Stainless steels are characterized as having relatively poor wear resistance and tribological properties, but they are often required for a particular application because of their corrosion resistance. This article describes the classification of stainless steels and wear. Stainless steels have been classified by microstructure and are categorized as austenitic, martensitic, ferritic, or duplex. The main categories of wear are related to abrasion, erosion, adhesive wear, and surface fatigue. The article presents a list that proposes the alloy family that could be the optimal selection for a particular wear mode. The corrosion modes include dry sliding, tribocorrosion, erosion, erosion-corrosion, cavitation, dry erosion, erosion-oxidation, galling and fretting.

Stainless steels are primarily alloys of iron and chromium. They are grouped into five families, primarily based on their microstructure: ferritic, austenitic, martensitic, duplex, and precipitation hardening. Three out of the five families of stainless steels, namely, austenitic, ferritic, and martensitic, are well suited for manufacture via conventional powder metallurgy (PM) processes. This article presents the iron-chromium partial phase diagram to illustrate the changes in the temperature range when pure iron is alloyed with chromium. It describes AISI and UNS numbering systems, which are used as an identification system for stainless steels. The article tabulates the material designations of stainless steels in accordance with the Metal Powder Industries Federation. It also details the characteristics and chemical composition of wrought and PM stainless steels.

This article provides information on the metallurgy of austenitic stainless steels, and the formation of their intermediate phases (Sigma, Chi, and Laves). It discusses sensitization, a major problem associated with the austenitics, and solutions to avoid the problem. The article describes heat treatments applied to austenitic stainless steels, namely, soaking for homogenization and preparation for hot working; annealing to remove the effects of cold work and to put alloying elements into solid solution; and stress relieving. It provides information on the stabilizing anneal process, which is conducted on stabilized alloys, and discusses the metallurgical characteristics of austenitic stainless steels that may affect the selection of a stress-relieving treatment and prevention of stress corrosion by stress relieving. The article also discusses the heat treatments applied to duplex stainless steels, which involve soaking and annealing, achieving the austenite-ferrite balance, precipitation of intermetallics, and alpha prime precipitation.

Low-temperature surface hardening is mostly applied to austenitic stainless steels when a combination of excellent corrosion performance and wear performance is required. This article provides a brief history of low-temperature surface hardening of stainless steel, followed by a discussion on physical metallurgy, including crystallographic identity, thermal stability and decomposition, nitrogen and carbon solubility in expanded austenite, and diffusion kinetics of interstitials. It provides a description of low-temperature nitriding and nitrocarburizing processes for primarily austenitic and, to a lesser extent, other types of stainless steels along with practical examples and industrial applications of these steels.

Stainless steels are essential for the modern industrial civilization because of their corrosion resistance, especially in the chemical, petrochemical, and food industries. This article discusses the classification of the various types of stainless steels, including martensitic, ferritic, austenitic, duplex (ferritic-austenitic), and precipitation-hardening stainless steels. It presents a checklist of characteristics to be considered in selecting the proper type of stainless steel for a specific application. The article also outlines the need to promote the formation of an effective protective passive layer in stainless steels. It discusses hardness, fatigue and fretting properties, tribological properties, wear resistance, and corrosion-wear process of the S-phase layer. The article describes two thermochemical nitriding techniques of stainless steels: plasma-assisted nitriding techniques and non-plasma assisted nitriding processes. It also describes the difficulties in stainless steel nitriding/carburizing.

Stainless steels are used for medical implants and surgical tools due to the excellent combination of properties, such as cost, strength, corrosion resistance, and ease of cleaning. This article describes the classifications of stainless steels, such as austenitic stainless steels, martensitic stainless steels, ferritic stainless steels, precipitation-hardening stainless steels, and duplex stainless steels. It contains a table that lists common medical device applications for stainless steels. The article discusses the physical metallurgy and physical and mechanical properties of stainless steels. Medical device considerations for stainless steels, such as fatigue strength, corrosion resistance, and passivation techniques, are reviewed. The article explains the process features of implant-grade stainless steels, including type 316L, type 316LVM, nitrogen-strengthened, ASTM F1314, ASTM F1586, ASTM F2229, and ASTM F2581 stainless steels.

This article focuses on the general internal state variable method, and its simplification, for single-parameter models, in which the microstructure evolution may be treated as an isokinetic reaction. It explains that isokinetic microstructure models are applied to diffusional transformations in fusion welding, covering particle dissolution, growth, and coarsening of precipitates in the heat-affected zone. The article discusses the versatility of the internal state variable approach in modeling of nonisothermal transformations for various materials and processes. It describes the process models applied to predict the microstructure evolution in Al-Mg-Si alloys during multistage thermal processing involving heat treatment and welding. The article also provides information on the microstructure models exploited in engineering design to optimize the load-bearing capacity of welded aluminum components.

This article discusses the corrosion characteristics of superaustenitic stainless and duplex stainless steels, which are used in pharmaceutical industry. It describes passivation treatments and the electropolishing of stainless steels. The article informs that electropolishing is not a passivation treatment, although the proper execution of the process will result in a passive surface. The article concludes with a discussion on roughing, which is a phenomenon of particular interest to the pharmaceutical industry.

Metallurgical variables, mainly carbon distribution and the presence of nitrogen and metallic phases, can influence the corrosion behavior of austenitic, ferritic, duplex, and martensitic stainless steels. This article describes the effects of these metallurgical and processing variables on the susceptibility of the stainless steels to intergranular corrosion and intergranular stress-corrosion cracking and their testing methods. It explains the effect of sigma and related phases on the corrosion behavior of stainless steels.

