This article describes the viscoelastic behavior of plastics in their solid state only, from the standpoint of the material deforming without fracturing. The consequences of viscoelasticity on the mechanical properties of plastics are described, especially in terms of time-dependencies, as well as the dependence of the viscoelastic character of a plastic on chemical, physical, and compositional variables. By examining the viscoelastic behavior of plastics, the information obtained are then applied in situations in which it may be important to anticipate the long-term properties of a material. This includes assessing the extent of stress decay in materials that are pre-stressed, the noise and vibration transmission characteristics of a material, the amount of heat build-up in a material subjected to cyclic deformation, and the extent a material can recover from any prior deformation. Several qualitative graphs are presented, which highlights the possible differences in the viscoelastic behavior that can exist among plastics.

This article provides some new developments in elevated-temperature and life assessments. It is aimed at providing an overview of the damage mechanisms of concern, with a focus on creep, and the methodologies for design and in-service assessment of components operating at elevated temperatures. The article describes the stages of the creep curve, discusses processes involved in the extrapolation of creep data, and summarizes notable creep constitutive models and continuum damage mechanics models. It demonstrates the effects of stress relaxation and redistribution on the remaining life and discusses the Monkman-Grant relationship and multiaxiality. The article further provides information on high-temperature metallurgical changes and high-temperature hydrogen attack and the steps involved in the remaining-life prediction of high-temperature components. It presents case studies on heater tube creep testing and remaining-life assessment, and pressure vessel time-dependent stress analysis showing the effect of stress relaxation at hot spots.

Independent verification of coating system performance can be based on laboratory testing and/or field exposure. Qualification testing is a critical component to coating system selection. This article focuses on performance evaluations that are used to prequalify coating systems, namely, facility-specific, industry-specific, coating-type-specific, or a combination of these. It describes the standard laboratory tests used to generate performance data, namely, physical, compositional, chemical exposure, and application characteristics tests. The pros and cons of using manufacturer-generated data versus independently generated data are discussed. The article provides information on accelerated corrosion/weathering testing and nuclear level 1/level 2 service coatings qualification. It also describes the procedures for establishing minimum performance requirements and for determining when requalification testing may be required.

This article reviews the applied aspects of creep and stress-rupture failures. It discusses the microstructural changes and bulk mechanical behavior of classical and nonclassical creep behavior. The article provides a description of microstructural changes and damage from creep deformation, including stress-rupture fractures. It also describes metallurgical instabilities, such as aging and carbide reactions, and evaluates the complex effects of creep-fatigue interaction. The article concludes with a discussion on thermal fatigue and creep fatigue failures.

This article focuses on the life assessment methods for elevated-temperature failure mechanisms and metallurgical instabilities that reduce life or cause loss of function or operating time of high-temperature components, namely, gas turbine blade, and power plant piping and tubing. The article discusses metallurgical instabilities of steel-based alloys and nickel-base superalloys. It provides information on several life assessment methods, namely, the life fraction rule, parameter-based assessments, the thermal-mechanical fatigue, coating evaluations, hardness testing, microstructural evaluations, the creep cavitation damage assessment, the oxide-scale-based life prediction, and high-temperature crack growth methods.

This article provides the theoretical background for understanding many of the physical processes relevant to mechanical testing methods, experimental results, and analytical approaches described in this volume.

Creep deformation is normally studied by applying either a constant load or a constant true stress to a material at a sufficiently high homologous temperature so that a measurable amount of creep strain occurs in a reasonable time. This article provides the phenomenological descriptions of creep and explains the testing and mechanism of creep in crystalline solids. It also presents information on the creep response of crystalline and amorphous solids.

This article reviews the basic equipment and methods for creep and creep rupture testing. It begins with a discussion on the creep properties, including stress and temperature dependence, as well as of the extrapolation techniques that permit estimation of the long-term creep and rupture strengths of materials. The article describes the different types of equipment for determination of creep characteristics, including test stands, furnaces, and extensometers. It also discusses the different testing methods for creep rupture: constant-load testing and constant-stress testing. The article presents other testing considerations and concludes with information on stress relaxation testing.

This article discusses the methods for assessing creep-rupture properties, particularly, nonclassical creep behavior. The determination of creep-rupture behavior under the conditions of intended service requires extrapolation and/or interpolation of raw data. The article describes the various techniques employed for data handling of most materials and applications of engineering interest. These techniques include graphical methods, methods using time-temperature parameters, and methods used for estimations when data are sparse or hard to obtain. The article reviews the estimation of required creep-rupture properties based on insufficient data. Methods for evaluation of remaining creep-rupture life, including parametric modeling, isostress testing, accelerated creep testing, evaluation by the Monkman-Grant coordinates, and the Materials Properties Council (MPC) Omega method, are also reviewed.

Predicting the service life of structural components involves creep-fatigue crack growth (CFCG) testing under pure creep conditions. This article provides a discussion on the loading condition and the type of ductile and brittle material showing creep behavior. It focuses on a description of the experimental method that should be followed in conducting tests of CFCG with various hold times. The article describes the testing conditions, definitions, and the necessary calculations of various crack-tip parameters considered during static and cyclic loading in time-dependent fracture mechanics. The parameters considered for static loading are C*, C(t), C*(t), C*h, Ct, and Cst(t). For cyclic loading, the parameters are delta Jc and (Ct)avg. An overview of life-prediction models is also provided.

An integral aspect of designing and material selection is the use of mechanical properties derived from various mechanical testing. This article introduces the basic concepts of mechanical design and its relation with the properties derived from various mechanical testings, namely, tensile, compressive, hardness, torsion and bend, shear load, shock, and fatigue and creep testings. It describes the design criteria for combined properties derived from each of the mechanical testing. The article concludes with a discussion on the effect of environment on the mechanical properties.

This article describes the concepts for characterizing and predicting elevated-temperature crack growth in structural materials. It discusses both creep and creep-fatigue crack growth and focuses mainly on creep crack growth tests that are carried out in accordance with ASTM E 1457. The article provides information on typical test procedures and equipment used for these tests. It concludes with information on crack growth correlations.

This article discusses the deformation and viscoelastic characteristics of plastics as polymeric materials, focusing on the test methods used for the evaluation of their mechanical properties, methods available for analytically predicting the deformation response of polymers, and the effect of viscoelasticity on the test methods used. Two common ways of evaluating viscoelasticity of plastics are by means of creep experiments and dynamic mechanical experiments. Graphic or tabular analysis of test data, time-temperature superposition, and empirical correlation methods are commonly employed for analytical prediction of deformation characteristics of polymers.

This article focuses on the evaluation of mechanical properties of freestanding films and films adherent to their substrates. Common methods of testing freestanding films, including uniaxial tensile testing, uniaxial creep testing, biaxial testing, and beam-bending methods, are discussed. For films which are adherent to their substrates, indentation testing is used to evaluate hardness, creep, and strength.