This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.

Castability of alloys is a measure of their ability to be cast to a given shape with a given process without the formation of cracks/tears, pores/shrinkage, and/or other significant casting defects. This article discusses the factors which affect the fluidity of an iron melt: alloy composition and initial melt condition. Besides the basic alloy properties, the effective castability of high-alloy irons can be significantly improved through casting and casting system design. The article describes the product design and processing factors of high-alloy graphitic irons and high-alloy white irons. It explains the heat treatment of high-silicon irons for high-temperature service and concludes with a discussion on machining and finishing of high-alloy iron castings.

The high-alloyed white irons are primarily used for abrasion-resistant applications and are readily cast into the parts needed in machinery for crushing, grinding, and handling of abrasive materials. This article discusses three major groups of the high-alloy white cast irons: nickel-chromium white irons, chromium-molybdenum irons, and high-chromium white irons. Mechanical properties for three white irons representing each of these three general groups are presented as bar graphs. The article also describes the various heat treatments of a martensitic microstructure, including austenitization, quenching, tempering, annealing, and stress relieving.

The high-alloy irons can be categorized into two main groups: the high-alloy graphitic irons (covering both gray and ductile grades) and the high-alloy white irons. High-alloy irons are used in applications with demanding requirements, such as high resistance to wear, heat, and corrosion, or for combined properties. This article discusses the specification and selection of high-alloy irons. The common alloying elements and their effect on the stable and metastable eutectic temperatures are listed in a table. The article provides information on the compositions, properties and applications of high-alloy graphitic irons and high-alloy white irons.

A wide range of mechanical properties can be obtained with a given composition of cast iron, depending on the microstructural constituents that form during solidification and subsequent solid-state processing. This article discusses the mechanical properties of gray iron and provides some general property comparisons with malleable, ductile (nodular), and compacted graphite irons. The mechanical properties of gray iron are determined by the combined effects of its chemical composition, processing technique in the foundry, and cooling rates during solidification. The article provides information on the classification of gray irons based on ASTM International specification A48/A48M. It discusses the loading effect, surface effect, notch sensitivity, and environmental effect on the mechanical properties of gray iron. The chemical composition ranges of some of the more widely used heat-resistant gray irons suitable for elevated-temperature service are presented in a table.

Gray irons are commonly classified by their minimum tensile strength. This article describes properties used in the selection of gray irons and the factors that affect properties, particularly the effect of solidification. It discusses the three steps that its processing undergoes in the foundry: liquid metal preparation, solidification, and solid-state transformation. The article discusses the tensile properties of gray cast iron: tensile strength, yield strength, ductility, and modulus of elasticity. It describes hardness tests that are performed for determining the approximate strength characteristics and machinability of a gray iron casting. The article also presents typical mechanical properties of heat-resistant gray irons in a table. It concludes with information on the automotive application of alloy cast irons.

This article describes two contemporary approaches for preparing cast iron specimens with a wide range of phases and constituents as well as different graphite morphologies. It introduces concepts and preparation materials that enable metallographers to shorten the process while producing better, more consistent results. Recommended procedures to prepare cast irons and examples of high-alloy cast iron microstructures revealed using a variety of etchants are presented. Several etchants are used to reveal the matrix microstructure, depending on the alloy content. The article discusses the use of black and white etchants and lists the compositions of abrasion-resistant cast irons according to ASTM A532/A532M in a table.

High-alloy graphitic cast irons are used primarily in applications requiring corrosion resistance or strength and oxidation resistance in high-temperature service. This article describes the properties, applications and heat treatment processes of high-alloy graphitic cast irons, including austenitic gray irons and austenitic ductile irons. It also provides a discussion on the heat treatment of high-silicon irons for heat resisting and corrosion resisting applications.

This article introduces the general principles and applications of heat treatment to iron castings. It provides a detailed discussion on the heat treatment processes, namely, stress relieving, annealing, normalizing, throughhardening, and surface hardening for various types of cast irons. These include gray iron, ductile iron, compacted graphite iron, white iron, malleable iron, and high-alloy iron. The article describes how to control temperature and atmosphere during the heat treatment of the iron castings.

High-alloyed white cast irons are an important group of materials whose production must be considered separately from that of ordinary types of cast irons. The metallic matrix supporting the carbide phase in the high-alloy white cast irons can be adjusted by alloy content and heat treatment to develop proper balance between resistance to abrasion and toughness needed to withstand repeated impact. This article provides a brief discussion on the heat treatment, mechanical properties, and chemical compositions of high-alloy white cast irons such as nickel-chromium white irons and high-chromium white irons.

