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Ductile iron
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Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006831
EISBN: 978-1-62708-329-4
Abstract
The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.
Book Chapter
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006416
EISBN: 978-1-62708-192-4
Abstract
Cast irons have been widely used by engineers in applications that require low cost, excellent castability, good damping capacity, ease of machining, and wear resistance. This article discusses the classification of wear for cast irons: adhesive wear, abrasive wear, and erosive wear. Typical wear applications for a variety of cast iron grades are listed in a table. The article reviews the general wear characteristics of gray irons, compacted graphite (CG) irons, and ductile irons. It discusses the typical compositions and properties of white and chilled iron castings. Gray cast iron is the dominant material for both brake drums and disk brake rotors. The article reviews brake lining chemistry effects, graphite morphology effects, and external abrasive effects on brake drums. It concludes with information on cast iron grinding balls.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006339
EISBN: 978-1-62708-179-5
Abstract
Austempered ductile iron (ADI) results from a specialty heat treatment of ductile cast iron. This article discusses the production of austempered ductile iron by heat treatment. The austempered ductile iron grades, according to ISO 17804 and EN 1564, are presented in a table. For economic reasons, or to avoid metallurgical problems, combinations of alloys are often used to achieve the desired hardenability in austempered ductile iron. The article provides information on the alloy combinations for austempered ductile iron. The mechanical properties, fracture toughness, fatigue, and abrasion resistance of the austempered ductile iron are discussed. The article concludes with information on the applications for austempered ductile iron.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006309
EISBN: 978-1-62708-179-5
Abstract
Malleable iron is a type of cast iron that has most of its carbon in the form of irregularly shaped graphite nodules instead of flakes, as in gray iron, or small graphite spherulites, as in ductile iron. This article discusses the production of malleable iron based on the metallurgical criteria: to produce solidified white iron throughout the section thickness; and to produce the desired graphite distribution (nodule count) upon annealing. It describes the induction heating and quenching or flame heating and quenching for surface hardening of fully pearlitic malleable iron. Laser and electron beam techniques also have been used for hardening selected areas on the surface of pearlitic and ferritic malleable iron castings that are free from decarburization.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006310
EISBN: 978-1-62708-179-5
Abstract
Unlike gray iron, which contains graphite flakes, ductile iron has an as-cast structure containing graphite particles in the form of small, rounded, spheroidal nodules in a ductile metallic matrix. This article discusses the raw materials that are used for ductile iron production and outlines the most common and important requirements for controlling the composition of ductile iron. Treatment to produce ductile iron involves the addition of magnesium to change the form of the graphite, followed by or combined with inoculation of a silicon-containing material to ensure a graphitic structure with freedom from carbides. The article describes the methods of magnesium treatment, control of magnesium content, and inoculation. It concludes with a discussion on the metallurgical controls of ductile iron production.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006300
EISBN: 978-1-62708-179-5
Abstract
This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006334
EISBN: 978-1-62708-179-5
Abstract
This article describes different methods by which the composition of cast iron can be analyzed. It provides particular emphasis on the methods for evaluating the graphitization potential of a melt with prescribed limits on carbon, silicon, and alloying elements. The article discusses the effect of cooling rate on the graphitization of a given composition by chill and wedge tests. Thermal analysis of cooling curves gives excellent information about the solidification and subsequent cooling of cast iron alloys. The article presents some applications of the cooling curve analysis and explains the evaluation of carbon-silicon contents, graphite shape, graphite nucleation, and contraction-expansion balance. It illustrates the use of an immersion steel sampling device for compacted graphite iron production and provides information on the ferrite-pearlite ratio in ductile iron.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006340
EISBN: 978-1-62708-179-5
Abstract
