimides and addition-type polyimides. It describes the chemistry of condensation-type polyimides during synthesis, processing of polyamide acid precursor solution to polyimide, and preparation of polyimide films from thermoplastic polyamic acid precursors. The article reviews the chemistry of several addition-type polyimides, including phenylethynyl-containing imide oligomers, nadic end-capped polyimides, and LARC RP46. It explains the preparation processes of nadic end-capped amic acid oligomer resin solutions, including the preparation of resin powder and resin disks, adhesive film, adhesive bond specimens, and films.

This article provides an overview of the various types of unsaturated polyester resins and low-profile additives. The resins include general-purpose resins, isophthalic resins, bisphenol A fumarate resins, chlorendic resins, and vinyl ester resin. The article describes the mechanical and electrical properties, thermal and oxidative stability, and chemical and ultraviolet (UV) resistance of polyester resins. It concludes with a discussion on the flame-retardant polyester resins.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

This article discusses postconsumer plastics recyclate quantities, the classification of plastics recycling into primary, secondary, tertiary, and quaternary categories, and how the life cycle of plastics is affected by recycling. The recycling processes of polyethylene terephthalate (PET), which accounts for the largest percentage of plastic recycling, high-density polyethylene (HDPE) plastics, the other large-volume plastic recyclate, as well as vinyl resins and polycarbonate resins are described. The life cycle of plastics has four phases: poly formation, part fabrication, product service, and disposal. Landfilling is still the primary method of final disposal, and incineration is another option, but recycling has become a viable alternative. The article presents a comparison between secondary and tertiary recycling.

This article discusses the family characteristics, commercial forms, applications, resin grades, and mechanical and physical properties of traditional engineering thermoplastics in their neat (unmodified) form and as compounds and composites, namely, acrylonitrile-butadiene-styrenes, acrylics, high-density polyethylenes, reinforced polypropylenes, high-impact polystyrenes, polyvinyl chloride, styrene-acrylonitriles, and styrene-maleic anhydrides.