Bridges and highways are core components of transportation system and range from pavements with earth, gravel, or stone covered by a thin bituminous surface course to a continually reinforced Portland cement concrete (PCC) roadway with or without a bituminous wear course. This article provides information on bridges and dowels and the reinforcement used in PCC roadways that suffer from corrosion. An overview is provided on the rise in awareness of the corrosion issues affecting bridges and highways. The chemistry and structure of concrete and its role as an electrolyte in promoting corrosion are also discussed. The article addresses reinforcement, including conventional, prestressed, cable stays, and corrosion-resistant reinforcement. It deals with the electrochemical methods for the inspection and corrosion control of embedded reinforcement. The article also reviews the corrosion of metal bridges and corrosion control, including the use of weathering steels and coating systems.

Weathering steels contain deliberate additions of alloying elements intended to increase the atmospheric corrosion resistance of steel. This article provides an overview of atmospheric corrosion testing. It describes the estimation of the atmospheric corrosion behavior of weathering steels by two methods such as short-term exposure tests and calculation of a corrosion index based on the steel composition. The article highlights some generalities about corrosion mechanisms. Based on the mechanism of atmospheric corrosion resistance of weathering steel, working rules for creating the protective oxide film have evolved. The article also provides case histories that illustrate both the violations of these rules and suggestions on how to avoid certain maintenance problems that may be encountered with weathering steels.