This article discusses the production process, testing methods, quality control, and common defects found in heavy-section ductile iron (DI) castings, along with analyses of industrial examples. The common defects include shrinkage defects, graphite-particle-related defects, and chunk graphite defects. The recommended chemical compositions for certain section thicknesses in ductile iron grades are presented in a table. The article illustrates the relationship between microstructure and mechanical properties of DI by using either industrial examples or castings produced under laboratory conditions.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006294
EISBN: 978-1-62708-179-5
Abstract
This article discusses criteria that can be used for the classification of cast iron: fracture aspect, graphite shape, microstructure of the matrix, commercial designation, and mechanical properties. It addresses the main factors of influence on the structure of cast iron, including chemical composition, cooling rate, and heat treatment. The article describes some basic principles of cast iron metallurgy. It discusses the main effects of the chemical composition of ductile iron and compacted graphite (CG) iron. The composition of malleable irons must be selected in such a way as to produce a white as-cast structure and to allow for fast annealing times. Some typical compositions of malleable irons are presented in a table. The article concludes with information on special cast irons.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006325
EISBN: 978-1-62708-179-5
Abstract
The mechanical properties of ductile cast irons are determined largely by the microstructure of the steel matrix in combination with the shape, size, and distribution of the graphite nodules. This article describes the designation of ductile cast irons according to the ASTM International designation system and reviews standard-grade ductile cast irons. An overview of the most commonly used standards related to designation and specification of ductile cast iron is presented in a table. This article discusses the use of low-alloy ductile cast irons at elevated temperatures and the chemical compositions and some mechanical properties of austenitic ductile cast irons. The article concludes with a discussion on heat treatment of austempered ductile iron.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006301
EISBN: 978-1-62708-179-5
Abstract
This article describes some examples of the different welding processes for gray, ductile, and malleable irons. These processes include fusion welding, repair welding, shielded metal arc welding, gas metal arc welding, flux cored arc welding, gas tungsten arc welding, submerged arc welding, oxyfuel welding, and braze welding. The article discusses various special techniques, such as groove-face grooving, studding, joint design modifications, and peening, for improving the strength of a weld or its fitness for service. The article describes other fusion welding methods such as electrical resistance welding and thermite welding. It reviews thermal spraying processes, such as flame spraying, arc spraying, and plasma spraying, of a cast iron.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006315
EISBN: 978-1-62708-179-5
Abstract
This article describes the modification and inoculation of cast iron, and schematically illustrates the major effects of inoculation in gray cast irons. Inoculation could be considered as a common liquid-state treatment for all commercial cast irons (gray/compacted/ductile irons), while modification is essential to produce compacted graphite iron (intermediate level) and ductile iron. The article discusses the most important aspects of a gray cast iron inoculation treatment and the factors influencing its inoculation efficiency. It describes the modification and inoculation of ductile cast iron and compacted graphite cast iron.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006326
EISBN: 978-1-62708-179-5
Abstract
This article discusses some of the factors that are linked directly to the casting design of ductile iron castings. It reviews the choice of molding process, application of draft, and patternmaker's allowance that should be taken into consideration in designing castings. The article describes the solidification shrinkage associated with the volume change that occurs during solidification, as well as strength and stiffness of ductile iron castings. It concludes with a discussion on the thermal deformation and residual stress in ductile iron castings.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006327
EISBN: 978-1-62708-179-5
Abstract
From the point of view of economics and ecology, thin-wall ductile iron (TWDI) castings can compete in terms of mechanical properties with the light castings made of aluminum alloys. This article discusses the effect of technological factors on the cooling rate and physicochemical state of the liquid metal for preparing thin-wall castings with good mechanical properties and performance while avoiding casting defects. It describes a variety of defects that may appear during the production of TWDI castings, such as casting skin anomalies (e.g., flake graphite, graphite segregation), graphite clusters, exploded graphite, slag inclusions, shrinkage porosity, eutectic chill and secondary carbides, and cold shuts. The article reviews the tensile, fatigue, impact, and wear properties of TWDI castings. It provides information on the production and applications of TWDI castings.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006322
EISBN: 978-1-62708-179-5
Abstract
