This article summarizes some of the effects of the major alloying elements in low-alloy steels and the heat treating for some common types of low-alloy steels. Coverage includes common alloys of the following low-alloy steel types: low-alloy manganese steels, low-alloy molybdenum steels, low-alloy chromium-molybdenum steels, low-alloy nickel-chromium-molybdenum steels, low-alloy nickel-molybdenum steels, low-alloy chromium steels, low-alloy chromium-vanadium steels, and low-alloy silicon-manganese steels. The article reviews heat treating parameters and processing considerations for each category of steel, including spherodizing, normalizing, annealing, hardening, and tempering.

Cr-Mo steels are preferred in the construction of high-temperature components because they possess excellent strength, toughness, and corrosion resistance relative to carbon steels and most low-alloy steels. This article discusses the composition and metallurgy of the heat-resistant Cr-Mo steels. It details the Charpy V-notch (CVN) toughness properties of Cr-Mo steels relevant to fatigue and fracture resistance. The fracture mechanics of Cr-Mo steels are reviewed. The article analyzes the characterization of low-cycle fatigue based on fatigue damage calculations. It concludes with information on fatigue crack growth and fatigue behavior of weldments.

This article presents in-depth metallurgical information about the response of carbon and low-alloy steels to welding conditions and micro-structural evolution in the weld heat-affected zone. It discusses the fabrication weldability and service weldability of carbon and low-alloy steels. The article describes six general classes of the metal: low-carbon steels, high-strength low-alloy steels, quenched-and-tempered steels, heat-treatable low-alloy steels, thermal-mechanical-controlled processing steels, and chromium-molybdenum steels. It concludes with an illustration of steels' susceptibility to hydrogen-assisted cold cracking relative to carbon content and carbon equivalent.

This article discusses some elevated-temperature properties of carbon steels and low-alloy steels with ferrite-pearlite and ferrite-bainite microstructures for use in boiler tubes, pressure vessels, and steam turbines. The selection of steels to be used at elevated temperatures generally involves compromise between the higher efficiencies obtained at higher operating temperatures and the cost of equipment, including materials, fabrication, replacement, and downtime costs. The article considers the low-alloy steels which are the creep-resistant steels with 0.5 to 1.0% Mo combined with 0.5 to 9.0% Cr and perhaps other carbide formers. The factors affecting mechanical properties of steels include the nature of strengthening mechanisms, the microstructure, the heat treatment, and the alloy composition. The article describes these factors, with particular emphasis on chromium-molybdenum steels used for elevated-temperature service. Although the mechanical properties establish the allowable design-stress levels, corrosion effects at elevated temperatures often set the maximum allowable service temperature of an alloy. The article also discusses the effects of alloying elements in annealed, normalized and tempered, and quenched and tempered steels.