A detailed fracture mechanics evaluation is the most accurate and reliable prediction of process equipment susceptibility to brittle fracture. This article provides an overview and discussion on brittle fracture. The discussion covers the reasons to evaluate brittle fracture, provides a brief summary of historical failures that were found to be a result of brittle fracture, and describes key components that drive susceptibility to a brittle fracture failure, namely stress, material toughness, and cracklike defect. It also presents industry codes and standards that assess susceptibility to brittle fracture. Additionally, a series of case study examples are presented that demonstrate assessment procedures used to mitigate the risk of brittle fracture in process equipment.

This article describes some of the welding discontinuities and flaws characterized by nondestructive examinations. It focuses on nondestructive inspection methods used in the welding industry. The sources of weld discontinuities and defects as they relate to service failures or rejection in new construction inspection are also discussed. The article discusses the types of base metal cracks and metallurgical weld cracking. The article discusses the processes involved in the analysis of in-service weld failures. It briefly reviews the general types of process-related discontinuities of arc welds. Mechanical and environmental failure origins related to other types of welding processes are also described. The article explains the cause and effects of process-related discontinuities including weld porosity, inclusions, incomplete fusion, and incomplete penetration. Different fitness-for-service assessment methodologies for calculating allowable or critical flaw sizes are also discussed.

Impact wear can be defined as the wear of a solid surface that is due to percussion, which is a repetitive exposure to dynamic contact by another solid body. This article discusses the volume (or mass) removal of material either at or under engineering contact stress levels and outlines a rational, semi-empirical impact wear theory. It illustrates a linear wear mechanism that occurs in print heads and repetitive impacts that take place in metallic machine contacts. The article concludes with information on plotting a wear curve for an originally plane, massive carbon steel machine platen subjected to repetitive compound impact by a hard, nonwearing spherical-ended steel alloy component.

This article presents information regarding the use of protective coatings in municipal potable water systems, including raw water collection and transmission, water treatment plants, and treated water distribution. It provides useful guidance for the selection and use of protective coatings in these municipal water systems. The most commonplace corrosion-damage mechanisms are highlighted. The article describes the most common materials of construction found in municipal water systems, namely, cast iron, ductile iron, carbon steel, precast concrete cylinder pipe and reinforced concrete pipe, prestressed concrete tanks, and stainless steel. It provides information on the most common generic coating systems used for new steel tanks and water storage tanks. It concludes with a discussion of quality watch-outs when selecting or using protective coatings in municipal water systems.

This article provides information on the municipal wastewater system components such as piping, pump stations, headworks, clarifiers, aeration structures, digesters, biosolids dewatering equipment, and sludge stabilization. It explains the major corrosion damage mechanisms to which those component parts of the system are exposed. It presents useful guidelines for selecting and using protective coatings in municipal sewerage collection systems and water reclamation facilities in wastewater treatment plants. The article includes annotated flow diagrams of a wastewater collection system, wastewater treatment plants, and spreadsheets listing the most widely used generic coating systems by structure and substrate material. It concludes with a section on quality watchouts when selecting or using protective coatings in municipal wastewater systems.

This article briefly reviews the production methods and characteristics of plain carbon and low-alloy water-atomized iron and steel powders, high-porosity iron powder, carbonyl iron powder, and electrolytic iron powder. It emphasizes on atomized powders, because they are the most widely used materials for ferrous powder metallurgy. The article provides information on the properties and applications of these powders. It also includes an overview of diffusion alloying, basics of admixing, and bonded premixes.

High-alloy graphitic cast irons are used primarily in applications requiring corrosion resistance or strength and oxidation resistance in high-temperature service. This article describes the properties, applications and heat treatment processes of high-alloy graphitic cast irons, including austenitic gray irons and austenitic ductile irons. It also provides a discussion on the heat treatment of high-silicon irons for heat resisting and corrosion resisting applications.

This article introduces the general principles and applications of heat treatment to iron castings. It provides a detailed discussion on the heat treatment processes, namely, stress relieving, annealing, normalizing, throughhardening, and surface hardening for various types of cast irons. These include gray iron, ductile iron, compacted graphite iron, white iron, malleable iron, and high-alloy iron. The article describes how to control temperature and atmosphere during the heat treatment of the iron castings.

This article summarizes some of the effects of the major alloying elements in low-alloy steels and the heat treating for some common types of low-alloy steels. Coverage includes common alloys of the following low-alloy steel types: low-alloy manganese steels, low-alloy molybdenum steels, low-alloy chromium-molybdenum steels, low-alloy nickel-chromium-molybdenum steels, low-alloy nickel-molybdenum steels, low-alloy chromium steels, low-alloy chromium-vanadium steels, and low-alloy silicon-manganese steels. The article reviews heat treating parameters and processing considerations for each category of steel, including spherodizing, normalizing, annealing, hardening, and tempering.

Tool steels are an important class of steels due to their distinct applications and their specific heat treating issues. This article provides an overview of the classification and production of tool steels, and discusses the procedures and process control requirements for heat treating principal types of tool steels. It reviews the various heat treating processes, namely, normalizing, annealing, stress relieving, austenitizing, quenching, and tempering, and surface treatments and cold treating. The article also provides information on the applicability of these processes to various types of tool steels.