Ductile cast irons are heat treated primarily to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article discusses the most important heat treatments of ductile irons and their purposes. International standards of ductile iron provided by ASTM International, the International Organization for Standardization (ISO), and SAE International are presented in a table. The article explains basic structural differences between the ferritic, pearlitic, martensitic, and ausferritic classes. It presents recommended practices for annealing ductile iron castings for different alloy contents and for castings with and without eutectic carbides. The article discusses the induction surface hardening and remelt hardening of ductile iron. It concludes with information on the effect of heat treatment on fatigue strength of ductile iron.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006348
EISBN: 978-1-62708-179-5
Abstract
This article presents typical wear applications for a variety of cast iron grades in a table. In general, wear is classified according to three major types: adhesive (frictional) wear (sliding and rolling) caused by contact of one metallic surface with another; abrasive wear caused by contact with metallic (shots, swarf) or nonmetallic abrasive materials; and erosive wear. The article discusses general wear characteristics of gray iron, compacted gray iron, and ductile iron. It provides information on the brake lining chemistry effects, graphite morphology effects, normal cast iron wear, local cast iron wear, and external abrasive effects on brake drums and disk brake rotors made of gray cast iron. The article concludes with a discussion on the application of cast iron for grinding balls.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006350
EISBN: 978-1-62708-179-5
Abstract
Metallographic techniques for ductile irons are similar to those for other cast irons but more difficult than for steels, because graphite retention is a challenging task. This article presents recommended procedures to prepare ductile irons. It discusses three contemporary approaches for preparing ductile cast iron specimens with a wide range of phases and constituents as well as variations in graphite morphologies. A wide variety of matrix microstructures can be obtained in ductile irons. Examples are presented using a variety of etchants. Control of the nodularity of graphite in ductile irons is critical to their performance. The article presents details concerning the characterization of the graphite nodules.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006344
EISBN: 978-1-62708-179-5
Abstract
A wide range of mechanical properties can be obtained with a given composition of cast iron, depending on the microstructural constituents that form during solidification and subsequent solid-state processing. This article discusses the mechanical properties of gray iron and provides some general property comparisons with malleable, ductile (nodular), and compacted graphite irons. The mechanical properties of gray iron are determined by the combined effects of its chemical composition, processing technique in the foundry, and cooling rates during solidification. The article provides information on the classification of gray irons based on ASTM International specification A48/A48M. It discusses the loading effect, surface effect, notch sensitivity, and environmental effect on the mechanical properties of gray iron. The chemical composition ranges of some of the more widely used heat-resistant gray irons suitable for elevated-temperature service are presented in a table.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006342
EISBN: 978-1-62708-179-5
Abstract
The metallographic specimen preparation process for microstructural investigations of cast iron specimens usually consists of five stages: sampling, cold or hot mounting, grinding, polishing, and etching with a suitable etchant to reveal the microstructure. This article describes the general preparation of metallographic specimens and the methods of macroscopic and microscopic examination. Usually, gray-scale (black-and-white) metallography is sufficient for microstructural analysis of cast irons. The article discusses the use of color metallography of gray irons and ductile irons. It also presents application examples of color metallography.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006345
EISBN: 978-1-62708-179-5
Abstract
Ductile iron, also known as nodular iron or spheroidal graphite iron, is second to gray iron in the amount of casting produced. This article discusses the common grades of ductile iron that differ primarily by the matrix structure that contains the spherical graphite. The grades of ductile iron designated by their tensile properties in the specification ASTM A536 are presented in a table. The article various reviews factors, such as microstructure, composition, and section effect, affecting the mechanical properties of ductile iron. It discusses the hardness properties, tensile properties, shear and torsional properties, damping capacity, compressive properties, fatigue properties, and fracture toughness of ductile iron. The article concludes with information on the applications of austempered ductile iron.
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