This article reviews the metallurgical factors associated with welding. It provides a discussion on the preferential attack associated with weld metal precipitates in austenitic stainless steels. The article describes the corrosion associated with postweld and weld backing rings. The effects of gas-tungsten arc weld shielding gas composition and heat-tint oxides on corrosion resistance are also discussed. The article explains microbiological corrosion of butt welds in water tanks with the examples. In addition, it provides information on corrosion of ferritic stainless steel weldments and duplex stainless steel weldments.

This article commences with a discussion on the characteristics of stress-corrosion cracking (SCC) and describes crack initiation and propagation during SCC. It reviews the various mechanisms of SCC and addresses electrochemical and stress-sorption theories. The article explains the SCC, which occurs due to welding, metalworking process, and stress concentration, including options for investigation and corrective measures. It describes the sources of stresses in service and the effect of composition and metal structure on the susceptibility of SCC. The article provides information on specific ions and substances, service environments, and preservice environments responsible for SCC. It details the analysis of SCC failures, which include on-site examination, sampling, observation of fracture surface characteristics, macroscopic examination, microscopic examination, chemical analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium.

Stainless steels are iron-base alloys containing minimum of approximately 11% Cr, and owing to its excellent corrosion resistance, are used for wide range of applications. These applications include nuclear reactor vessels, heat exchangers, oil industry tubular, chemical processing components, pulp and paper industries, furnace parts, and boilers used in fossil fuel electric power plants. The article provides a brief introduction on corrosion resistance of wrought stainless steel and its designations. It lists the chemical composition and describes the physical and mechanical properties of five major stainless steel families, of which four are based on the crystallographic structure of the alloys, including martensitic, ferritic, austenitic, or duplex. The fifth is precipitation-hardenable alloys, based on the type of heat treatment used. The article further discusses the factors in the selection of stainless steel, namely corrosion resistance, fabrication characteristics, product forms, thermally induced embrittlement, mechanical properties in specific temperature ranges, and product cost.

This article reviews the influence of local strains and corrosion fatigue on the initiation of fatigue cracks in duplex stainless steels. It provides useful information on fatigue crack growth, fatigue strength, and fracture toughness of duplex stainless steels. The article discusses the fatigue and fracture behavior of duplex stainless steels during stress-corrosion cracking. It details the elevated-temperature properties of duplex stainless steels, such as creep-fatigue behavior and thermal cycling properties.

This article summarizes the key mechanical characteristics of various types of stainless steel, including ferritic, austenitic, martensitic, precipitation hardening, and duplex steels. Particular emphasis is on fracture properties and corrosion fatigue. The article tabulates typical room-temperature mechanical properties and fatigue endurance limits of stainless steels. Stainless steels are susceptible to embrittlement during thermal treatment or elevated-temperature service. The article discusses embrittlement in terms of sensitization, 475 deg C embrittlement, and sigma-phase embrittlement. It also describes the effect of environment on fatigue crack growth rate.

Stainless steels are an important class of engineering alloys used in both wrought and cast form for a wide range of applications and in many environments. This article aids in the selection of stainless steels based on weldability and service integrity. Stainless steels are classified by microstructure and are described as ferritic, martensitic, austenitic, or duplex. The article illustrates compositional ranges of the ferritic, martensitic, austenitic, and duplex alloys in the Schaeffler diagram. It describes the metallurgical aspects of welded stainless steels to be considered for particular engineering applications and service conditions. The article discusses the microstructural evolution of the weld metal and the heat-affected zone, susceptibility to defect formation during welding, mechanical and corrosion properties, and weld process tolerance.

This article provides information on the base material properties of wrought duplex stainless steels (DSS). These properties include microstructure, alloy grades, mechanical and physical properties, and corrosion resistance. The article reviews the applications and microstructural development of DSS. It describes the factors influencing welding and weldability of the DSS. These factors include preheating, postweld heat treatment, interpass temperature control, welding practices, welding procedure qualification, filler metal requirements, cracking behavior, and loss of properties. The article examines the applicable welding processes such as fusion welding and solid-state welding processes.

This article addresses consumable selection and procedure development for the welding of stainless steels. The WRC-1992 diagram and the Schaeffier diagram, are used to illustrate the rationale behind many filler-metal choices. The article discusses the basic metallurgy and base metals of five major families of stainless steels: martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, precipitation-hardening (PH) stainless steels, and duplex ferritic-austenitic stainless steels. Stainless steels of all types are weldable by virtually all welding processes. The article describes the common arc welding processes with regard to procedure and technique errors that can lead to loss of ferrite control with the common austenitic stainless steel weld metals that are designed to contain a small amount of ferrite for protection from hot cracking. The arc welding processes include shielded-metal arc welding, gas-tungsten arc welding, and gas-metal arc welding.

The machinability of stainless steels varies from low to very high, depending on the final choice of the alloy. This article discusses general material and machining characteristics of stainless steel. It briefly describes the classes of stainless steel, such as ferritic, martensitic, austenitic, duplex, and precipitation-hardenable alloys. The article examines the role of additives, such as sulfur, selenium, tellurium, lead, bismuth, and certain oxides, in improving machining performance. It provides ways to minimize difficulties involved in the traditional machining of stainless steels. The article describes turning, drilling, tapping, milling, broaching, reaming, and grinding operations on stainless steel. It concludes with information on some of the nontraditional machining techniques, including abrasive jet machining, abrasive waterjet machining electrochemical machining, electron beam machining, and plasma arc machining.