This article reviews the production stages of iron foundry casting, with particular emphasis on the melting practices, molten metal treatment, and feeding of molten metal into sand molds. It discusses the molten metal treatments for high-silicon gray, high-nickel ductile, and malleable irons. Foundry practices are also described for compacted graphite, high-silicon ductile, and high-alloy white irons.

This article presents a discussion on the melting, pouring, and shakeout practices; composition control; molds, patterns, and casting design; heat treatment; and applications of different classes of nickel-chromium white irons and high-chromium white irons.

This article discusses the melting and pouring practices, heat treatment, and applications of different types of high-alloy graphitic iron, namely, high-silicon gray irons, high-silicon ductile irons, nickel-alloyed austenitic irons, austenitic gray irons, austenitic ductile irons, and aluminum-alloyed irons.

Hydrochloric acid (HCl) may contain traces of impurities that will change the aggressiveness of the solution. This article discusses the effects of impurities such as fluorides, ferric salts, cupric salts, chlorine, and organic solvents, in HCl. It describes the corrosion resistance of various metals and alloys in HCl, including carbon and alloy steels, austenitic stainless steels, standard ferritic stainless steels, nickel and nickel alloys, copper and copper alloys, corrosion-resistant cast iron, zirconium, titanium and titanium alloys, tantalum and its alloys, and noble metals. The article illustrates the effect of HCl on nonmetallic materials such as natural rubber, neoprene, thermoplastics, and reinforced thermoset plastics. It also tabulates the corrosion of various metals in dry hydrogen chloride.

Alloy cast irons are casting alloys based on the Fe-C-Si system that contain one or more alloying elements added to enhance one or more useful properties. This article discusses the composition of different types of alloy cast iron, including white cast irons, corrosion-resistant cast irons, heat-resistant cast irons, and abrasion-resistant cast irons. It provides information on the effect of the alloying element on their high-temperature properties. The article also discusses the microstructure and mechanical properties of alloy cast irons.

Cast iron, which usually refers to an in situ composite of stable eutectic graphite in a steel matrix, includes the major classifications of gray iron, ductile iron, compacted graphite iron, malleable iron, and white iron. This article discusses melting, pouring, desulfurization, inoculation, alloying, and melt treatment of these major ferrous alloys as well as carbon and alloy steels. It explains the principles of solidification by describing the iron-carbon phase diagram, and provides a pictorial presentation of the basic microstructures and processing steps for cast irons.

Cast irons may be compared with steels in their reactions to hardening. However, because cast irons (except white iron) contain graphite and substantially higher percentages of silicon, they require higher austenitizing temperatures. This article describes the effect of heat treatment processes such as annealing, normalizing, surface hardening, tempering, stress relieving, quenching, and austempering, on hardness and tensile properties of cast irons, namely gray irons, ductile irons, malleable irons, and austenitic irons.

Alloy cast irons are considered to be those casting alloys based on the iron-carbon-silicon system that contain one or more alloying elements intentionally added to enhance one or more useful properties. Alloy cast irons can be classified as white cast irons, corrosion-resistant cast irons, and heat-resistant cast irons. This article discusses abrasion-resistant chilled and white irons, high-alloy corrosion-resistant irons, and medium-alloy and high-alloy heat-resistant gray and ductile irons. The article outlines in a list the approximate ranges of alloy content for various types of alloy cast irons. The article explains the effects of alloying elements and the effects of inoculants. In most cast irons, it is the interaction among alloying elements that has the greatest effect on properties. Inoculants other than appropriate graphitizing or nodularizing agents are used rarely, if ever, in high-alloy corrosion-resistant or heat-resistant irons.

This article discusses the classification schemes for cast irons and describes the characteristics of major categories, including gray iron, white iron, ductile iron, compacted graphite iron, mottled iron, malleable iron, and austempered ductile iron. It also discusses some of the basic principles of cast iron metallurgy. When discussing the metallurgy of cast iron, the main factors of influence on the structure include chemical composition, cooling rate, liquid treatment, and heat treatment. In terms of commercial status, cast irons can be classified as common cast irons and special cast irons. Special cast irons differ from the common cast irons mainly in the higher content of alloying elements. Alloying elements can be added in common cast iron to enhance some mechanical properties. They influence both the graphitization potential and the structure and properties of the matrix.

This article provides a discussion on cutting tools, their materials and design; cutting fluids; and various aspects of machining operations of heat-resistant alloys, with several examples. Operations such as turning, planing and shaping, broaching, drilling, reaming, counterboring and spotfacing, tapping and thread milling, milling, sawing, and grinding are discussed. Nominal compositions of wrought heat-resistant alloys and nickel-base heat-resistant casting alloys, as well as compositions of cobalt-base heat-resistant casting, iron-base heat-resistant casting, and mechanically alloyed (oxide dispersion strengthened) products are also listed.