Ductile cast irons are heat treated to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article provides a detailed account of the general characteristics of ductile irons. It discusses the most important heat treatments of ductile irons, namely, stress relieving, austenitizing, annealing, normalizing, quenching, martempering, austempering, and surface hardening. The article elucidates the effects of these heat treatments on the mechanical properties of the ductile irons.

The choice of heat treatment depends on the service requirements of a given bearing and how the bearing will be made. This article describes the design parameters, material characteristics required to sustain performance characteristics, metallurgical properties, and dimensional stability. It also provides a description of various extensively-used heat treatment processes, namely, carburizing, carbonitriding, induction surface hardening, and nitriding associated with various bearings. In addition, the article explores the factors to be considered in selecting a process and explains why it is optimum for a specific application.

The design of a tool-steel part directly affects the susceptibility to shape distortion on heating and cooling. This article provides information on the selection of chemical composition and the effect of composition on size distortion. It explains the various factors considered to control distortion in tools steels, namely, design, initial condition, machining procedure, and heat treatment. Distortion can occur both during and after heat treatment. The article discusses the chief ways to precisely control the extent of distortion by heat treating and auxiliary mechanical methods. Stabilizing treatments, namely, stabilizing by tempering and stabilizing by cold treatment are used to minimize dimensional changes that occur following heat treatment.

Quench cracking is a brittle fracture phenomenon, and its occurrence depends not only on the stress changes but also on the mechanical characteristics of metals. Simulation of quenching processes has become possible in the analysis of quench cracking. This article commences with a discussion on the studies conducted to determine the origin of quench cracks, and then describes various test procedures for determining the susceptibility of quench cracking. It provides a description of the brittle fracture in terms of fracture mechanics and fracture toughness of quenched metals, and discusses the effects of impurities, hydrogen, and surface roughness on cracking. The article exemplifies simulation works applied to several successful cracking tests on cylindrical and complex-shaped steel parts.

This article describes the microstructure, properties, and performance of carburized steels, and elucidates the microstructural gradients associated with carbon and hardness gradients. It provides information on case depth measurement, the factors affecting case depth, and the formation and causes of microcracks. The article discusses the effects of alloying elements on hardenability, the effects of excessive retained austenite and massive carbides on fatigue resistance, the effects of residual stresses and internal oxidation on fatigue performance of carburized steels. In addition, the causes of intergranular fracture at austenite grain boundaries and their prevention methods are explored. The article also describes the major mechanisms of bending fatigue crack initiation in carburized steels.

High-alloyed white cast irons are an important group of materials whose production must be considered separately from that of ordinary types of cast irons. The metallic matrix supporting the carbide phase in the high-alloy white cast irons can be adjusted by alloy content and heat treatment to develop proper balance between resistance to abrasion and toughness needed to withstand repeated impact. This article provides a brief discussion on the heat treatment, mechanical properties, and chemical compositions of high-alloy white cast irons such as nickel-chromium white irons and high-chromium white irons.

Distortion, encompassing all irreversible dimensional changes, is of two main types: size distortion and shape distortion. This article provides an overview of the nature and causes of distortion and discusses the process and material aspects of distortion specific to steels and tool steels. It also discusses the prediction of distortion and residual stresses by heat treatment simulation for optimizing production processes. The advantages and limitations of heat treatment simulation are also described.

Precipitation hardening is a hardening mechanism found in various steels and alloy systems, such as nickel-, cobalt-, titanium-, copper-, and iron-base alloys. This article provides a brief description of precipitation hardening process, furnace equipment, surface-related problems, and protective atmospheres used in heat treatment of iron-base precipitation-hardenable (PH) superalloys. It focuses on various factors to be considered in heat treating of PH stainless steels: cleaning prior to heat treatment, furnace atmospheres, time-temperature cycles, variations in cycles, and scale removal after heat treatment. The article describes the mechanical properties, solution treatment, and aging treatment for many martensitic PH alloys, including: Alloy 17-4 PH, Alloy 13-8 Mo, Alloy 15-5 PH, Custom 450, and Custom 455; as well as semiaustenitic PH stainless steels such as Alloy 17-7 PH, Alloy PH 15-7 Mo, AM-350, Pyromet 350, AM-355, and Pyromet 355; austenitic PH stainless steel, A-286; cast PH stainless steels; and iron-nickel PH superalloys.

Low-temperature carburization hardens the surface of austenitic stainless steels through the diffusion of interstitial carbon without the formation of carbides. This article provides an overview on austenitic stainless steels and low-temperature carburization. It reviews the competing technologies and commercial application of low-temperature carburization. The article discusses several processing parameters, including activation of the surface, proper surface preparation, selection and condition of the alloy to be carburized, treatment temperature, and carburizing atmosphere for successful low-temperature carburization of austenitic stainless steels and other chromium-containing alloys. It describes the performance properties of the low-temperature carburized layer: fatigue resistance, wear resistance, erosion resistance, and corrosion resistance.

Powder metallurgy (PM) processes include press and sinter hardening, metal injection molding, powder forging, hot isostatic pressing, powder rolling, and spray forming. This article provides an overview of PM processing methods and general considerations of heat treatment of PM parts that are case-hardened to obtain higher hardness, wear, fatigue, and impact properties. It describes the effects of porosity on heat treatment, alloy content on PM hardenability, and starting material on homogenization of PM steels. The article describes the properties, following heat treatment, of low-alloy steels tempered at 175 ºC for one hour, and lists recommended quench and temper parameters to achieve good wear resistance and core strength based on different ranges of porosity.